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351.
Anthropogenic metal cycles in China 总被引:2,自引:0,他引:2
Tao Wang Jiansu Mao Jeremiah Johnson Barbara K. Reck Thomas E. Graedel 《Journal of Material Cycles and Waste Management》2008,10(2):188-197
The flows and stocks of seven important industrial metals were characterized for mainland China for several years in the dynamically
changing decade of 1994–2004. One-year snapshot cycles are provided for chromium, nickel, and silver. For copper, zinc, lead,
and iron, multiple-year cycles have been completed; they demonstrate that the flows of these metals into use in China doubled
between 2000 and 2004. Although the Chinese per capita flows from production to disposal are mostly shown to be below the
global average rate, they are increasing or are expected to increase dramatically. The metal resource efficiency is evaluated
for several indicators of material flow analysis; these metrics for China are also below the global average values. The research
quantitatively illustrates that China’s metal cycles may pose significant resource and environmental challenges in terms of
their magnitudes and potential for growth. 相似文献
352.
353.
The removal of Cr(VI) by zero-valent iron (Fe(0)) and the effect of three complex reagents, ethylenediaminetetraacetic acid (EDTA), NaF and 1,10-phenanthroline, on this reaction were investigated using batch reactors at pH values of 4, 5 and 6. The results indicate that the removal of Cr(VI) by Fe(0) is slow at pH 5.0 and that three complex reagents play different roles in the reaction. EDTA and NaF significantly enhance the reaction rate. The zero-order rate constants at pH 5.0 were 5.44 microM min(-1) in the presence of 4mM EDTA and 0.99 micrM min(-1) in the presence of 8 mM NaF, respectively, whereas that of control was only 0.33 micrM min(-1), even at pH=4.0. This enhancement is attributed to the formation of complex compounds between EDTA/NaF and reaction products, such as Cr(III) and Fe(III), which eliminate the precipitates of Cr(III), Fe(III) hydroxides and Cr(x)Fe(1-)(x)(OH)(3) and thus reduce surface passivation of Fe(0). In contrast, 1,10-phenanthroline, a complex reagent for Fe(II), dramatically decreases Cr(VI) reduction by Fe(0). At pH=4.0, the zero-order rate constant in the presence of 1mM of 1,10-phenanthroline was 0.02 micrM min(-1), decreasing by 99.7% and 93.9%, respectively, compared with the results in the presence and absence of EDTA. The results suggest that a pathway of the reduction of Cr(VI) to Cr(III) by Fe(0) may involve dissolution of Fe(0) to produce Fe(II), followed by reduction of Cr(VI) by Fe(II), rather than the direct reaction between Cr(VI) and Fe(0), in which Fe(0) transfers electrons to Cr(VI). 相似文献
354.
Jia-Yeong Ku Huiting Mao Kesu Zhang Kevin Civerolo S. Trivikrama Rao C. Russell Philbrick Bruce Doddridge Richard Clark 《Environmental Fluid Mechanics》2001,1(2):209-233
This paper examines the effects of two different planetary boundary-layer (PBL) parameterization schemes – Blackadar and Gayno–Seaman – on the predicted ozone (O3) concentration fields using the MM5 (Version 3.3) meteorological model and the MODELS-3 photochemical model. The meteorological fields obtained from the two boundary-layer schemes have been used to drive the photochemical model to simulate O3 concentrations in the northeastern United States for a three-day O3 episodic period. In addition to large differences in the predicted O3 levels at individual grid cells, the simulated daily maximum 1-h O3 concentrations appear at different regions of the modeling domain in these simulations, due to the differences in the vertical exchange formulations in these two PBL schemes. Using process analysis, we compared the differences between the different simulations in terms of the relative importance of chemical and physical processes to O3 formation and destruction over the diurnal cycle. Finally, examination of the photochemical model's response to reductions in emissions reveals that the choice of equally valid boundary-layer parameterizations can significantly influence the efficacy of emission control strategies. 相似文献
355.
Numerical Investigation of Boundary-Layer Evolution and Nocturnal Low-Level Jets: Local versus Non-Local PBL Schemes 总被引:3,自引:0,他引:3
Kesu Zhang Huiting Mao Kevin Civerolo Stephen Berman Jia-Yeong Ku S. Trivikrama Rao Bruce Doddridge C. Russell Philbrick Richard Clark 《Environmental Fluid Mechanics》2001,1(2):171-208
Numerical simulations of the evolution of the planetary boundary layer (PBL) and nocturnal low-level jets (LLJ) have been carried out using MM5 (version 3.3) with four-dimensional data assimilation (FDDA) for a high pollution episode in the northeastern United States during July 15–20, 1999. In this paper, we assess the impact of different parameterizations on the PBL evolution with two schemes: the Blackadar PBL, a hybrid local (stable regime) and non-local (convective regime) mixing scheme; and the Gayno–Seaman PBL, a turbulent kinetic energy (TKE)-based eddy diffusion scheme. No FDDA was applied within the PBL to evaluate the ability of the two schemes to reproduce the PBL structure and its temporal variation. The restriction of the application of FDDA to the atmosphere above the PBL or the lowest 8 model levels, whichever is higher, has significantly improved the predicted strength and timing of the LLJ during the night. A systematic analysis of the PBL evolution has been performed for the primary meteorological fields (temperature, specific humidity, horizontal winds) and for the derived parameters such as the PBL height, virtual potential temperature, relative humidity, and cloud cover fraction. There are substantial differences between the PBL structures and evolutions simulated by these two different schemes. The model results were compared with independent observations (that were not used in FDDA) measured by aircraft, RASS and wind profiler, lidar, and tethered balloon platforms during the summer of 1999 as part of the NorthEast Oxidant and Particle Study (NE-OPS). The observations tend to support the non-local mixing mechanism better than the layer-to-layer eddy diffusion in the convective PBL. 相似文献
356.
The Natural Vegetation Responses to the Groundwater Change Resulting from Ecological Water Conveyances to the Lower Tarim River 总被引:4,自引:0,他引:4
This paper takes the ecological water conveyance project (EWCP) that transfers water from the Bosten Lake, to Daxihaizi Reservoir, and finally to the Taitema Lake as a case study to analyze
the dynamic change of the groundwater depth, the vegetation responses to the elevation of the groundwater depth as well as
the relationship between the groundwater depth and the natural vegetation. The results from many years’ monitoring in field
indicate: (1) the groundwater depth has been elevating gradually with the increase in the times of watering and the elevation
range has been expanding continuously in the lower reaches of Tarim River. Correspondingly, the natural vegetation has a favorable
response to the elevation of the groundwater depth. The change of the natural vegetation has accordance with that of the groundwater
depth. Such facts not only show that groundwater is a key factor to the growth of the native vegetation but also prove it
is feasible that the degraded ecosystem can be restored and protected by the EWCP; (2) the results of analysis of the spatial-temporal response of the natural vegetation to watering reveals that the beneficial
influence of the EWCP on the ecosystem in the lower Tarim River is a long-term process; (3) in terms of the function and structure of ecosystem
after watering in the lower reaches of Tarim River, the EWCP does not still reach the goal of ecological restoration at a large spatial scale at present. Based on such monitoring results,
some countermeasures and suggestions for the future restoration strategy are proposed so as to provide a theoretical basis
for restoring and protecting the ecosystem in Tarim River, and meanwhile it can also provide some scientific references for
implementing the similar ecological projects in other areas. 相似文献
357.
358.
359.
水体沉积物中有效砷的测试新方法研究 总被引:2,自引:1,他引:1
一种氧化铁/醋酸纤维素复合膜(FeO/CAM)被用于太湖沉积物中砷的生物有效性评估.结果发现,在水介质中,FeO/CAM对沉积物中砷的富集量随土水比增加而呈乘幂函数减少,在土水质量比为0.025(即1:40)之后趋于某一平台值;在土水比为0.025并得到充分振荡的条件下,沉积物中释放的有效砷被FeO/CAM富集至膜中,并随时间增加而增加,至24 h后逐渐趋于平衡,这一过程恰当地模拟了生物对砷的吸收.因此,FeO/CAM可以用于有效砷的体外测试.利用FeO/CAM对12个总砷含量为6.4~34.6 mg·kg-1的太湖沉积物样品中的有效砷进行了测定.结果发现,FeO/CAM提取的有效砷含量与磷酸盐缓冲液提取的有效砷含量之间显著相关.太湖沉积物中的有效砷含量与总砷、总磷、有机质和吸附磷含量以及磷吸附饱和度显著相关,说明沉积物理化属性对有效砷含量有重要影响.FeO/CAM克服了化学试剂提取过程中引起的非有效态砷释放的根本缺陷,因此,FeO/CAM方法在沉积物有效砷含量的测定时比化学试剂提取法可能更准确. 相似文献
360.
This research aims to shed light on the interaction mechanism of cost risks for biomass material supply in power generation, especially for biomass-coal dual-fuel systems. Firstly, a game model is established to analyze interactions among factors including unit procurement cost, unit transportation cost, basic price and coal price for crop residue collection. Secondly, a Monte Carlo simulation is implemented to compare the profit increase under material competition with that under price alliance. The methodology is illustrated with a case study in a biomass power plant in Shandong Province, China. It shows that developing a price alliance will benefit both the allied enterprises and the local collection area in most circumstances. Thirdly, a risk tolerance area approach is applied in mapping the cost risk and in explaining the risky circumstances of the case study. 相似文献