Corrections for measurements of tritium in subterranean vapor using silica gel

Hazardous contaminants buried within vadose zones can accumulate in soil gas. The concentrations and spatial extent of these contaminants are measured to evaluate potential transport to groundwater for public risk evaluation. Tritium is an important contaminant found and monitored for in vadose zones across numerous sites within the US nuclear weapons complex, including Los Alamos National Laboratory. The extraction, collection, and laboratory analysis of tritium from subterranean soil gas presents numerous technical challenges that have not been fully studied. Particularly, the lack of moisture in the soil gas in the vadose zone makes it difficult to obtain enough sample (e.g., >5 g) to provide for the required measurement sensitivity, and often, only small amounts of moisture can be collected. Further, although silica gel has high affinity for water vapor and is prebaked prior to sampling, there is still sufficient residual moisture in the prebaked gel to dilute the relatively small amount of sampled moisture; thereby, significantly lowering the ??true?? tritium concentration in the soil gas. This paper provides an evaluation of the magnitude of the bias from dilution, provides methods to correct past measurements by applying a correction factor (CF), and evaluates the uncertainty of the CF values. For this, 10,000 Monte Carlo calculations were performed, and distribution parameters of CF values were determined and evaluated. The mean and standard deviation of the distribution of CF values were 1.53 ± 0.36, and the minimum, median, and maximum values were 1.14, 1.43, and 5.27, respectively.     

Evidence of highly dynamic geochemical behaviour of zinc in the Deûle river (northern France)

The monitoring of dissolved zinc in the De?le river was undertaken at three different periods of the years 2008 and 2009. Electrolabile concentrations of Zn were estimated every 2 hours for several weeks by using an ATMS (Automatic Trace metal Monitoring System) based on voltammetric measurements using a solid Ag-Hg rotating disc working electrode. Complementary measurements were carried out with DGT (Diffusive Gradient in Thin films) pistons deployed directly in the river for 24 hours. Water samples filtrated at 0.45 μm were also analysed by HR-ICP-MS to estimate the total dissolved concentrations of zinc and other trace metals. High frequency monitoring of zinc over several weeks in the De?le river indicated that the concentration could change significantly over short time periods. Resuspension of polluted sediment and biological activities are two main factors that control the behaviour of zinc in the De?le river. Furthermore, in May 2009, daily cycles of the electrolabile zinc fraction have been observed at relatively constant total dissolved concentration. It is assumed that this particular behaviour of zinc is based on an exchange between colloids and/or nonelectrolabile forms and free cation and inorganic complexes at a daily time scale.     

Genotoxicity,oxidative stress,and inflammatory response induced by crack-cocaine: relevance to carcinogenesis

Environmental Science and Pollution Research - Crack-cocaine is a cocaine by-product widely consumed by general population in developing countries. The drug is low cost and is associated with more...     

Safety Level of Acrobatic Work: A Probabilistic Study

Acrobatic work constitutes an activity during which individuals intervene on buildings, cliffs, towers, and so forth, through the use of mountaineering or speleological techniques. The most dangerous situations occur particularly when ascending a rope with ascenders or roping with a descender. Any free fall or false manoeuvre will result in a strong shock on the belaying system that may cause its rupture. The fatal accident rate (FAR) of a given occupation is defined as the average number of fatal accidents per 10⁸ hrs of exposure to a given hazard. In this study it is assumed that the FAR is proportional to the average number of fall-initiating events, η, per worker and per hour of exposure to the fall hazard. η is estimated to be between 10^-3 and 3 × 10^-3. The maximum values of the rupture probability of the securing systems are calculated for the FAR of acrobatic work to be smaller than the FAR of the three most dangerous activity groups of the construction industry in France. These values allow the varying ranges of the parameters that influence this rupture probability to be determined.     

A discourse-analytical perspective on sustainability assessment: interpreting sustainable development in practice

Sustainable development is a ubiquitously used concept in public decision-making: it refers to an ideal vision of global society where human development and environmental quality go hand in hand. Logically, any decision-supporting process aiming at facilitating and steering society toward a sustainable future then seems desirable. Assessing the sustainability of policy decisions is, however, influenced by what sustainable development is believed to entail, as different discourses coexist under the umbrella of the sustainable development meta-discourse. This paper proposes a typology of sustainable development discourses, and, subsequently, applies a discourse-analytical lens on two practical cases of sustainability assessment in different institutional and geographical contexts (in Belgium and in Benin). The results indicate that sustainability assessments tend to be influenced mainly by the consensual ‘sustainable development as integration’ discourse, while also providing a forum for dialogue between different discourses. The results shed light on context-specific discursive and institutional dynamics for the development and application of sustainability assessment. Acknowledging these dynamics as well as sustainable development’s inherent interpretational limits can lead to an improved use of sustainable development as a decision-guiding strategy.     

Evaluation of the Effect of Chemical or Enzymatic Synthesis Methods on Biodegradability of Polyesters

This work compares the biodegradability of polyesters produced by an esterification reaction between glycerol and oleic di-acid (D 18:1) issued from green chemical pathways, via either classical thermo-chemical methods, or an enzymatic method using the immobilized lipase of Candida antartica B (Novozym 435). An elastomeric polymer synthesized by enzymatic catalysis is more biodegradable than an elastomeric thermo-chemical polyester synthesized by a standard chemical procedure. This difference lies in percentage of the dendritic motifs, in values of the degree of substitution, and certainly in cross-links inducing an hyper-branched structure less accessible to the lipolytic enzymes in a waste treatment plant. However, when the elastomeric polymer synthesized by enzymatic catalysis is processed at high temperature as required for certain industrial applications, it presents an identical rate of biodegradation than the chemical polyester. The advantages of the thermo-chemical methods are greater speed and lower cost. Enzymatic synthesis appears be suited to producing polyesters, devoid of metallic catalysts, which must be used without processing at high temperature to keep a high biodegradability.     

Heavy metal contamination from mining sites in South Morocco: 2. Assessment of metal accumulation and toxicity in plants

Metalliferous soils cover a relatively large surface area in Morocco, and up to now no hyperaccumulating plants have been identified on these mining or these industrial sites. The aim of this work was to assess the extent of metal accumulation by plants found in three mining areas in southern Morocco with the ultimate goal of finding metal hyperaccumulating species by using the MetPAD biotest. The biotest helps to obtain information on the selective metal toxicity of aqueous extracts from the plants. A strong metal toxicity, as revealed by the biotest is an indication of a hyperaccumulating plant. Toxicity tests were run concurrently with chemicals analyses of metals in plants and their water extracts. The chemical analyses allow the determination of the hyperaccumulated metal(s). Specimens of the plant species mainly growing on and in the vicinity of the three mines were sampled with their corresponding soils. The results show that all plants analyzed had lower heavy metal content and toxicity despite the relatively very high soil concentrations. A comparison of our results with the criterion used to classify the hyperaccumulator plants indicates that plants we collected from mining sites were hypertolerant but not hyperaccumulators. This was confirmed by transfer factors generally lower than 1. Nevertheless, these tolerant plants species can be used as tools for revegetation for erosion control in metals-contaminated sites (phytostabilization).     

The role of personality characteristics in young adult driving

BACKGROUND: Motor vehicle injury is the major cause of mortality among young adults. Information about the individual characteristics of those who drive dangerously could enhance traffic safety programs. The goal of this research was to examine the association between various personality-related characteristics and risky driving behaviors. METHODS: Young adults in Michigan, USA (n = 5,362) were surveyed by telephone regarding several personality factors (risk-taking, hostility, aggression, tolerance of deviance, achievement expectations) and driving behaviors (competitive driving, risk-taking driving, high-risk driving, aggressive driving, and drink/driving). Michigan driver records were obtained to examine offenses, serious offenses, driving offense points, crashes and serious crashes in the three pre-interview years. Multivariate regression analyses, adjusting for age, race, and marital status were conducted separately by sex to identify personality factors related to driving. RESULTS: For men and women, greater risk-taking propensity, physical/verbal hostility, aggression, and tolerance of deviance were significant predictors of a competitive attitude toward driving, risk-taking driving, high-risk driving, driving aggression, and drink/driving. Greater risk-taking propensity, physical/verbal hostility, aggression, and to a small degree, expectations for achievement predicted higher numbers of offenses, serious offenses, and points. CONCLUSION: Traffic safety policies and programs could be enhanced through recognition of the role personality factors play in driving behavior and the incorporation of this knowledge into the design and implementation of interventions that modify the behaviors associated with them.     

添加生物炭对西北黄土吸附克百威的影响

研究了不同温度下制得的生物炭对西北黄土吸附农药克百威的影响,并对溶液p H值和初始浓度对吸附的影响进行了探讨.结果表明,克百威在添加生物炭黄土上的动力学吸附过程较好地符合准二级吸附动力学模型;热力学吸附较好地符合Freundlich等温吸附模型;随着系统温度的升高,添加生物炭的黄土对克百威的吸附量增大,且其对克百威的吸附自由能变(ΔGθ)小于0,吸附焓变(ΔHθ)及吸附熵变(ΔSθ)均大于0,表明吸附是一个自发吸热且体系混乱程度增大的等温吸附过程.溶液p H值和克百威的初始浓度对添加生物炭的土样吸附影响较明显.当p H值为4~7时,添加生物炭的土样饱和吸附量随p H升高呈缓慢降低,当p H值大于7时,吸附容量随p H升高呈明显降低趋势.克百威初始浓度从20 mg·L-1增至50 mg·L-1的过程中,吸附量快速上升,初始浓度大于50 mg·L-1时,吸附量随初始浓度的升高而缓慢增加并逐渐趋于平衡.