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421.
J F Müller D Haynes M McLachlan F B?hme S Will G R Shaw M Mortimer R Sadler D W Connell 《Chemosphere》1999,39(10):1707-1721
Concentrations of 2,3,7,8-chlorine substituted PCDDs, PCDFs, selected PCB congeners and HCB were determined in sediment samples collected from sites along the east coast of Queensland in northern Australia. PCDDs were detectable in all sediment samples while PCDFs, PCBs and HCB were mainly found in sediment samples collected from sites in the Brisbane metropolitan area. The results provide evidence that an unidentified source for higher chlorinated PCDDs exists along the Queensland coast. 相似文献
422.
Andreas Ahrens Arnim von Gleich und Lothar Li?ner 《Umweltwissenschaften und Schadstoff-Forschung》2002,14(3):165-169
Ohne Zusammenfassung
Online First: 27. 03. 2002
‚Sustainable Substitution of Hazardous Substances‚; Projektbeschreibung unter wwwoekopolde oder wwwfh-hamburgdelpers/gleich_von bzw. www.uni-hamburgde/kooperationssteI1e-hh. Das Vorhaben wird vom Bundesministerium für Bildung und Forschung (BMBF) im F?rderschwerpunkt ‚Rahmenbedingungen für Innovationen
zum nachhaitigen Wirtschaften’ (RIW) gef?rdert und von der GSF als Projekttr?ger betreut (FkZ. O7Riw4). 相似文献
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Fate of ah receptor agonists during biological treatment of an industrial sludge containing explosives and pharmaceutical residues 总被引:1,自引:0,他引:1
Gustavsson LK Klee N Olsman H Hollert H Engwall M 《Environmental science and pollution research international》2004,11(6):379-387
GOAL, SCOPE AND BACKGROUND: Sweden is meeting prohibition for deposition of organic waste from 2005. Since 1 million tons of sludge is produced every year in Sweden and the capacity for incineration does not fill the demands, other methods of sludge management have to be introduced to a higher degree. Two biological treatment alternatives are anaerobic digestion and composting. Different oxygen concentrations result in different microbial degradation pathways and, consequently, in a different quality of the digestion or composting residue, It is therefore necessary to study sludge treatment during different oxygen regimes in order to follow both degradation of compounds and change in toxicity. In this study, an industrial sludge containing explosives and pharmaceutical residues was treated with anaerobic digestion or composting, and the change in toxicity was studied. Nitroaromatic compounds, which are the main ingredients of both pharmaceutical and explosives, are well known to cause cytotoxicity and genotoxicity. However, little data are available concerning sludge with nitroaromatics and any associated dioxin-like activity. Therefore, we studied the sludge before and after the treatments in order to detect any changes in levels of Ah receptor (AhR) agonists using two bioassays for dioxin-like compounds. METHODS: An industrial sludge was treated with anaerobic digestion or composting in small reactors in a semi-continuous manner. The same volume as the feeding volume was taken out daily and stored at -20 degrees C. Sample preparation for the bioassays was done by extraction using organic solvents, followed by clean up with silica gel or sulphuric acid, yielding two fractions. The fractions were dissolved in DMSO and tested in the bioassays. The dioxin-like activity was measured using the DR-CALUX assay with transfected H4IIE rat hepatoma pGudluc cells and an EROD induction assay with RTL-W1 rainbow trout liver cells. RESULTS AND DISCUSSION: The bioassays showed that the sludge contained AhR agonists at levels of TCDD equivalents (TEQs) higher than other sludge types in Sweden. In addition, the TEQ values for the acid resistant fractions increased considerably after anaerobic digestion, resulting in an apparent formation of acid resistant TEQs in the anaerobic reactors. Similar results have been reported from studies of fermented household waste. There was a large difference in effects between the two bioassays, with higher TEQ levels in the RTL-W1 EROD assay than in the DR-CALUX assay. This is possibly due to a more rapid metabolism in rat hepatocytes than in trout hepatocytes or to differences in sensitivities for the AhR agonists in the sludge. It was also demonstrated by GC/FID analysis that the sludge contained high concentrations of nitroaromatics. It is suggested that nitroaromatic metabolites, such as aromatic amines and nitroanilines, are possible candidates for the observed bioassay effects. It was also found that the AhR agonists in the sludge samples were volatile. CONCLUSIONS: The sludge contained fairly high concentrations of volatile AhR agonists. The increase of acid resistant AhR agonist after anaerobic digestion warrants further investigations of the chemical and toxic properties of these compounds and of the mechanisms behind this observation. RECOMMENDATION AND OUTLOOK: This study has pointed out the benefits of using different types of mechanism-specific bioassays when evaluating the change in toxicity by sludge treatment, in which measurement of dioxin-like activity can be a valuable tool. In order to study the recalcitrant properties of the compounds in the sludge using the DR-CALUX assay, the exposure time can be varied between 6 and 24 hours. The properties of the acid-resistant AhR agonists formed in the anaerobic treatment have to be investigated in order to choose the most appropriate method for sludge management. 相似文献
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Significance of platinum group metals emitted from automobile exhaust gas converters for the biosphere 总被引:1,自引:0,他引:1
Intention, Goal, Scope, Background Following the introduction of automobile catalytic converters the platinum group metals (PGM) platinum (Pt), palladium (Pd)
and rhodium (Rh) gain on increasing interest in environmental research as these metals are emitted with exhaust fumes into
the environment. Consequently, elevated PGM levels were found in different environmental matrices uch as road dusts, soils
along heavily frequented roads, sediments of urban rivers etc. Accordingly, the effects of increasing PGM emissions on the
biosphere are controversially discussed.
Objective This paper summarizes the present knowledge on the biological availability of PGM to plants and animals. As biological availability
is one of the most decisive factors determining the toxicologi-cal potential of xenobiotics, this information is very important
to evaluate the possible threat of the noble metals to ecosystems.
Results and Discussion The availability of soluble as well as particle bound PGM to terrestrial plants was demonstrated in several studies. Experimental
investigations revealed uptake of Pt, Pd and Rh also by aquatic plants. Additionally, the biological availability of the noble
metals for animals has been verified in experimental studies using soluble metal salts, catalytic converter model substances,
sediments of urban rivers, road dust or tunnel dust as metal sources. These studies refer mainly to aquatic animals. Beside
of free living organisms, in particular worms parasitizing fish demonstrated a high potential to accumulate PGM. This could
be of great interest in respect of biomonitoring purposes. Generally, for plants as well as for animals Pd turns out to be
the best available metal among the PGM. Compared to other heavy metals, the biological availability of PGM from road dust
to zebra mussels(Dreissena polymorpha) ranged between that of Cd and Pb.
Conclusion Especially chronic effects of PGM on the biosphere can not be excluded due to (1) their cumulative increase in the environment,
(2) their unexpected high biological availability and bioaccumulation and (3) their unknown toxicological and ecotoxicological
potential. However, it appears that acute effects on ecosystems due to anthropogenic PGM emission are not likely.
Recommendation and Outlook Research on environmental PGM contamination of the biosphere, especially the fauna, and on long-term toxiciry of low PGM concentrations
is highly appreciated. These studies require very sensitive analytical techniques to determine PGM even in low sample amounts.
Research has to be done in particular on reliable determination of (ultra) trace levels of Pd and Rh as the lack of data on
these two metals is mainly due to analytical problems. 相似文献
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Varotsos (2002a,b), suggested that both the smaller-sized ozone hole over Antarctica and its splitting in two holes in September 2002 occurred due to an unprecedented major sudden stratospheric warming caused by very strong planetary waves propagated in the southern hemisphere. Subsequently, a NASA press release of December 6, 2002, also reported the prevalence of very strong planetary waves in Antarctica. The aim of this Letter is to further discuss the morphology of the Antarctic ozone hole, to detect the causes that allowed the Antarctic stratosphere to exhibit this exceptional warming and to examine what it denotes about its mechanisms. Concerning the morphology, among the principal findings is that the ozone hole split occurred not only in the stratosphere but extended in the lower altitudes (upper troposphere). As to the causes of the major sudden stratospheric warming of 2002, a comparison with the previous warmings in Antarctica since 1964 is made. The smaller-sized Antarctic ozone hole of 2002 is approximately equal to that of 1988 when a strong sudden stratospheric warming occurred. If only the destruction of ozone by chlorofluorocarbons resulted in the delayed sudden stratospheric warmings in Antarctica, then the early sudden stratospheric warmings of 1988 and 2002 would not have occurred, since chlorofluorocarbon loading of the stratosphere has remained relatively stable in recent years. Furthermore, it appears that the El Nino characteristics in 1988 and 2002 are not similar. 相似文献