The study was aimed at determining the levels of metals in water samples and muscles of the fish caught in the Una River basin,
located in the northwestern part of Bosnia and Herzegovina. For that purpose, three fish species: Brown Trout (Salmo trutta m. fario), Grayling (Thymallus thymallus) and Californian Trout (Salmo gairdneri), together with stem water samples, were analyzed for metal concentrations (Pb, Hg, Cd, As, Mn, Ni, Cu, Cr, Se, Co, Sn, Zn,
Fe, Ca, P) during a 2-year period. The fish was captured using electric fishing, nets or fishing equipment. The capture was
undertaken on three sites (the river source, the middle flow and the river mouth) of each of the five biggest rivers belonging
to the Una River basin (Unac, Krušnica, Sana, Klokot, and Una). The concentrations of metals in each sample were determined
via atomic absorption spectrophotometry. In the tested waters, the presence of Mn in concentrations higher than permitted
(0.07 mg/l) had been detected. In the tested meat, the following average concentrations of metals (mg/kg) had been found:
Pb (0.67), Cd (0.06), Mn (0.65), Ni (0.15), Cu (0.79), Cr (1.05), Se (0.03), Zn (8.92), Fe (5.40), Ca (14.68), and P (10.85).
The correlation between Mn concentrations identified in the tested waters and those identified in the meat of Brown Trout
was revealed to be statistically significant, which confirms that, over time, bioaccumulation of metals took place. Even though
the results were not indicative of contamination, they strongly suggest that constant monitoring of the ecosystems in reference
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To date, heavyweight concretes have been produced from various heavy aggregates as radiation insulation materials, and their gamma ray absorption levels have been investigated. Many of the studies have used heavy aggregates instead of cement or coarse aggregates from composite material components. The present study prepared lightweight concretes using copper mine tailings, clay brick dust, and fly ash instead of fine aggregates. Some mechanical tests (density, compressive strength, and ultrasonic pulse velocity) were performed on composite blocks with dimensions of 5*5*5 cm, and radiation interaction parameters [linear absorption coefficient (cm−1), mass attenuation coefficient (cm2/gr), HVL (half-value layer) (cm), MFP (cm), and permeability (%)] were measured. Radiation interaction parameters were obtained using a HPGe gamma detector. Radiation measurements were performed at five different photon energies: 583 keV (133Ba), 609 keV (133Ba), 662 keV (137Cs), 911 keV (133Ba), 1173 keV (60Co), and 1332 keV (60Co). Additionally, the compressive strength and UPV values of composite materials were associated with their gamma ray permeability. Tests revealed that samples with the addition of copper mine tailings yielded the best energy absorption at all energy levels and that absorption decreased as the energy level increased. For example, with the increasing of the energy level, mass attenuation coefficients decreased. The highest mass attenuation coefficients were obtained as 0.128 cm2/g at an energy level of 583 keV in composites produced from copper mine tailings. On the other hand, it was measured at the same energy level as 0.069 cm2/g (a 46% decrease) in the composites produced with fly ash. In addition, it was observed that fly ash used as a fine aggregate did not have a significant effect on mass attenuation coefficient and could be used as a gamma shield if the material thickness was increased to an average of 14 cm. This study revealed that tailings materials could be used as radiation shields. This study also demonstrated that not using heavy aggregates and producing lightweight concrete in radiation shield production significantly reduced shield production cost.