Screening of short- and medium-chain chlorinated paraffins in selected riverine sediments and sludge from the Czech Republic

Wide distribution of chlorinated paraffins in the environment has already been demonstrated in several studies; however, information about their levels in the Central Europe is still very limited. First study focused on the SCCP contamination of the Czech aquatic environment have been performed recently, and its results motivated the authors to analyze sediments from a wide set of the Czech rivers in order to obtain more detailed information. Thirty-six sediment samples from eleven rivers and five drainage vents neighboring the chemical factories were analyzed; special attention was paid to the industrial areas. For the first time in the Czech Republic, medium-chain in addition to short-chain chlorinated paraffins were analyzed using GC-ECNI-MS. Chlorinated paraffins were detected in sediment samples on the concentration levels up to 347 ngg(-1) for short-chain chlorinated paraffins, and 5575 ngg(-1) for medium-chain chlorinated paraffins. Average chlorination degree of SCCPs was 65%.     

Effects of pore volume-transmissivity correlation on transport phenomena

The relevant velocity that describes transport phenomena in a porous medium is the pore velocity. For this reason, one needs not only to describe the variability of transmissivity, which fully determines the Darcy velocity field for given source terms and boundary conditions, but also any variability of the pore volume. We demonstrate that hydraulically equivalent media with exactly the same transmissivity field can produce dramatic differences in the displacement of a solute if they have different pore volume distributions. In particular, we demonstrate that correlation between pore volume and transmissivity leads to a much smoother and more homogeneous solute distribution. This was observed in a laboratory experiment performed in artificial fractures made of two plexiglass plates into which a space-dependent aperture distribution was milled. Using visualization by a light transmission technique, we observe that the solute behaviour is much smoother and more regular after the fractures are filled with glass powder, which plays the role of a homogeneous fault gouge material. This is due to a perfect correlation between pore volume and transmissivity that causes pore velocity to be not directly dependent on the transmissivity, but only indirectly through the hydraulic gradient, which is a much smoother function due to the diffusive behaviour of the flow equation acting as a filter. This smoothing property of the pore volume-transmissivity correlation is also supported by numerical simulations of tracer tests in a dipole flow field. Three different conceptual models are used: an empty fracture, a rough-walled fracture filled with a homogeneous material and a parallel-plate fracture with a heterogeneous fault gouge. All three models are hydraulically equivalent, yet they have a different pore volume distribution. Even if piezometric heads and specific flow rates are exactly the same at any point of the domain, the transport process differs dramatically. These differences make it important to discriminate in situ among different conceptual models in order to simulate correctly the transport phenomena. For this reason, we study the solute breakthrough and recovery curves at the extraction wells. Our numerical case studies show that discrimination on the basis of such data might be impossible except under very favourable conditions, i.e. the integral scale of the transmissivity field has to be known and small compared to the dipole size. If the latter conditions are satisfied, discrimination between the rough-walled fracture filled with a homogeneous material and the other two models becomes possible, whereas the parallel-plate fracture with a heterogeneous fault gouge and the empty fracture still show identifiability problems. The latter may be solved by inspection of aperture and pressure testing.     

Eutrophication of Buttermilk Bay,a cape cod coastal embayment: Concentrations of nutrients and watershed nutrient budgets

Nutrient concentrations in Buttermilk Bay, a coastal embayment on the northern end of Buzzards Bay, MA, are higher in the nearshore where salinities are lower. This pattern suggests that freshwater sources may contribute significantly to nutrient inputs into Buttermilk Bay. To evaluate the relative importance of the various sources we estimated inputs of nutrients by each major source into the watershed and into the bay itself. Septic systems contributed about 40% of the nitrogen and phosphorus entering the watershed, with precipitation and fertilizer use adding the remainder. Groundwater transported over 85% of the nitrogen and 75% of the phosphorus entering the bay. Most nutrients entering the watershed failed to reach the bay; uptake by forests, soils, denitrification, and adsorption intercepted two-thirds of the nitrogen and nine-tenths of the phosphorus that entered the watershed. The nutrients that did reach the bay most likely originated from subsoil injections into groundwater by septic tanks, plus some leaching of fertilizers.Buttermilk Bay water has relatively low nutrient concentrations, probably because of uptake of nutrients by macrophytes and because of relatively rapid tidal flushing. Annual budgets of nutrients entering the watershed showed a low nitrogen-to-phosphorus ratio of 6, but passage of nutrients through the watershed raised N/P to 23, probably because of adsorption of PO₄ during transit. The N/P ratio of water that leaves the watershed and presumably enters the bay is probably high enough to maintain active growth of nitrogenlimited coastal producers. There is a seasonal shift in N/P in the water column of Buttermilk Bay. N/P exceeded the 161 Redfield ratio during midwinter; the remainder of the year N/P fell below 161. This suggests that annual budgets do not provide sufficiently detailed data with which to interpret nutrient-limitation of producers. Further, some idea of water turnover is also needed to evaluate impact of loading rates. Urbanization of watersheds seems to increase loadings to nearshore environments, and to shift the nutrient loadings delivered to coastal waters to relatively high N-to-P ratios, potentially stimulating growth of nitrogen-limited primary producers.     

Change in levels of persistent organic pollutants in human plasma after consumption of a traditional northern Norwegian fish dish-mølje (cod,cod liver,cod liver oil and hard roe)

The traditional northern Norwegian fish dish "m?lje", consisting of boiled cod, cod liver, cod liver oil and hard roe, is still consumed frequently during the winter months January to March. The liver of the cod is rich in lipids and the levels of persistent organic pollutants (POPs) are relatively high. To better understand the short-term consequences of this traditional meal on the plasma levels of PCBs and p,p'-DDE, individual intake of liver and cod liver oil during one meal was measured. Blood samples were collected from 33 participants before the meal, and then 4 h, 12 h and 5 days after it. Lipid-weight and wet-weight levels of 10 PCB congeners and p,p'-DDE were determined in the plasma samples and the food. The plasma levels of p,p'-DDE was found to increase significantly from 0 to 4 h, both when expressed as wet-weight (35% change) and lipid-weight (20% change). The corresponding changes (0-4 h) in wet-weight levels of the most prevalent PCB congeners were non significant. By contrast, PCB congeners with low levels in the food showed a significant drop in lipid-weight levels during the first 4 h. The observed changes were independent of amount consumed. Significant differences in fasting and non-fasting samples were found for most PCBs and p,p'-DDE. For the lipid weight levels of sum PCBs there was a significant decrease of 16% from non-fasting to fasting samples. To obtain reliable data on human levels of POPs it is, on the basis of these findings, recommended that blood samples should be collected from fasting individuals and both wet-weight and lipid-weight levels should be reported.     

Cytotoxicity of gamma irradiated aflatoxin B1 and ochratoxin A

Toxicity of gamma irradiated mycotoxins aflatoxin B₁ (AFB₁) and ochratoxin A (OTA) was investigated in vitro. AFB₁ and OTA stock solutions (50?mM, in methanol) were gamma irradiated (5 and 10 kGy) and non-irradiated and irradiated mycotoxins solutions were tested for cytotoxicity on Pk15, HepG2 and SH-SY5Y cell lines (MTT assay, 1–500?μM concentration range; 24?h exposure). Degradation of mycotoxin molecules was examined by liquid chromatography tandem mass spectrometry (HPLC-MS/MS). AFB₁ and OTA radiolytic products were less toxic than the parent mycotoxins to all of the tested cell lines. Gamma irradiation even at 5 kGy had effect on AFB₁ and OTA molecules however, this effect was dependent on chemical structure of mycotoxin. Since gamma irradiation at low dose reduced initial level of both mycotoxins, and gamma irradiated mycotoxins had lower toxicity in comparison to non-irradiated mycotoxins, it can be concluded that gamma irradiation could be used as decontamination method.     

Treatment of metal (loid) contaminated solutions using iron-peat as sorbent: is landfilling a suitable management option for the spent sorbent?

Environmental Science and Pollution Research - This study firstly aimed to investigate the potential of simultaneous metal (loid) removal from metal (oid) solution through adsorption on iron-peat,...     

Nitrogen mineralization in O horizon soils during 27 years of nitrogen enrichment at the Bear Brook Watershed in Maine,USA

Chronic elevated nitrogen (N) deposition has altered the N status of temperate forests, with significant implications for ecosystem function. The Bear Brook Watershed in Maine (BBWM) is a whole paired watershed manipulation experiment established to study the effects of N and sulfur (S) deposition on ecosystem function. N was added bimonthly as (NH₄)₂SO₄ to one watershed from 1989 to 2016, and research at the site has studied the evolution of ecosystem response to the treatment through time. Here, we synthesize results from 27 years of research at the site and describe the temporal trend of N availability and N mineralization at BBWM in response to chronic N deposition. Our findings suggest that there was a delayed response in soil N dynamics, since labile soil N concentrations did not show increases in the treated watershed (West Bear, WB) compared to the reference watershed (East Bear, EB) until after the first 4 years of treatment. Labile N became increasingly available in WB through time, and after 25 years of manipulations, treated soils had 10× more extractable ammonium than EB soils. The WB soils had 200× more extractable nitrate than EB soils, driven by both, high nitrate concentrations in WB and low nitrate concentrations in EB. Nitrification rates increased in WB soils and accounted for ~?50% of net N mineralization, compared to ~?5% in EB soils. The study provides evidence of the decadal evolution in soil function at BBWM and illustrates the importance of long-term data to capture ecosystem response to chronic disturbance.