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11.
In multiphase systems capillary pressures play a significant role on fluid movement and retention. The facility to predict
the effect of different thermal remediation strategies requires the knowledge of the effect of temperature on capillary pressure-saturation
relationships in the soils.
The objective of recent study was (a) to develop a technique for routinely measuring the pressure-saturation curves of soil
samples saturated with a nonpolar liquid at different regulated temperatures (b) to build a database using the measured pressure-saturation
curves and the physical, chemical properties of the model soils (c) to establish the dependence of nonaqueous phase liquid
retention on the soil properties and the temperature.
The retention curves (extraction isotherms) with nonaqueous phase liquid were determined using a modified
pressure plate extractor. The wetting phase was a non-aromatic hydrocarbon distillation product. Pressure plates were designed and constructed in
the laboratory of our department. The temperature was held constant at 20, 40 and 60 ∘C.
Statistical analysis was performed involving selected soil parameters and the measured nonaqueous phase liquid retention data.
The results show that knowing some easily measurable soil parameters (bulk density, particle size distribution, humus and
lime content) we can estimate the nonaqueous phase liquid retention of the soils. The measured “extraction isotherms” provide
essential information about the temperature-dependency of pressure-saturation curves. 相似文献
12.
Izaskun Zorita Joana Larreta Natalia Montero José Germán Rodríguez Javier Franco Ángel Borja 《Chemistry and Ecology》2013,29(5):432-445
Bioaccumulation and biological effects of pollution were assessed in mussels (Mytilus galloprovincialis) caged for one month at three sites in the Oiartzun estuary (south-eastern Bay of Biscay, Spain) with the aim of evaluating their usefulness within the investigative monitoring defined in the European Union Water Framework Directive (WFD). The highest concentrations of organic contaminants determined in mussels' tissue were detected towards the inner part of the estuary but no gradient pattern was found for metal bioaccumulation. Population fitness responses measured as condition index, stress on stress and gonad index were similar in all caged mussels and did not follow the organic pollution gradient. However, biomarkers determined at tissue, cell and protein level (histopathology, micronuclei frequency, malondialdehyde levels and vitellogenin-like protein levels) revealed a higher stress syndrome at the inner part of the estuary showing signs of genotoxicity, oxidative stress and endocrine disruption. Overall, the integrated chemical–biological approach in connection with mussel caging technique proved to be a useful tool to assess environmental pollution, allowing a better understanding of the cause–effect relationship within the investigative monitoring defined in the WFD. 相似文献
13.
Summary. We investigated the hypothesis that aggregation signals produced by male webbing clothes moths (WCM), Tineola bisselliella (Hum.) (Lepidoptera: Tineidae), and close-range male attractant signals produced by females have a pheromonal basis, at least
in part. Gas chromatographic-electroantennographic detection (GC-EAD) and GC-mass spectrometric analyses of bioactive methanolic
extracts of male WCM disclosed three candidate pheromone components: hexadecanoic acid methyl ester (16:Ester), (Z)-9-hexadecenoic acid methyl ester (Z9—16:Ester), and octadecanoic acid methyl ester (18:Ester). In bioassay experiments in a large Plexiglas™ arena, a blend of
synthetic 16:Ester plus Z9—16:Ester was attractive to male and virgin (but not mated) female WCM; the 18:Ester was inactive.
GC-EAD analyses of pheromone gland extracts from female WCM revealed (E,Z)-2,13-octadecadienal (E2Z13—18:Ald) and (E,Z)-2,13-octadecadienol (E2Z13—18:OH) as candidate sex pheromone components. In arena bioassay experiments, 1—5 female equivalents of synthetic E2Z13—18:Ald (0.2 ng) and E2Z13—18:OH (0.1 ng) were more attractive to male WCM than were two virgin female WCM. We anticipate that the combination of
aggregation and sex pheromones, male-produced sonic aggregation signals, and habitat-derived semiochemicals will be highly
effective in attracting male and female WCM to commercial traps.
Received 12 January 2001; accepted 8 June 2001. 相似文献
14.
Maria A. García-Valiñas Roberto Martínez-Espiñeira Francisco González-Gómez 《Journal of environmental management》2010,91(12):2696-2706
Using information on a basic or “lifeline” level of domestic water use obtained from a water demand function based on a Stone–Geary utility function, a minimum water threshold of 128 m3 per household per year was estimated in a sample of municipalities in Southern Spain. As a second objective, water affordability indexes were then calculated that relate the cost of such lifeline to average municipal income levels. The analysis of the factors behind the differences in that ratio across Andalusian municipalities shows that the relative cost of purchasing the lifeline appears inversely related to average income levels, revealing an element of regressivity in the component of water tariffs affecting the least superfluous part of the household’s consumption. The main policy recommendation would involve redesigning water tariffs in order to improve access for lower income households to an amount of water sufficient to cover their basic needs. The proposed methodology could be applied to other geographical areas, both from developed and from developing countries, in order to analyze the degree of progressivity of the water tariffs currently in effect and in order to guide the design of more equitable regulatory policies. 相似文献
15.
Recycled blocks with improved sound and fire insulation containing construction and demolition waste
Carlos Leiva Jaime Solís-Guzmán Madelyn Marrero Celia García Arenas 《Waste management (New York, N.Y.)》2013,33(3):663-671
The environmental problem posed by construction and demolition waste (C&D waste) is derived not only from the high volume produced, but also from its treatment and disposal. Treatment plants receive C&D waste which is then transformed into a recycled mixed aggregate. The byproduct is mainly used for low-value-added applications such as land escape restoration, despite the high quality of the aggregate. In the present work, the chemical composition properties and grading curve properties of these aggregates are defined. Furthermore, the resulting recycled concrete with a high proportion of recycled composition, from 20% to 100% replacement of fine and coarse aggregate, is characterized physically and mechanically. An environmental study of the new construction material when all aggregates are substituted by C&D waste shows a low toxicity level, similar to that of other construction materials. The new material also has improved properties with respect to standard concrete such as high fire resistance, good heat insulation, and acoustic insulation. 相似文献
16.
María Pía Areal M. Lorena Arciniegas Fernanda Horst Verónica Lassalle Francisco H. Sánchez Vera A. Alvarez Jimena S. Gonzalez 《Journal of Polymers and the Environment》2018,26(8):3129-3138
Scientific and technological researches are devoted to obtain materials capable of retaining different kinds of pollutants, contributing to contamination solutions. In this context, hydrogels have emerged as great candidates because of their excellent absorption properties as well as good mechanical, thermal and chemical properties. More specifically, ferrogels (magnetic gels) present the extra advantage of being easily manipulated by a permanent magnet. Here, we present the results derived from the application of ferrogels as efficient tools to extract heavy metal pollutants from wastewater samples. The gels were prepared following the method of freezing and thawing of a polyvinyl alcohol aqueous solution with magnetic nanoparticles coated with polyacrylic acid. Ferrogels were fully characterized and their ability to retain Cu2+ and Cd2+, as model heavy metals, was studied. Thus kinetics and mechanisms of adsorption were evaluated and modeled. The concentration of MNPs on the PVA matrix was key to improve the adsorption capability (approximately the double of retention is improved by the MNPs addition). The adsorption kinetics was determined as pseudo-second order model, whereas the Langmuir model was the most appropriate to explain the behavior of the gels. Finally reuse ability was evaluated to determine the real potential of these materials, the ferrogels demonstrated high efficiency up to about five cycles, retaining about 80–90% of their initial adsorption capability. All the results indicated that the materials are promising candidates able to compete with the commercial technology regarding to water remediation. 相似文献
17.
Rybová Kristýna Slavík Jan Burcin Boris Soukopová Jana Kučera Tomáš Černíková Alena 《Journal of Material Cycles and Waste Management》2018,20(3):1884-1891
Journal of Material Cycles and Waste Management - Increasing pressure of the European Union on diverting municipal waste from landfills requires an active role of households and commands a radical... 相似文献
18.
Francisca Castilla-Polo M. Isabel Sánchez-Hernández Dolores Gallardo-Vázquez 《Journal of Agricultural and Environmental Ethics》2017,30(1):99-120
The attention to ethics has gradually become a concurrent topic of modern companies’ management. In the last years Social Responsibility has become a key issue in the strategic agenda of competitive agriculture cooperatives. However, reputation management has not been a visible strength in the cooperative enterprises. First of all, this work theoretically analyzes the relationship between Social Responsibility and reputation in cooperatives. Later, from a practical point of view, we carry on an empirical analysis focused on the olive oil cooperatives in the south of Spain, in the province of Jaén. With respect to the previous studies on the topic, this work reveals a main reason of interest reinforcing the role of research in addressing real problems of cooperatives. The article points out the characteristics of this kind of agribusiness and shows the importance of the adoption of a responsible orientation in fostering reputation for creating sustainable competitive advantages. 相似文献
19.
20.
Tomáš Hlásny Ivan Barka Ladislav Kulla Tomáš Bucha Róbert Sedmák Jiří Trombik 《Regional Environmental Change》2017,17(1):65-77
European forestry is facing many challenges, including the need to adapt to climate change and an unprecedented increase in forest damage. We investigated these challenges in a Norway spruce-dominated mountain region in Central Europe. We used the model Sibyla to explore forest biomass production to the year 2100 under climate change and under two alternative management systems: the currently applied management (CM), which strives to actively improve the forest’s adaptive capacity, and no management (NM) as a reference. Because biodiversity is thought to have mostly positive effects on the adaptive capacity of forests and on the quality of ecosystem services, we explored how climate change and management affect indicators of biodiversity. We found a differential response across the elevation-climatic gradient, including a drought-induced decrease in biomass production over large areas. With CM, the support of non-spruce species and the projected improvement of their growth increased tree species diversity. The promotion of species with higher survival rates led to a decrease in forest damage relative to both the present conditions and NM. NM preserved the high density of over-matured spruce trees, which caused forest damage to increase. An abundance of dead wood and large standing trees, which can increase biodiversity, increased with NM. Our results suggest that commercial spruce forests, which are not actively adapted to climate change, tend to preserve their monospecific composition at a cost of increased forest damage. The persisting high rates of damage along with the adverse effects of climate change make the prospects of such forests uncertain. 相似文献