Spectral Analysis of Chemical Time Series from Long-Term Catchment Monitoring Studies: Hydrochemical Insights and Data Requirements

Hydrological and hydrochemical data from long-term monitoring stations are vital for inferring travel times and flowpaths of water, and transport of contaminants through catchments. Spectral analysis is particularly powerful for studying the hydrological and chemical dynamics of catchments across a wide range of time scales. Here, recent work is reviewed that illustrates how spectral analyses of long-term monitoring data can be used to infer the travel-time distribution of water through catchments, and to measure the chemical retardation of reactive solutes at the catchment scale. For spectral analysis, it is desirable to have data sets with high sampling frequency and long periods of coverage. Using two data sets, a 3-yr daily data series and a 17-yr weekly data series from the Hafren catchment at Plynlimon, Wales, we demonstrate that high-frequency sampling (e.g., daily or more frequent) is particularly useful for revealing the short-term chemical dynamics that most clearly reflect the interplay of subsurface chemical and hydrological processes. However, data sets that combine high-frequency sampling during storm events with low-frequency sampling between storms can cause spectral artifacts and must be treated with special care.     

REVIVING URBAN STREAMS: LAND USE,HYDROLOGY, BIOLOGY,AND HUMAN BEHAVIOR1

ABSTRACT: Successful stream rehabilitation requires a shift from narrow analysis and management to integrated understanding of the links between human actions and changing river health. At study sites in the Puget Sound lowlands of western Washington State, landscape, hydrological, and biological conditions were evaluated for streams flowing through watersheds with varying levels of urban development. At all spatial scales, stream biological condition measured by the benthic index of biological integrity (B‐IBI) declined as impervious area increased. Impervious area alone, however, is a flawed surrogate of river health. Hydrologic metrics that reflect chronic altered streamflows, for example, provide a direct mechanistic link between the changes associated with urban development and declines in stream biological condition. These measures provide a more sensitive understanding of stream basin response to urban development than do treatment of each increment of impervious area equally. Land use in residential backyards adjacent to streams also heavily influences stream condition. Successful stream rehabilitation thus requires coordinated diagnosis of the causes of degradation and integrative management to treat the range of ecological stressors within each urban area, and it depends on remedies appropriate at scales from backyards to regional storm water systems.     

Herbicide loading to shallow ground water beneath Nebraska's Management Systems Evaluation Area

Better management practices can counter deterioration of ground water quality. From 1991 through 1996 the influence of improved irrigation practices on ground water pesticide contamination was assessed at the Nebraska Management Systems Evaluation Area. Three 13.4-ha corn (Zea mays L.) fields were studied: a conventional furrow-irrigated field, a surge-irrigated field and a center pivot-irrigated field, and a center pivot-irrigated alfalfa (Medicago sativa L.) field. The corn fields received one identical banded application of Bicep (atrazine [6-chloro-N-ethyl-N'-(1-methylethyl)-1,3,5-triazine-2,4,-diamine] + metolachlor [2-chloro-N-(2-ethyl-6-methylphenyl)-N-(2-methoxy-1-methylethyl) acetamidel) annually; the alfalfa field was untreated. Ground water samples were collected three times annually from 16 depths of 31 multilevel samplers. Six years of sample data indicated that a greater than 50% reduction in irrigation water on the corn management fields lowered average atrazine concentrations in the upper 1.5 m of the aquifer downgradient of the corn fields from approximately 5.5 to <0.5 microg L(-1). Increases in deethylatrazine (DEA; 2-chloro-4-amino-6-isopropylamino-s-triazine) to atrazine molar ratios indicated that reducing water applications enhanced microbial degradation of atrazine in soil zones. The occurrence of peak herbicide loading in ground water was unpredictable but usually was associated with heavy precipitation within days of herbicide application. Focused recharge of storm runoff that ponded in the surge-irrigated field drainage ditch, in the upgradient road ditch, and at the downgradient end of the conventionally irrigated field was a major mechanism for vertical transport. Sprinkler irrigation technology limited areas for focused recharge and promoted significantly more soil microbial degradation of atrazine than furrow irrigation techniques and, thereby, improved ground water quality.     

Modelling trends in woody vegetation structure in semi-arid Australia as determined from aerial photography

Accounting of carbon stocks in woody vegetation for greenhouse purposes requires definition of medium term trends with accurate error assessment. Tree and shrub cover was sampled through time at randomly located sites over a large area of central Queensland, Australia using aerial photography from 1945 to 1999. Calibration models developed from field data for the same land types as those represented within the study area allowed for the extrapolation of overstorey and understorey cover, basal area and biomass values and these were modelled as trends over the latter half of the 20th century. These structural attributes have declined over the region because of land clearing with values for biomass changing from a mean of 58.0(+/-1.2)t/ha in 1953 to 41.1(+/-1.0)t/ha in 1991. The biomass of Acacia on clay and Eucalypt on texture contrast soils land types has declined most dramatically. Within uncleared vegetation there was an overall trend of increase from 56.1(+/-1.2)t/ha in 1951 to 67.6(+/-1.3)t/ha in 1995. The increase in structural attributes within uncleared vegetation was most pronounced for the Eucalypt on texture contrast soils and Eucalypt on clay land types. It was demonstrated that the sites sampled were representative of their land types and that spatial bias of the photography, undetected tree-killing, sampling error, inherent variability of structural attributes and measurement error should not have impacted greatly on bias or precision of trend estimates for well-sampled land types. Certainly the errors are not likely to be substantial for trends averaged over all land types and they provide an accurate assessment of the magnitude and direction of change. The technique presented here would appear to be a robust means of accounting for the above-ground woody component of woodlands and open forests and will also contribute to a broader understanding of savanna dynamics.     

Elements of resilience after the World Trade Center disaster: reconstituting New York City's Emergency Operations Centre

In this paper we examine the reconstitution of the Emergency Operations Centre (EOC) after its destruction in the World Trade Center attack, using that event to highlight several features of resilience. The paper summarises basic EOC functions, and then presents conceptions of resilience as understood from several disciplinary perspectives, noting that work in these fields has sought to understand how a natural or social system that experiences disturbance sustains its functional processes. We observe that, although the physical EOC facility was destroyed, the organisation that had been established to manage crises in New York City continued, enabling a response that drew on the resources of New York City and neighbouring communities, states and the federal government. Availability of resources--which substituted for redundancy of personnel, equipment and space--pre-existing relationships that eased communication challenges as the emergency developed and the continuation of organisational patterns of response integration and role assignments were among the factors that contributed to resilience following the attack.     

Fuzzy decision analysis for integrated environmental vulnerability assessment of the mid-Atlantic Region

A fuzzy decision analysis method for integrating ecological indicators was developed. This was a combination of a fuzzy ranking method and the analytic hierarchy process (AHP). The method was capable of ranking ecosystems in terms of environmental conditions and suggesting cumulative impacts across a large region. Using data on land cover, population, roads, streams, air pollution, and topography of the Mid-Atlantic region, we were able to point out areas that were in relatively poor condition and/or vulnerable to future deterioration. The method offered an easy and comprehensive way to combine the strengths of fuzzy set theory and the AHP for ecological assessment. Furthermore, the suggested method can serve as a building block for the evaluation of environmental policies.     

Environmental Values and Popular Conflict over Environmental Management: A Comparative Analysis of Public Comments on the Clinton Forest Plan

/ Public participation in environmental management decisions has frequently led to conflict. This paper examines the role of environmental values in fueling these conflicts, based on a data base and sample content analysis of written public comments solicited in 1994 regarding the highly contentious Clinton Forest Plan (also known as Option 9) proposed for management of federal forests in the US Pacific Northwest. The analysis considered whether those respondents favoring more versus less environmental protection than was offered in Option 9 held entirely different values, identifying which antagonistic values appeared to be most fundamental and where (if at all) values consensus occurred. It also compared values emanating from respondents within and outside the affected region, although few major differences were detected in this regard. Results suggest that strong values differences did exist among those preferring greater versus less environmental protection, in particular as concerned the extent, form, and spatial and temporal scope of justification of their positions, their ideas of forests, and the appropriate role of people in forest management. Disagreement concerned far more than purely environmental values: a major point of difference involved human benefits and harms of the proposed forest plan. Indeed, both sides' positions were overridingly anthropocentric and consequentialist-a values orientation that almost inevitably spells conflict in light of the commonly differentiated social impacts of environmental management decisions. Although public involvement in environmental management thus cannot be expected to lead to a clear and consensual social directive, the Pacific Northwest case suggests that viable environmental management solutions that take this range of values into account can still be crafted.KEY WORDS: Environmental values; Public participation; Clinton Forest Plan; Pacific Northwest     

The pedagogy of atmospheric issues and the UK Atmospheric Research and Information Centre's Education Programme

Mrs Sue Hare is the education and information services coordinator of the UK Atmospheric Research and Information Centre (ARIC). Professor James Longhurst was recently the director of the ARIC and Joe Buchdahl its global climate change information services coordinator. Professor Longhurst is now head of the Department of Environmental Health and Science, University of the West of England, Frenchay Campus, Coldharbour Lane, Bristol BS16 1QY. Kelvin Williams is a geography consultant and is head of geography at Ysgol y Creuddyn, Penrhyn Bay, Llandudno, Gwynedd LL30 3LB. The pedagogy of atmospheric issues is identified in the context of environmental education in this paper. The UK Atmospheric Research and Information Centre (ARIC) has developed an education programme which has responded to the dynamic issues relating to the atmosphere since the establishment of the ARIC in 1984. The main route for the teaching of atmospheric issues is identified as being through the UK's National Curriculum although public awareness of issues has increased through the media and more recently through government publicity campaigns.