Membrane,action, and oscillatory potentials in simulated protocells

Electrical membrane potentials, oscillations, and action potentials are observed in proteinoid microspheres impaled with (3 M KCl) microelectrodes. Although effects are of greater magnitude when the vesicles contain glycerol and natural or synthetic lecithin, the results in the purely synthetic thermal protein structures are substantial, attaining 20 mV amplitude in some cases. The results add the property of electrical potential to the other known properties of proteinoid microspheres, in their role as models for protocells.     

Evaluation of the efficiency of some sediment trapping methods after a Mediterranean forest fire

Forest fires are common in Mediterranean environments and may become increasingly more frequent as the climate changes. Destruction of the forest cover and litter layer leads to greater overland flow and increased erosion rates. The greatest risk occurs during the first rainstorms following a major fire, so local authorities must act quickly to put erosion control methods in place in order to avoid excessive post-fire sediment loads in river channels. Deciding on which methods to use requires accurate knowledge of their impact on sediment load and an estimate of their cost efficiency. The objective of this study was to evaluate the efficiency of Log Debris Dams (LDDs) and a sedimentation basin for their effectiveness in trapping sediments. Paired sub-catchments were studied to quantify the amount of sediments trapped in stream channels by a series of LDDs and a sedimentation basin. Cost efficiency was evaluated for each of the measures as a function of the cost per unit volume of sediments trapped. In addition, grain size analyses were performed to characterise the nature of the sediments trapped. A third sediment trapping method, Log Erosion Barriers (LEBs) was evaluated more superficially than the first two and conclusions regarding this method are tentative. LDDs trapped a mean volume of 1.57 m³ per unit (median = 1.28 m³); mean LDD height was 105.4 cm (std. dev. = 21.9 cm), and mean height of trapped sediments was only 50.0 cm (std. dev. = 22.9 cm), showing that the traps were only half filled. Sediment height was limited by the presence of gaps between logs or branches that allowed runoff to flow through. Comparison of the textural characteristics of slope and trapped sediments showed distinct sorting: particles greater than 20 mm were not mobilised from the slopes during the study period, sediments in the medium to coarse sand size fractions were trapped preferentially by the LDDs, and sediments in the sedimentation basin were enriched by clay and silt sized (<0.050 mm) particles as coarser sediments were trapped upstream by the LDDs. Cost efficiency of LDDs was estimated at about 143 € m⁻³ for the LDDs and 217 € m⁻³ for the sedimentation basin at the time of sampling. The LDDs are therefore a cost effective method of trapping sediments, but they can only be used when pine trees or straight-trunked trees are locally available. In this case, they should be combined with LEBs, which had a cost efficiency estimated at about 250 € m⁻³. Installation of the LEBs had not been optimised and they have the advantage of trapping sediments on the slopes where they can continue to play an ecological role, so this method can give better results with more care. Sedimentation basins can be emptied if necessary and are useful in areas where pine trees are not available and where the site can be secured.     

Distribution of common dolphins (Delphinus spp.) in the western Atlantic Ocean: a critical re-examination

Due to indications that misidentification (largely confusion among dolphins of the genera Delphinus and Stenella) in the past had led to erroneous assumptions of distribution of the two species of common dolphins (Delphinus delphis and D. capensis) in the western Atlantic Ocean, we conducted a critical re-examination of records of the genus Delphinus from this region. We compiled 460 ‘plottable’ records, required support for confirmation of genus and species identifications, and found many records lacking (and some clearly misidentified). When we plotted only the valid records (n = 364), we found evidence of populations in only three areas, and apparent absence throughout much of the tropical/subtropical regions. Off the east coast of the US and Canada, D. delphis is found from the Georgia/South Carolina border (32°N) north to about 47–50°N off Newfoundland. Since the 1960s, they have apparently been absent from Florida waters. There is no evidence that dolphins of the genus occur in the Gulf of Mexico. Reports of common dolphins from most of the Caribbean Basin are also rejected, and the only place in that region where they are confirmed to occur is off central-eastern Venezuela (a coastal D. capensis population). Off eastern South America, common dolphins appear to be restricted to south of 20°S. There is a coastal long-beaked population found in the South Brazil Bight, and one or more short-beaked populations south and offshore of this (ranging south to at least northern Argentina). The results are very different from commonly-accepted patterns of distribution for the genus in the Atlantic. Most areas of distribution coincide with moderate to strong upwelling and common dolphins appear to avoid warm, tropical waters. This study shows that great care must be taken in identification of similar-appearing long-beaked delphinids, and that uncritical acceptance of records at face value can lead to incorrect assumptions about the ranges of the species involved.     

Use of organic coagulant/flocculant for treatment of effluents generated in intensive rearing of swine

Separation of water for reuse is essential in an effluent treatment system, especially in activities with high water consumption, such as a pig production system. The objective of this work was to evaluate the efficiency of Tanfloc SG^® coagulant tannin/organic flocculant used to treat effluent generated during the intensive rearing of swine. For the evaluation, laboratory and in situ tests (field test) were performed. The laboratory tests were performed to define the concentration (1 and 16%), dosage (0, 0.1, 0.2, 0.3, 0.4, 0.5, 1.0, 2.0, 4.0, 8.0, and 16.0 milliliters of the solution), and time (24, 48, 72, and 96 hours) of coagulation/flocculation treatment of the solid portion of the effluent. The parameters pH, turbidity, oxidation reduction potential, dissolved oxygen, and electroconductivity (in microsiemens per centimeter) were evaluated using a multiparameter probe and the parameters ammonia (NH₃), nitrate (NO₃), and nitrite (NO₂) in the laboratory, in relation to the coagulation/flocculation time of the solid part of the effluent. The use of tannin as a coagulant/flocculant of plant origin in the treatment of swine effluents was effective in reducing turbidity and concentrations of ammonia, nitrite, and nitrate, and it allowed separation of the solid–liquid phase in approximately 68% as liquid phase.     

Accumulation, release, and solubility of arsenic, molybdenum, and vanadium in wetland sediments

This study was undertaken to determine the fate of As, Mo, and V (trace elements, TEs) in the sediments of a constructed wetland in use for the remediation of potentially toxic trace element-contaminated agricultural drainwater. After three years of wetland operation, sediment cores were collected to determine changes in TE concentrations as a function of depth and the effects of varying water column depth. All TE concentrations were highest in the top 2 to 4 cm and decreased with depth. Molybdenum accumulated in the wetland sediments, up to levels of 32.5 +/- 4.6, 30.2 +/- 8.9, and 59.3 +/- 26.1 mg kg(-1) in the top 1 cm of sediment at water depths of 15, 30, and 60 cm, respectively. In the top 2 cm of sediment, As accumulated (28.2 +/- 3.0 mg kg(-1)) only at the 60-cm water depth. Below 2 cm, as much as 10 mg kg(-1) of As was lost from the sediment at all water depths. In most cases, V concentrations decreased in the sediment. In this wetland system, the lowest redox potentials were found near the sediment surface and increased with depth. Thus, in general As, Mo, and V concentrations in the sediment were highest under more reducing conditions and lowest under more oxidizing conditions. Most of the accumulated Mo (73%) became water soluble on drying of samples. This has important implications for systems undergoing changes in redox status; for instance, if these wetland sediments are dried, potentially large amounts of Mo may be solubilized.     

Ozone and Radionuclide Correlations In Air of Marine Trajectory At Quillayute,Washington

A large number of radioactive and non-radioactive airborne constituents are being measured continually at our coastal air reference station located in northwestern Washington State. Important correlations have been observed between many of these materials. There are also apparent relationships between changing concentrations and meteorological parameters. Interesting fluctuations in the ozone levels with incoming clean air masses may help explain some of the high ozone levels observed by workers elsewhere. Positive correlations between certain known high altitude source region particulate radionuclides and ozone on a daily basis point to the upper level origin of the higher ozone concentrations observed at this site. This view is reinforced by the more usual negative correlations observed between general particulate levels at Quillayute and ozone concentrations when measured on a continuous monitoring basis.     

Chemical solutions for greywater recycling

Greywater recycling is now accepted as a sustainable solution to the general increase of the fresh water demand, water shortages and for environment protection. However, the majority of the suggested treatments are biological and such technologies can be affected, especially at small scale, by the variability in strength and flow of the greywater and potential shock loading. This investigation presents the study of alternative processes, coagulation and magnetic ion exchange resin, for the treatment of greywater for reuse. The potential of these processes as well as the influence of parameters such as coagulant or resin dose, pH or contact time were investigated for the treatment of two greywaters of low and high organic strengths. The results obtained revealed that magnetic ion exchange resin and coagulation were suitable treatment solutions for low strength greywater sources. However, they were unable to achieve the required level of treatment for the reuse of medium to high strength greywaters. Consequently, these processes could only be considered as an option for greywater recycling in specific conditions that is to say in case of low organic strength greywater or less stringent standards for reuse.