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861.
The use of pressure-volume-temperature (PVT) studies in processing of a biodegradable plastic composition made from soy protein
isolate and corn starch is described. The ability of PVT measurements to predict the combined effects of pressure, volume,
and temperature effects is demonstrated. The results show that the PVT relations of the plastic can be predicted by using
a regression analysis similar to the Tait equations of state. A change in slope of the PVT curves was observed at around 80‡C,
which is ascribed to the glass-transition process of the plastic. Evidence of onset of thermal degradation of the plastic
was observed at ca. 160‡C under 0 to 200 MPa isobaric pressure. This thermal degradation precluded determination of the crystal
melting point of the plastic. 相似文献
862.
With the increased use of electric and electronic equipment in our offices, our daily exposure to electromagnetic fields has become increasingly complex due to the great variety of the frequency content of the fields. Today focus has shifted from monitors as the dominating sources of electromagnetic fields to other electronic equipment, cabling, nearby substations, power lines and stray currents in buildings. In the last 5 years wireless communication has become common in our offices. These devices use radio frequency waves to communicate and are therefore sources of radio frequency fields in our offices. To a certain degree, they all add to the complicated issue of the extensive field frequencies found in offices. The exposure of office workers is generally considered to be low and not in conflict with the existing guidelines, but if a precaution approach is applied there are a number of measures that can be taken to reduce the electromagnetic fields in offices in order to obtain a good electrical environment. 相似文献
863.
864.
Jeffrey H. Kahn Kimberly T. Schneider Theresa M. Jenkins‐Henkelman Laura L. Moyle 《组织行为杂志》2006,27(6):793-807
The authors investigated whether the relationship between the contents of emotional social support and job burnout among high‐school teachers is spurious because of the role of dispositional positive and negative affectivity. A national sample of 339 teachers was surveyed via a web‐based procedure. Hierarchical regression analyses did not support spuriousness; emotional social support was uniquely predictive of three dimensions of burnout controlling for affectivity. As positive emotional social support increased, emotional exhaustion and cynicism decreased, and professional efficacy increased. As negative emotional social support increased, emotional exhaustion and cynicism also increased. Commonality analyses based on the present data and data reported by K. L. Zellars and P. L. Perrewé (2001; Journal of Applied Psychology, 86, 459–467) provided additional support for the unique role of emotional social support on burnout, but these analyses suggest a greater role of affectivity than emotional social support. These findings have implications for research on burnout as well as the prevention of burnout among teachers. Copyright © 2006 John Wiley & Sons, Ltd. 相似文献
865.
This study meta‐analyzed the relationships between locus of control (LOC) and a wide range of work outcomes. We categorized these outcomes according to three theoretical perspectives: LOC and well‐being, LOC and motivation, and LOC and behavioral orientation. Hypotheses reflecting these three perspectives were proposed and tested. It was found that internal locus was positively associated with favorable work outcomes, such as positive task and social experiences, and greater job motivation. Our findings are discussed in relation to research on core self‐evaluation and the Big Five personality traits. Copyright © 2006 John Wiley & Sons, Ltd. 相似文献
866.
Aaron I. Packman Andrea Marion Mattia Zaramella Cheng Chen Jean-François Gaillard Denis T. Keane 《Water, Air, & Soil Pollution: Focus》2006,6(5-6):433-442
Hyporheic exchange is known to provide an important control on nutrient and contaminant fluxes across the stream-subsurface
interface. Similar processes also mediate interfacial transport in other permeable sediments. Recent research has focused
on understanding the mechanics of these exchange processes and improving estimation of exchange rates in natural systems.
While the structure of sediment beds obviously influences pore water flow rates and patterns, little is known about the interplay
of typical sedimentary structures, hyporheic exchange, and other transport processes in fluvial/alluvial sediments. Here we
discuss several processes that contribute to local-scale sediment heterogeneity and present results that illustrate the interaction
of overlying flow conditions, the development of sediment structure, pore water transport, and stream-subsurface exchange.
Layered structures are shown to develop at several scales within sediment beds. Surface sampling is used to analyze the development
of an armor layer in a sand-and-gravel bed, while innovative synchrotron-based X-ray microtomography is used to observe patterns
of grain sorting within sand bedforms. We show that layered bed structures involving coarsening of the bed surface increase
interfacial solute flux but produce an effective anisotropy that favors horizontal pore water transport while limiting vertical
penetration. 相似文献
867.
Elvis G. Ngwenya Maud Walsh Caroline A. Metosh‐Dickey Ralph J. Portier 《补救:环境净化治理成本、技术与工艺杂志》2006,16(2):79-90
Biological and physicochemical approaches were utilized in a treatment train for acid mine dis charge (AMD) waters. Anaerobic bioreactors, chemical precipitation reactors, and biopolymer chelation reactors, operated in static, semicontinuous, and continuous flow modes, removed significant quantities of metals and sulfates associated with AMD water. Static tests indicated accept able copper removal via precipitation by generation of hydrogen sulfide in anaerobic reactors. However, low pH affected the biopolymer coating in the chelation reactor, resulting in loss of bed surface. Corrections of AMD to pH > 7 resulted in some metal precipitationprior to biopolymer treatment. A series of static semicontinuous tests at pH 5.0 provided improved metal and sulfate removal. Copper (Cu+) was reduced to trace concentrations, while manganese (Mn+), although reduced, proved to be the most recalcitrant of the metals. © 2006 Wiley Periodicals, Inc. 相似文献
868.
869.
Calculating overpressure from BLEVE explosions 总被引:3,自引:0,他引:3
E. Planas-Cuchi J. M. Salla J. Casal 《Journal of Loss Prevention in the Process Industries》2004,17(6):431-436
Although a certain number of authors have analyzed the prediction of boiling liquid expanding vapour explosion (BLEVE) and fireball effects, only very few of them have proposed methodologies for predicting the overpressure from such explosions. In this paper, the methods previously published are discussed and shown to introduce a significant overestimation due to the erroneous thermodynamic assumptions—ideal gas behaviour and isentropic vapour expansion—on which they are based (in fact, they give the maximum value of overpressure which can be caused by a BLEVE). A new approach is proposed, based on the—more realistic—assumption of an adiabatic and irreversible expansion process; the real properties of the substance involved in the explosion are used. The two methods are compared through the application to a given case. 相似文献
870.
T. D. Blackall M. R. Theobald C. Milford K. J. Hargreaves E. Nemitz L. J. Wilson J. Bull P. J. Bacon K. C. Hamer S. Wanless M. A. Sutton 《Water, Air, & Soil Pollution: Focus》2004,4(6):279-285
Ammonia emissions from two contrasting seabird colonies in Scotland were measured, based on the determination of atmospheric concentrations downwind of the colonies. Atmospheric concentrations of ammonia (NH3) across the downwind plume were compared with the inverse application of a Gaussian dispersion model (ID) to calculate the modelled NH3 emission that would generate the measured cross-wind-integrated plume concentration. In parallel, a tracer gas (sulphur hexafluoride, SF6) was released from the colonies with air samples taken to allow determination of SF6 concentrations. On the basis of the known emission rate of SF6, the magnitude of ammonia emissions was estimated by the cross-wind-integrated tracer ratio (TR) of NH3/SF6 concentrations. Coupled with data on annual bird attendance, the measurements indicate annual emissions from the Isle of May and the Bass Rock of 18 and 132 tonnes NH3-N year–1, respectively. The measured NH3 emissions were compared with estimates of seabird nitrogen excretion to estimate the proportion of excreted N that is volatilised as NH3 (FNr). The emission estimates of the two methods compared favourably, giving 4 and 6 kg NH3-N h–1 (FNr = 15%) for the Isle of May for the ID and TR methods, respectively, and 21 and 25 kg NH3-N h–1 (FNr = 50%) for the Bass Rock for the ID and TR methods, respectively. The results provide the first measurement-based estimates to allow regional up scaling of ammonia emissions from seabirds. 相似文献