Higher intrinsic photocatalytic efficiency of 2,4,6-triphenylpyrylium-based photocatalysts compared to TiO2 P-25 for the degradation of 2,4-dichlorophenol using solar simulated light

The photocatalytic efficiency of two 2,4,6-triphenylpyrylium (TP(+)) based photocatalysts (supported on silica or incorporated inside zeolite Beta, 3wt%) for the degradation of 2,4-dichlorophenol (DCP) in aqueous media has been compared with TiO(2) (Degussa P-25). It was found that the efficiency of the degradation depends on the photocatalytic setup, recirculation through a tubular reactor being highly unfavorable for the TP(+)-based photocatalysts due to the deposition of the silica or zeolite particles. In contrast, high efficiency in DCP disappearance (up to 87%) and in the total organic content decrease (up to 62%) were obtained using a discontinuous batch reactor in which the TP(+) photocatalysts were uniformly suspended. Kinetic studies were also made and DCP degradation follows a first order kinetics. The obtained kinetic constants when corrected to account for the influence of the fraction of light absorbed and the amount of active sites shows that the intrinsic activity of TP(+) adsorbed on silica or incorporated inside zeolite Beta was over one order of magnitude higher than TiO(2) activity.     

Eutrophication and Sedimentation Patterns in Complete Exploitation of Water Resources Scenarios: An Example from Northwestern Semi-arid Mexico

Water requirements to supply human needs lead water stakeholders to store more water during surplus periods to fulfil the demand during – not only – scarcity periods. At the reservoirs, mostly those in semi-arid regions, water level then fluctuates extremely between rises and downward during one single year. Besides of water management implications, changes on physical, chemical and biological dynamics of these drawdown and refilling are little known yet. This paper shows the results, throughout a year, on solids, nutrients (N and P), chlorophyll-a, and sedimentation changes on the dynamics, when the former policy was applied in a reservoir from the semi-arid Northwestern Mexico. Water level sinusoidal trend impinged changes on thermal stratification and mixing, modifying nutrient cycling and primary producer responses. According to nitrogen and phosphorus concentration as well as chlorophyll-a, reservoir was mesotrophic, becoming hypertrophic during drawdown. Nutrient concentrations were high (1.22 ± 0.70 and 0.14 ± 0.12 mg P l⁻¹), increasing phosphorus and lowering N:P significantly throughout the study period, although no intensive agricultural, no urban development, neither industrial activities take place in the watershed. This suggests nutrient recycling complex mechanisms, including nutrient release from the sediment–water interface as the main nutrient pathway when shallowness, at the same time as mineralization, increases. Outflows controlled nitrogen and phosphorus availability on the ecosystem while organic matter depended on river inflows. As on other subtropical aquatic ecosystems, nitrogen limited primary productivity (Spearman correlation R = 0.75) but chlorophyll-a seasonal pattern showed an irregular trend, prompting other no-nutrient related limitants. Shallowness induced a homogeneous temporal pattern on water quality. This observed temporal variability was mainly explained statistically by changes on solids (mineral and organic), chlorophyll-a and flows (62.3%). Annual sedimentation rates of total solids ranged from 11.73 to 16.29 kg m⁻² year⁻¹ with organic matter comprising around 30%. N:P ratio on sedimentation rates were as high as could be expected in a resuspension dominated ecosystem, and spatially inverse related with N:P ratio on bottom sediments. Distance from river inlet into the reservoir reveals a marked spatial heterogeneity on solid and nitrogen sedimentation, showing the system dependence on river inflows and supporting resuspension as the main phosphorus pathway. Accretion rates (2.19 ± 0.40 cm year⁻¹) were not related to hydrological variability but decreased with the distance to the river input. Total sediment accumulation (9,895 tons km⁻² year⁻¹) denotes siltation as other serious environmental problem in reservoirs but possibly not related with operational procedures.     

Effect of Watershed Subdivision and Filter Width on SWAT Simulation of a Coastal Plain Watershed1

Cho, Jaepil, Richard R. Lowrance, David D. Bosch, Timothy C. Strickland, Younggu Her, and George Vellidis, 2010. Effect of Watershed Subdivision and Filter Width on SWAT Simulation of a Coastal Plain Watershed. Journal of the American Water Resources Association (JAWRA) 46(3):586-602. DOI: 10.1111/j.1752-1688.2010.00436.x Abstract: The Soil and Water Assessment Tool (SWAT) does not fully simulate riparian buffers, but has a simple filter function that is responsive to filter strip width (FILTERW). The objectives of this study were to (1) evaluate SWAT hydrology and water quality response to changes in watershed subdivision levels and different FILTERW configurations and (2) provide guidance for selecting appropriate watershed subdivision for model runs that include the riparian buffer feature through the FILTERW parameter. Watershed subdivision level is controlled by the critical source area (CSA) which defines the minimum drainage area required to form the origin of a stream. SWAT was calibrated on a 15.7 km² subdrainage within the Little River Experimental Watershed, Georgia. The calibrated parameter set was applied to 32 watershed configurations consisting of four FILTERW representations for each of eight CSA levels. Streamflow predictions were stable regardless of watershed subdivision and FILTERW configuration. Predicted sediment and nutrient loads from upland areas decreased as CSA increased when spatial variations of riparian buffers are considered. Sediment and nutrient yield at the watershed outlet was responsive to different combinations of CSA and FILTERW depending on selected in-stream processes. CSA ranges which provide stable sediment and nutrient yields at the watershed outlet was suggested for avoiding significant modifications in selected parameter set.     

Diclofenac photodegradation with the Perovskites BaFeyTi1-yO3 as catalysts

Environmental Science and Pollution Research - Perovskite oxides BaFeyTi1-yO3, with y = 0, 0.6, 0.8 and 1, were prepared by ceramic (CM) and complex polymerization methods (CPM) and utilized in...     

Arsenic and trace metals in river water and sediments from the southeast portion of the Iron Quadrangle, Brazil

The Iron Quadrangle has been one of the most important gold production regions in Brazil since the end of the seventeenth century. There, arsenic occurs in close association with sulfide-rich auriferous rocks. The most abundant sulfide minerals are pyrite and arsenopyrite, yet trace metal sulfides occur in subordinate phases as well. Historical mining activities have been responsible for the release of As and trace metals to both aquatic and terrestrial environments close to mining sites in the region. Therefore, this study was aimed to evaluate the distribution and mobility of As, Cd, Co, Cr, Cu, Ni, Pb, and Zn in streams in the southeast portion of the Iron Quadrangle between the municipalities of Ouro Preto and Mariana, the oldest Brazilian Au mining province. Total concentrations of some trace metals and arsenic in water were determined. The four-stage sequential extraction procedure proposed by the commission of the European Communities Bureau of Reference (BCR) was used to investigate the distribution of these elements in stream sediments. Arsenic concentration in water was >10 ??g L^???1 (maximum limit permitted by Brazilian environmental regulations for water destined for human consumption) at all sampling sites, varying between 36.7 and 68.3 ??g L^???1. Sequential extraction in sediments showed high concentrations of As and trace metals associated with easily mobilized fractions.     

An indicator tool for assessing local vulnerability to climate change in the Mexican agricultural sector

To propose specific adaptation strategies in the agricultural sector based on vulnerability to climate variability and climate change at the local level, we built a vulnerability index using an indicator tool at a fine spatial scale. This index was applied as a case study in the municipality of Guasave, Sinaloa, Mexico, at the basic census area (BCA) level. We used a total of 37 variables organized into three groups with equal weighting: exposure (13), sensitivity (13), and adaptive capacity (11). From the 20 rural BCAs located in the study area, eight were categorized as having very low vulnerability; five had low vulnerability; two had medium vulnerability because of the lack of basic services (sewers, water, and electricity) and a high rural population density; three had high vulnerability due to a high frequency of days with temperatures below 5 °C and the lack of basic services; and two had very high vulnerability, characterized by a high percentage of production units (PUs) with losses due to climate factors, a high rural population density, and a high frequency of days with temperatures below 5 °C. Approximately 50 % of the municipal rural population lives in BCAs vulnerable to climate change. This methodology allowed us to identify the most susceptible agricultural areas at the local level and the variables that require more attention so that we can propose adaptation strategies and minimize vulnerability due to climate change.     

Assessment of a Portable Handheld UV Light Device for the Disinfection of Viruses and Bacteria in Water

Effective individual microbiological water purifiers are needed for consumption of untreated water sources by campers, emergency use, military, and in developing counties. A handheld UV light device was tested to assess if it could meet the virus reduction requirements established by the United State Environmental Protection Agency, National Science Foundation and the World Health Organization. The device was found capable of inactivating at least 4 log₁₀ of poliovirus type 1, rotavirus SA-11 and MS-2 virus in 500 mL volumes of general case test water. But in the presence of high turbidity and organic matter, filtration was necessary to achieve a 4 log₁₀ reduction of the test viruses.     

Trophic structure of fish communities in mangrove systems subject to different levels of anthropogenic intervention,Tropical Eastern Pacific,Colombia

Environmental Science and Pollution Research - Mangroves are important ecosystems of tropical and subtropical shorelines. Anthropogenic activity decreases their habitat quality, affecting...     

Ultrastructural, Morphological, and Antifungal Properties of Micro and Nanoparticles of Chitosan Crosslinked with Sodium Tripolyphosphate

Recent studies have demonstrated the antibacterial effect of micro and nanoparticles of chitosan (CS) crosslinked with sodium tripolyphosphate (TPP), and incorporating metallic ions, bringing that the size, shape, and zeta potential are related to the antimicrobial potential. However, there are few studies on the antifungal activity and the effect of TPP on the antimicrobial potential. Micro and nanoparticles were prepared from CS by ionotropic gelation with TPP, and structurally characterized by transmission and scanning electron spectroscopy, and Fourier transformed infrared spectroscopy. Depending on the concentration of CS and TPP, spherical particles were obtained from 80 nm to 20 μm. Subsequently, particles were evaluated for their antifungal potential against Aspergillus parasiticus assessing radial growth, spore germination, and morphological changes. An increase in the antifungal potential compared with CS in solution was observed, inhibiting the development of the fungus causing clear morphological changes in both, hyphae and spores. Particle size and the availability of functional groups of CS/TPP (amino group and phosphate), suggest a possible synergistic effect between CS and TPP.