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51.
Andreas Züttel 《Mitigation and Adaptation Strategies for Global Change》2007,12(3):343-365
Hydrogen storage and transportation or distribution is closely linked together. Hydrogen can be distributed continuously in
pipelines or batch wise by ships, trucks, railway or airplanes. All batch transportation requires a storage system but also
pipelines can be used as pressure storage system. Hydrogen exhibits the highest heating value per weight of all chemical fuels.
Furthermore, hydrogen is regenerative and environment friendly. There are two reasons why hydrogen is not the major fuel of
toady’s energy consumption: First of all, hydrogen is just an energy carrier. And, although it is the most abundant element
in the universe, it has to be produced, since on earth it only occurs in the form of water. This implies that we have to pay
for this energy, which results in a difficult economic task, because since the industrialization we are used to consuming
energy for free. The second difficulty with hydrogen as an energy carrier is the low critical temperature of 33 K, i.e. hydrogen
is a gas at room temperature. For mobile and in many cases also for stationary applications the volumetric and gravimetric
density of hydrogen in a storage system is crucial. Hydrogen can be stored by six different methods and phenomena: high pressure
gas cylinders (up to 800 bar), liquid hydrogen in cryogenic tanks (at 21 K), adsorbed hydrogen on materials with a large specific
surface area (at T < 100 K), absorbed on interstitial sites in a host metal (at ambient pressure and temperature), chemically bond in covalent
and ionic compounds (at ambient pressure), oxidation of reactive metals e.g. Li, Na, Mg, Al, Zn with water. These metals easily
react with water to the corresponding hydroxide and liberate the hydrogen from the water. Finally, the metal hydroxides can
be thermally reduced to the metals in a solar furnace. 相似文献
52.
FUENSANTA CARAVACA DINO FIGUEROA ANTONIO ROLDÁn CONCEPCIÓN AZCÓN-AGUILAR 《Environmental management》2003,31(3):0412-0420
The reestablisment of autochthonous plant species is an essential strategy for recovering degraded areas under semiarid conditions.
A field experiment was carried out to assess the short-term effect of two reafforestation methods involving mycorrhizal inoculation
and compost addition on soil quality parameters and Rhamnus lycioides seedling growth. The nutrient content (NPK) and enzymatic activities (dehydrogenase, urease, protease-BAA, acid phosphatase
and β-glucosidase) increased and bulk density decreased in the rhizosphere soil with the organic amendment. Biomass C of rhizosphere
soil increased by at least 240% with respect to the control soil after mycorrhizal inoculation and the combination of compost
addition + mycorrhizal inoculation. Both mycorrhizal inoculation and composted organic residue addition increased R. lycioides seedling growth in the same proportion. In the short term, we conclude that the application of both reafforestation methods
not only enhances the establishment of R. lycioides seedlings, but also improves soil quality. 相似文献
53.
Devendra Kumar Agrawal Prasanna Kumar Samal Nehal Ahmed Farooquee Lok Man Singh Palni 《The Environmentalist》2003,23(1):39-47
The Indian Himalayan Region (IHR) is suffering from environmental degradation due to population pressure and infra-structural needs. This is coupled with a natural setting, which creates problems of accelerated soil erosion and mass wasting. In view of these environmental difficulties and the growing concern for effective restoration, there has become an urgent need for multi-disciplinary coordinated improvement schemes. The mitigation of risk arising from hazardous mass wasting processes, through a careful and systematic approach, has helped in the development of the concept of Mountain Risk Engineering (MRE). The MRE practices involve an integrated approach to solving the infra-structural engineering problems of hilly and mountainous areas through environmentally conscious cost-effective and site-specific designs. However, the role of people's participation is extremely crucial for the success of such programs. This paper analyzes the perception of the local people about the approaches adopted in MRE participatory developmental programs and throws light on the intricacies of peoples' participation. 相似文献
54.
Seasonal variation in heavy metal contamination in water and sediments of river Sabarmati and Kharicut canal at Ahmedabad, Gujarat 总被引:3,自引:0,他引:3
Rita N. Kumar Rajal Solanki J. I. Nirmal Kumar 《Environmental monitoring and assessment》2013,185(1):359-368
The objective of the study is to reveal the seasonal variations in the river water and sediment quality with respect to heavy metal contamination. To get the extent of trace metals contamination, water and sediment samples were collected from five different sites along the course of Sabarmati River and its tributary Kharicut canal in pre-monsoon, monsoon and post-monsoon seasons. The concentration of trace metals such as chromium, copper, lead, nickel and zinc was determined using inductively coupled plasma spectroscopy. The concentrations of heavy metals were found to be higher in the pre-monsoon season than in the monsoon and post-monsoon seasons in water samples. The pollution load index, contamination factor and degree of contamination (C d) in sediments were calculated to know the extent of anthropogenic pressures. The values of C d clearly indicated very high degree of contamination at Kharicut canal (S-4: 32.25 and S-5: 54.52) and considerable degree of contamination at three sites of Sabarmati river viz; S-1, S-2 and S-3 with values 14.30, 14.42 and 17.21, respectively. Lead and nickel could not be traced in any of the river water samples. 相似文献
55.
Variations between rice cultivars in root secretion of organic acids and the relationship with plant cadmium uptake 总被引:13,自引:0,他引:13
To attempt to understand certain mechanisms causing the variations between rice cultivars with regard to Cd uptake and accumulation,
pot soil experiments were conducted with two rice cultivars at different levels of Cd, i.e., 0 (the control), 10, 50 mg Cd
kg−1 soil. The two rice cultivars differ significantly with regard to Cd uptake and accumulation. Root secretions of low-molecular-weight
organic acids (LMWOA) for each treatment were measured with ion chromatography. The results showed that LMWOA concentrations
in the soil planted with Shan you 63 (a high soil Cd accumulator) were all higher than those in the soil planted with Wu yun jing 7 (low soil Cd accumulator) at different soil Cd levels, although the magnitudes of the differences varied for individual LMWOA
and depend on soil Cd concentrations. For all six LMWOA, there were significant differences at P < 0.05 or < 0.01 levels for soils treated with 10 and 50 mg kg−1 Cd. The magnitude of the differences was greater under soil Cd treatments, especially at relatively low levels (for example,
10 mg Cd kg−1 soil), than in the control. Acetic acid and formic acid constituted more than 96% of the total concentration of the six LMWOA,
while citric acid constituted only about 0.1%. The rice cultivar with higher concentrations of LMWOA in soil accumulated more
Cd in the plants. The results indicate that LMWOA secretion by rice root, especially in Cd-contaminated soils, is likely to
be one of the mechanisms determining the plant Cd uptake properties of rice cultivars. 相似文献
56.
A review of the distribution of particulate trace elements in urban terrestrial environments and its application to considerations of risk 总被引:6,自引:0,他引:6
We review the evolution, state of the art and future lines of research on the sources, transport pathways, and sinks of particulate
trace elements in urban terrestrial environments to include the atmosphere, soils, and street and indoor dusts. Such studies
reveal reductions in the emissions of some elements of historical concern such as Pb, with interest consequently focusing
on other toxic trace elements such as As, Cd, Hg, Zn, and Cu. While establishment of levels of these elements is important
in assessing the potential impacts of human society on the urban environment, it is also necessary to apply this knowledge
in conjunction with information on the toxicity of those trace elements and the degree of exposure of human receptors to an
assessment of whether such contamination represents a real risk to the city’s inhabitants and therefore how this risk can
be addressed. 相似文献
57.
We present a new system for microscopic multicolour variable chlorophyll fluorescence imaging of aquatic phototrophs. The
system is compact and portable and enables microscopic imaging of photosynthetic performance of individual cells and chloroplasts
using different combinations of blue, green, red or white light. Automated sequential exposure of microscopic samples to the
three excitation colours enables subsequent deconvolution of the resulting fluorescence signals and colour marking of cells
with different photopigmentation, i.e., cyanobacteria, green algae, red algae and diatoms. The photosynthetic activity in
complex mixtures of phototrophs and natural samples can thus be assigned to different types of phototrophs, which can be quantified
simultaneously. Here, we describe the composition and performance of the new imaging system and present applications with
both natural phytoplankton and microalgal culture samples. 相似文献
58.
Photo-polymerization of triclosan in aqueous solution induced by ultraviolet radiation 总被引:1,自引:0,他引:1
The formation of 2,8-dichlorodibenzo-p-dioxin and other harmful degradation products in the photo-degradation process of triclosan is of increasing concern. Here we worked on the identification of polymerized products at high triclosan concentration and on the mechanism of photoreaction. Five dimmers and two trimers of triclosan were detected by liquid chromatography-mass spectrum analysis. 2,8-dichlorodibenzo-p-dioxin was also identified by comparing with an authentic standard. Relatively low pH and high concentration favored the polymerization of triclosan. Three main routes of photoreaction were postulated, namely dechlorination, ring closure and polymerization. 相似文献
59.
Aijun Yao Yani Wang Xiaodan Ling Zhe Chen Yetao Tang Hao Qiu Rongrong Ying Rongliang Qiu 《Environmental geochemistry and health》2017,39(2):353-367
Economic and highly effective methods of in situ remediation of Cd and As polluted farmland in mining areas are urgently needed. Pot experiments with Brassica chinensis L. were carried out to determine the effects of three soil amendments [a novel iron-silicon material (ISM), a synthetic zeolite (SZ) and an alkaline clay (AC)] on vegetable uptake of As and Cd. SEM–EDS and XRD analyses were used to investigate the remediation mechanisms involved. Amendment with ISM significantly reduced the concentrations of As and Cd in edible parts of B. chinensis (by 84–94 % and 38–87 %, respectively), to levels that met food safety regulations and was much lower than those achieved by SZ and AC. ISM also significantly increased fresh biomass by 169–1412 % and 436–731 % in two consecutive growing seasons, while SZ and AC did not significantly affect vegetable growth. Correlation analysis suggested that it was the mitigating effects of ISM on soil acidity and on As and Cd toxicity, rather than nutrient amelioration, that contributed to the improvement in plant growth. SEM–EDS analysis showed that ISM contained far more Ca, Fe and Mn than did SZ or AC, and XRD analysis showed that in the ISM these elements were primarily in the form of silicates, oxides and phosphates that had high capacities for chemisorption of metal(loid)s. After incubation with solutions containing 800 mg L?1 AsO4 2? or Cd2+, ISM bound distinctly higher levels of As (6.18 % in relative mass percent by EDS analysis) and Cd (7.21 % in relative mass percent by EDS analysis) compared to SZ and AC. XRD analysis also showed that ISM facilitated the precipitation of Cd2+ as silicates, phosphates and hydroxides, and that arsenate combined with Fe, Al, Ca and Mg to form insoluble arsenate compounds. These precipitation mechanisms were much more active in ISM than in SZ or AC. Due to the greater pH elevation caused by the abundant calcium silicate, chemisorption and precipitation mechanisms in ISM treatments could be further enhanced. That heavy metal(loid)s fixation mechanisms of ISM ensure the remediation more irreversible and more resilient to environmental changes. With appropriate application rate and proper nutrients supplement, the readily available and economic ISM is a very promising amendment for safe crop production on multi-metal(loids) polluted soils. 相似文献
60.
Environmental exposure to arsenic (As) in terms of public health is receiving increasing attention worldwide following cases of mass contamination in different parts of the world. However, there is a scarcity of data available on As geochemistry in Brazilian territory, despite the known occurrence of As in some of the more severely polluted areas of Brazil. The purpose of this paper is to discuss existing data on As distribution in Brazil based on recent investigations in three contaminated areas as well as results from the literature. To date, integrated studies on environmental and anthropogenic sources of As contamination have been carried out only in three areas in Brazil: (1) the Southeastern region, known as the Iron Quadrangle, where As was released into the drainage systems, soils and atmosphere as a result of gold mining; (2) the Ribeira Valley, where As occurs in Pb-Zn mine wastes and naturally in As-rich rocks and soils; (3) the Amazon region, including the Santana area, where As is associated with manganese ores mined over the last 50 years. Toxicological studies revealed that the populations were not exposed to elevated levels of As, with the As concentrations in surface water in these areas rarely exceeding 10 microg/L. Deep weathering of bedrocks along with formation of Fe/Al-enriched soils and sediments function as a chemical barrier that prevents the release of As into the water. In addition, the tropical climate results in high rates of precipitation in the northern and southeastern regions and, hence, the As contents of drinking water is diluted. Severe cases of human As exposure related to non-point pollution sources have not been reported in Brazil. However, increasing awareness of the adverse health effects of As will eventually lead to a more complete picture of the distribution of As in Brazil. 相似文献