Lead ion adsorption on functionalized sugarcane bagasse prepared by concerted oxidation and deprotonation

Environmental Science and Pollution Research - Targeting the removal of Pb2+ in wastewater, sugarcane bagasse was treated with nitric acid and an alkaline solution to prepare adsorbents. On a...     

Intrinsic chemiluminescence production from the degradation of haloaromatic pollutants during environmentally-friendly advanced oxidation processes: Mechanism, structure–activity relationship and potential applications

The ubiquitous distribution of halogenated aromatic compounds(XAr) coupled with their carcinogenicity has raised public concerns on their potential risks to both human health and the ecosystem. Recently, advanced oxidation processes(AOPs) have been considered as an"environmentally-friendly" technology for the remediation and destruction of such recalcitrant and highly toxic XAr. During our study on the mechanism of metal-independent production of hydroxyl radicals(UOH) by halogenated quinones and H_2O_2, we found, unexpectedly, that an unprecedented UOH-dependent two-step intrinsic chemiluminescene(CL) can be produced by H_2O_2 and tetrachloro-p-benzoquinone, the major carcinogenic metabolite of the widely used wood preservative pentachlorophenol. Further investigations showed that, in all UOH-generating systems, CL can also be produced not only by pentachlorophenol and all other halogenated phenols, but also by all XAr tested. A systematic structure–activity relationship study for all 19 chlorophenolic congeners showed that the CL increased with an increasing number of Cl-substitution in general. More importantly, a relatively good correlation was observed between the formation of quinoid/semiquinone radical intermediates and CL generation. Based on these results, we propose that UOH-dependent formation of quinoid intermediates and electronically excited carbonyl species is responsible for this unusual CL production; and a rapid, sensitive,simple, and effective CL method was developed not only to detect and quantify trace amount of XAr, but also to provide useful information for predicting the toxicity or monitoring real-time degradation kinetics of XAr. These findings may have broad chemical, environmental and biological implications for future studies on halogenated aromatic persistent organic pollutants.     

基于环境约束的浙江省制造业行业结构调整优化研究

文章在综合评价浙江省制造业内部各产业污染排放强度的基础上,对浙江省制造业污染排放量进行了因素分解,并构建了基于污染排放程度系数和工业总产值的区域类型划分矩阵,将浙江省制造业划分为优先发展行业、结构优化发展行业、引导发展行业、推动发展行业和限制发展行业,对浙江省制造业内部各产业结构的调整优化提出了针对性建议。     

Ecological Approaches to Urban Migration of the Three Gorges Reservoir Region

As a global developing tendency, the general viewpoint has been reached in the construction of the ecocities, which has produced widespread influence in the international society. Cities must enable people to live in harmony with nature and achieve sustainable development. Although more and more cities in the world are being designed and built to the ecological ones, the construction is also theoretical questions and arduous tasks. People oriented, ecocity development requires the comprehensiv…     

Study on Flood Disasters in China

The occurrence of a flood disaster is a reflection of both nature and society:natural condition of aflood disaster is the appearance of floodwater,which is requisite;while the social-economic causeas a sufficient condition lies in human activities.We can classify flood disasters into fourcategories according to their formation mechanism and regional characteristics:burst,overflow,flood catastrophe and deluge.China is a country of frequent flood disasters.From2 0 0 B.C.to1 949,there had occurr…     

Sustainable Development and the Basic Value of Natural Environment

Contrast with artificial environment, the multi-level self-organizational system of nature has great gain. Sustainable material environment should respect nature： non-rubbish and super-cycle quality of natural ecosystem offers the material source of human development, fractal structure of nature offers new field of space and information source to this high-density and information-based society, dissipative structure of nature links the new system of energy with whole ecosystem organically, and life-chain regulation is the base of sustainable life environment. Nature guarantees the physical healthy environ- ment by its all-dimension healthy factor, constructs the mental healthy environment by its quality of co-ordinate and chaos, so that guarantees the whole emergence of sustainable development on the ＇super-science＇ level In the view of sustainable development, construction, green economy and human health are basic fields. With the concept of ecosystem regulation, we can relate these fields organically and fulfill the task of human health, welfare and sustainable development. Ecosystem regulation is the base of sustainable development＇s new paradigm.     

混凝——吸附法处理油墨废水工艺研究

采用不同无机混凝剂及氧化还原剂对打印机生产中的油墨废水的混凝及脱色效果进行试验比较，确定了实验室工艺条件及各种混凝剂最佳用量及次序。结果表明，该工艺脱色率达１００％，ＣＯＤｃｒ去除率达５１％。     

纺织厂地下尘室火灾危险及其防治

纺织厂地下尘室是着火最多又不易扑救之处。本文介绍了沉降式和网罩过滤式、布袋过滤式尘室,同时分析了粉尘爆炸的特点、条件及防止其爆炸、火灾的方法。