Environmental assessment of different advanced oxidation processes applied to a bleaching Kraft mill effluent

Basic research on remediation of polluted sediment by leaching has, to date, been carried out exclusively with suspended material. For economic reasons, only solid-bed leaching is applicable to large-scale processes. Abiotic and microbial solid-bed leaching were comparatively studied in a percolator system using ripened and therefore permeable heavy metal polluted river sediment. In the case of abiotic leaching, sulfuric acid was supplied to the sediment by circulating water; the lower the pH of the percolating water, the higher the percolation flow, and the lower the solid-bed height was, the faster the heavy metals were solubilized. However, the pH and percolation flow are subjected to restrictions: strongly acidic conditions result in dissolution of mineral components, and the percolation flow must not exceed the bed permeability. And a high solid bed is an economic requirement. In the case of bioleaching, elemental sulfur added to the sediment was oxidized to sulfuric acid within the package which, in turn, solubilized the heavy metals. Here, the percolation flow and the solid-bed height did not affect the rate of metal solubilization. Solid-bed leaching on a larger scale will thus be much more efficient applying bioleaching with sulfur as the leaching agent than abiotic leaching with sulfuric acid.     

Caps yes,but how? A response to Alcott

This articles argues that extraction and emission caps are a promising strategy for a sustainable degrowth transition, but that their design and implementation is far from simple. We draw attention to the institutional structures and processes through which caps are to be set, designed and enforced, and discuss the danger of eco-authoritarian politics in the name of enforcing caps or other environmental limitations.     

Forest management policies and elk summer carrying capacity in theAbies amabilis forest,western Washington

Effects of different forest management policies on long-term vegetation development are incorporated into a computer simulation of a western Washington watershed. The response of a Rocky Mountain elk(Cervus canadensis nelsoni) population to these vegetation changes is simulated using information on their differential use of vegetation types. Simulations include: 1) a cessation of timber harvesting leading to an immediate decline in elk members resulting from a reduction in summer habitats; 2) a stable elk population, similar to the present one, resulting from a constant timber harvesting rate, and 3) initial increases in herd size, followed within 50 years by a sharp decrease, resulting from cutting all old growth timber within the next decade and then a cessation of timber harvestings.     

Channel change,sediment transport,and fish habitat in a coastal stream: Effects of an extreme event

A study on sediment transport and channel change was conducted on Zayante Creek and the lower San Lorenzo River in Santa Cruz County, California. A rainstorm with a recurrence interval locally in excess of 150 years occurred during the study year, 1982 WY. Stream surveys indicated that significant aggradation occurred during and after the peak flood. Upper study reaches were substantially recovered after high flows of early April, but the lower study reaches still had significant filling of pools and burial of riffles by sand. Increases in width-depth ratio were minor and localized in upper reaches, but were significant in lower reaches. Large inputs of sand, primarily from landsliding, altered the sediment transport regime. A higher proportion of the bedload is now transported by lower flows than before the January event. Roads and sand quarries contributed significantly to sediment input to the stream. A proposed dam may alter the sediment transport regime of Zayante Creek. Mitigating the effects of this dam on downstream fish habitat may require occasional bankfull discharges.     

Removal of PCDD/Fs and PCBs from sediment by oxygen free pyrolysis

Few studies have dealt on the evaluation of volatilization and decomposition reactions of dioxins from sediment by oxygen free pyrolysis. In this study, the performance of pyrolysis on the removal of dioxins from sediment was investigated. Dioxin concentrations of the raw sediment and the solid residues after pyrolysis were analyzed at different conditions. Results showed a removal efficiency of 99.9999% for total dioxins at 800℃ and retention time of 30 min. All the polychlorinated dibenzo-furans （PCDFs） have been removed and were not formed in the solid residues at the retention time range of 30-90 min at 800℃. Close to 100% removal of polychlorinated dibenzo-p-dioxins （PCDDs） was also achieved. Only trace PCDDs were detected in the solid yields at a retention time of 60 min. The highest removal efficiency of polychlorinated biphenyls （PCBs） was more than 99.9994% at a retention time of 30 min. During cooling period following pyrolysis, however, the concentration of total dioxins in solid residues increased 130 times as compared to that of the raw sediment under air atmosphere. This confirmed that some complex reactions do occur to form PCDD/Fs and PCBs from 800 to 400℃ in the presence of oxygen. Oxygen-free atmosphere therefore can prevent formation of dioxin during thermal process thus generating clean solid residues.     

Ecological distribution conflicts as forces for sustainability: an overview and conceptual framework

Can ecological distribution conflicts turn into forces for sustainability? This overview paper addresses in a systematic conceptual manner the question of why, through whom, how, and when conflicts over the use of the environment may take an active role in shaping transitions toward sustainability. It presents a conceptual framework that schematically maps out the linkages between (a) patterns of (unsustainable) social metabolism, (b) the emergence of ecological distribution conflicts, (c) the rise of environmental justice movements, and (d) their potential contributions for sustainability transitions. The ways how these four processes can influence each other are multi-faceted and often not a foretold story. Yet, ecological distribution conflicts can have an important role for sustainability, because they relentlessly bring to light conflicting values over the environment as well as unsustainable resource uses affecting people and the planet. Environmental justice movements, born out of such conflicts, become key actors in politicizing such unsustainable resource uses, but moreover, they take sometimes also radical actions to stop them. By drawing on creative forms of mobilizations and diverse repertoires of action to effectively reduce unsustainabilities, they can turn from ‘victims’ of environmental injustices into ‘warriors’ for sustainability. But when will improvements in sustainability be lasting? By looking at the overall dynamics between the four processes, we aim to foster a more systematic understanding of the dynamics and roles of ecological distribution conflicts within sustainability processes.     

LCA of selective waste collection systems in dense urban areas

This paper presents research concerning the environmental analysis of the selective collection management of municipal solid waste. The main goal of this study is to quantify and to compare, by means of Life Cycle Assessment (LCA), the potential environmental impacts of three selective collection systems modelled on densely populated urban areas. These systems are: the mobile pneumatic, the multi-container and the door-to-door. Impact assessment method based on CML 2 baseline 2000 is applied to the different systems. The study separates and analyzes the collection systems in substages: two urban substages and one inter-city substage. At the urban level, the multi-container system has the least environmental impact of all systems. The mobile pneumatic system has greater environmental impacts in terms of global warming, fresh water aquatic ecotoxicity, terrestrial ecotoxicity, acidification and eutrophication. In this system, the pipes and the pneumatic transport have the greatest impacts. The door-to-door system has a greatest environmental impact in terms of abiotic depletion, ozone layer depletion and human toxicity. An overall evaluation of the three substages, with a sensitivity analysis, indicates that the mobile pneumatic system at an inter-city distance of 20 km shows the greatest environmental impacts and the greatest energy demand. Inter-city transport is key; the results show that from an inter-city distance of 11 km onwards, this becomes the substage which most contributes to global warming impact and energy demand, in all the systems.     

Perception of the effects of climate change in winter and summer tourist areas: the Pyrenees and the Catalan and Balearic coasts,Spain

In this study, we compare the perception of climate change in two different tourist settings of northeastern Spain: the Catalan Pyrenees and the Catalan Mediterranean coast and the Balearic Islands. We carried out a survey of 906 cases (506 in the coastal areas of Catalonia and the Balearic Islands and 400 in the Catalan Pyrenees) asking residents on those areas to assess the possible effects of climate change on tourist-related activities. While the existence of climate change and of its estimated impacts is widely accepted, we observe statistically significant differences in most of the questions between residents in the coastal areas and residents in the Pyrenees. In general terms, respondents from the Pyrenees display a much higher concern regarding the economic impacts of climate change on tourism. On the other hand, the results also show that some demographic groups, such as women, members of large households, or unemployed, tend to present higher levels of concern. This study may give new hints on which tourist modalities and which groups are more concerned for the impacts of climate change in Mediterranean tourist environments and could translate into more targeted adaptive and mitigation practices.