Water quality index applied to rivers in the Vistula river basin in Poland

Summary A new method of a water quality index has been proposed. The unit indices were determined from the values of individual parameters using continuous functions. The base for such functions were the four water quality classes used in Poland. The summarized WQI is the square root of the harmonic mean of squares of unit indices. Using this mean we have eliminated the use of weights of parameters. Parameters are divided into basic parameters (7) and other additional parameters (19). The additional parameter is considered only if its unit index is lower than WQI from basic parameters. For many measurements at one point the guaranteed WQI has been calculated. The points of WQI were connected and the curves of WQI along the river were obtained.A method of WQI calculating and preparation of WQI curves has been shown using as an example the Pilica river in Poland. The WQI was then calculated for 31 rivers in the Vistula river basin by measuring points.     

National GHG inventories: Recent developments under the IPCC/OECD Joint Programme

This paper summarises key results of the Joint IPCC/OECD Programme, in particular the draft IPCC Guidelines for National GHG Inventories to be released in January 1994. The focus is on how these results are likely to improve the availability and the quality of national inventories of anthropogenic GHG emission sources and removals by sinks. The IPCC/OECD has already received nearly 50 inventories from 35 countries. Most of the data are for 1988, but some reports cover 1989 and 1990. In addition to CO₂, many of these inventories include CH₄, N₂O, NOx, CO, and NMVOC. Detailed analyses of these inventories have provided valuable insights about the strengths and weaknesses of the national inventories, differences in approach to estimation, reporting, available methods and data. These results in turn, have facilitated the development of the draft Guidelines, most notably the proposed reporting system, and also on estimation methods for the different anthropogenic sources and sinks of GHG. The paper previews key aspects of the draft Guidelines for non-CO₂ GHG. Experts are urged to actively participate in the IPCC/OECD Programme to continue to improve inventory methods and overall the Guidelines.The views presented in this paper are those of the authors and do not necessarily represent the views of the OECD or their Member countries.     

Nitrous oxide emissions from waste water

The estimation of nitrous oxide emissions is complicated by the high degree of uncertainty on the emission factors involved and by the limited acquaintance with all significant nitrous oxide sources. A potentially important source for which emission data are lacking is the sewage system transporting waste water from human activities. For this study an experimental measurement campaign has been carried out on waste water sampled at different sewage treatment plants. The nitrous oxide developing from the water samples was monitored by means of gas chromatography. The methodological analysis was based on the concentration/time curves obtained. Our results indicate that the formation of nitrous oxide from the waste water matrices results from microbiological denitrification. We deduced tentative emission factors for the waste water types studied.     

Comparison of methods for leaching heavy metals from composts

This paper presents the determination of total iron, copper, zinc, chromium, nickel, lead, cadmium and mercury contents in the compost obtained from sorted municipal organic solid waste applying the following methods of sample mineralization: 40% hydrofluoric acid with preliminary incineration of a sample, a mixture of concentrated nitric(V) and chloric(VII) acids with preliminary incineration of organic matter and a mixture of nitric(V) and chloric(VII) acids without sample incineration. The speciation analysis of Tessier was used to estimate the bioavailability of the metals. Elution degrees of the mobile forms of the metals from the compost with 10% nitric(V) acid and 1 mol/dm(3) hydrochloric acid were compared. The contents of the elements in the eluates were determined applying atomic absorption spectrometry.     

The asteroid and comet impact hazard: risk assessment and mitigation options

The impact of extraterrestrial matter onto Earth is a continuous process. On average, some 50,000 tons of dust are delivered to our planet every year. While objects smaller than about 30 m mainly disintegrate in the Earth’s atmosphere, larger ones can penetrate through it and cause damage on the ground. When an object of hundreds of meters in diameter impacts an ocean, a tsunami is created that can devastate coastal cities. Further, if a km-sized object hit the Earth it would cause a global catastrophe due to the transport of enormous amounts of dust and vapour into the atmosphere resulting in a change in the Earth’s climate. This article gives an overview of the near-Earth asteroid and comet (near-Earth object-NEO) impact hazard and the NEO search programmes which are gathering important data on these objects. It also points out options for impact hazard mitigation by using deflection systems. It further discusses the critical constraints for NEO deflection strategies and systems as well as mitigation and evacuation costs and benefits. Recommendations are given for future activities to solve the NEO impact hazard problem.     

Environmental pollutants in endangered vs. increasing subspecies of the lesser black-backed gull on the Norwegian Coast

Organochlorine (OC) residues were measured in eggs and blood of different subspecies of the lesser black-backed gull, Larus fuscus, on the Norwegian coast: a) increasing L. f. intermedius in the North Sea; b) endangered L. f. fuscus near the Arctic Circle; c) L. f. fuscus and greyish-mantled gulls, with a L. f. intermedius appearance, in the Barents Sea region. The dominating OCs in lesser black-backed gulls were polychlorinated biphenyls (PCB) and p,p'-dichlorodiphenyldichloroethylene (DDE). DDE and beta-hexachlorocyclohexane (beta-HCH) residues were higher in L. f. fuscus compared to L. f. intermedius and greyish-mantled birds in the Barents Sea region. In the latter area, blood residues of PCB and DDE in lesser black-backed gulls were as high as in great black-backed gulls, Larus marinus, while in the other regions they were lower. The higher DDE residues in endangered L. f. fuscus compared to increasing L. f. intermedius and greyish-mantled birds, which are invading northern Norway, suggest that OCs may have played a role in the population decline of L. f. fuscus, possibly in combination with nutrient stress.     

Model estimation and measurement of ammonia emission from naturally ventilated dairy cattle buildings with slatted floor designs

Laboratory experiments were carried out in a wind tunnel with a model of a slurry pit to investigate the characteristics of ammonia emission from dairy cattle buildings with slatted floor designs. Ammonia emission at different temperatures and air velocities over the floor surface above the slurry pit was measured with uniform feces spreading and urine sprinkling on the surface daily. The data were used to improve a model for estimation of ammonia emission from dairy cattle buildings. Estimates from the updated emission model were compared with measured data from five naturally ventilated dairy cattle buildings. The overall measured ammonia emission rates were in the range of 11-88 g per cow per day at air temperatures of 2.3-22.4 degrees C. Ammonia emission rates estimated by the model were in the range of 19-107 g per cow per day for the surveyed buildings. The average ammonia emission estimated by the model was 11% higher than the mean measured value. The results show that predicted emission patterns generally agree with the measured one, but the prediction has less variation. The model performance may be improved if the influence of animal activity and management strategy on ammonia emission could be estimated and more reliable data of air velocities of the buildings could be obtained.     

Carbon turnover and ammonia emissions during composting of biowaste at different temperatures

The effects of different process temperatures (40, 55, and 67 degrees C) during composting of source-separated household waste were studied in a 200 L compost reactor at an oxygen concentration of 16%. The overall decomposition measured as carbon mineralization, decomposition of different carbon constituents, and the dynamics of nitrogen mineralization and the microbial community, are reported. Ammonia emissions at 67 degrees C were more than double those at lower temperatures, and they were lowest at 40 degrees C. The decomposition rate, measured as CO2 emission, was highest at 55 degrees C. Decomposition of crude fat was slower at 40 degrees C than at 55 and 67 degrees C. The peak in microbial biomass was largest in the run at 40 degrees C, where substantial differences were seen in the microbial community structure and succession compared to thermophilic temperatures. Biowaste composting can be optimized to obtain both a high decomposition rate and low ammonia emissions by controlling the process at about 55 degrees C in the initial, high-rate stage. To reduce ammonia emissions it seems worthwhile to reduce the temperature after an initial high-temperature stage.     

From the Editors

Editorial Introduction

From the Editors     

Characterisation of potentially genotoxic compounds in sediments collected from United Kingdom estuaries

The mutagenic activity bioassay Mutatox was used to assess the mutagenic activity associated with sediments collected from five UK estuaries. Assays were performed on extracts of sediment pore water and residual particulate material isolated from sediment samples collected from the rivers Tyne, Tees, Mersey, and Thames as well as Southampton Water. No mutagenic activity was associated with the pore water extracts, however, 7 of the 28 organic solvent extracts of sediment particulate material contained potential genotoxins. By using Mutatox in association with bioassay-directed fractionation, attempts were made to identify the mutagenic compounds present in the extracts. The fractionation procedure used normal phase solid phase extraction, C18 reverse phase HPLC and cyano/amino bonded silica normal phase HPLC. GC-MS (EI and NICI) analysis was used to identify polycyclic aromatic hydrocarbons (PAH), alkyl substituted PAH, nitro-polycyclic aromatic compounds (nitro-PACs), polycyclic aromatic ketones, oxygenated-PACs, and other known mutagens contributing to the genotoxicity measured in the samples. Some potentially genotoxic compounds remain unidentified.