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951.
952.
953.
Although standard methods of monitoring the progress of in-situ remediation may provide general results for the most permeable zones affected by soil vapor extraction or bioventing, they are essentially unsuccessful at providing information on the degree of heterogeneity within the remediation zone and on the existence of “hot spots.” Data are presented that suggest that monitoring the concentrations of fixed and biogenic gases and measuring soil permeability on a small-scale basis may circumvent the common problems associated with assessing the progress of in-situ remediation. The costs of these monitoring techniques are minor compared to those of designing and operating an in-situ remediation system, and may save additional time and costs by identifying problem areas early in the cleanup process. 相似文献
954.
A new process for enhancing in-situ remediation of low-permeability soil and rock formations is presently under development at the Hazardous Substance Management Research Center (HSMRC). The patented process, known as ?pneumatic fracturing,”? consists of injecting high-pressure air or other gas into contaminated geologic formations at controlled flow rates and pressures. In fine-grained soils such as clay, pneumatic fracturing creates conductive channels in the formation, thereby increasing the permeability and exposed surface area of the contaminated soil. The potential benefits of pneumatic fracturing are significant, since in-situ remedial technologies are essentially limited by the pore gas exchange rate of the soil being treated. This article describes the results of a recent demonstration of pneumatic fracturing at an industrial site to enhance a volatile organic compound (VOC) extraction system. After establishing the baseline removal rate of soil gas effluent from the clay, soil surrounding the extraction system was fractured to enhance VOC with drawal. A substantial improvement in the VOC removal rate was observed, including: (1) flush effluent concentrations that increased up to 200 times; and (2) air flows in the formation that increased up to 1,000 times. 相似文献
955.
Section 7(a)(2) of the Endangered Species Act directs federal agencies to ensure that their actions do not jeopardize the
continued existence of endangered and threatened species. The US Fish and Wildlife Service (USFWS) issues jeopardy or nonjeopardy
biological opinions on proposed federal actions that affect endangered and threatened species. We summarize several biological
opinions issued by the USFWS to protect the threatened piping plover (Charadrius melodus). These opinions address federal actions involving hundreds of piping plovers on the Missouri River system and a few piping
plover pairs on short stretches of Atlantic coast beach. Some of these opinions are decisive, but most allow the proposed
action to proceed conditional upon a lengthy set of reasonable and prudent alternatives to protect the piping plover. These
conditions may prove difficult to track and will add to the workload of the USFWS. 相似文献
956.
John Moir 《Journal of Environmental Planning and Management》1991,34(2):61-67
This paper traces the history of attempts to introduce National Parks into Scotland. In so doing it identifies some of the alternatives that have been considered and adopted. Finally, the paper analyses the failure of the movement to introduce National Parks into Scotland. 相似文献
957.
We inventoried wetland impoundments in the Louisiana, USA, coastal zone from the late 1900s to 1985. Historically, impoundment
of wetlands for reclamation resulted in direct wetland loss after levees (dikes) failed and the impounded area was permanently
flooded, reverting not to wetland, but to open-water habitat. A current management approach is to surround wetlands by levees
and water control structures, a practice termed semi-impoundment marsh management. The purpose of this semi-impoundment is
to retard saltwater intrusion and reduce water level fluctuations in an attempt to reduce wetland loss, which is a serious
problem in coastal Louisiana. In order to quantify the total impounded area, we used historic data and high-altitude infrared
photography to map coastal impoundments. Our goal was to produce a documented inventory of wetlands intentionally impounded
by levees in the coastal zone of Louisiana in order to provide a benchmark for further research.
We inventoried 370,658 ha within the coastal zone that had been intentionally impounded before 1985. This area is equal to
about 30% of the total wetland area in the coastal zone. Of that total area, approximately 12% (43,000 ha) is no longer impounded
(i.e., failed impoundments; levees no longer exist or only remnants remain). Of the 328,000 ha still impounded, about 65%
(214,000 ha) is developed (agriculture, aquaculture, urban and industrial development, and contained spoil). The remaining
35% (114,000 ha) of impoundments are in an undeveloped state (wetland or openwater habitat). In December 1985, approximately
50% (78,000 ha) of the undeveloped and failed impoundments were open-water habitat. This inventory will allow researchers
to monitor future change in land-water ratios that occur within impounded wetlands and thus to assess the utility of coastal
wetland management using impoundments. 相似文献
958.
Overview of case studies on recovery of aquatic systems from disturbance 总被引:13,自引:2,他引:13
Gerald J. Niemi Philip DeVore Naomi Detenbeck Debra Taylor Ann Lima John Pastor J. David Yount Robert J. Naiman 《Environmental management》1990,14(5):571-587
An extensive review of the published literature identified more than 150 case studies in which some aspect of resilience in
freshwater systems was reported. Approximately 79% of systems studied were lotic and the remainder lentic. Most of the stressor
types were chemical with DDT (N=29) and rotenone (N=15) the most common. The most common nonchemical stressors were logging
activity (N=16), flooding (N=8), dredging (N=3), and drought (N=7).
The variety of endpoints to which recovery could be measured ranged from sparse data for phytoplankton (N=13), periphyton
(N=6), and macrophytes (N=8) to relatively more data for fish (N=412) and macroinvertebrates (N=698). Unfortunately the same
characteristics were rarely measured consistently among sites. For example, with respect to fish, more than 30 different species
were studied and recovery was measured in many ways, most commonly on the basis of: (1) first reappearance of the species,
(2) return time of predisturbance densities, and (3) return time of predisturbance average individual size. Based on these
criteria, all systems in these studies seem to be resilient to most disturbances with most recovery times being less than
three years. Exceptions included when (1) the disturbance resulted in physical alteration of the existing habitat, (2) residual
pollutants remained in the system, or (3) the system was isolated and recolonization was suppressed. 相似文献
959.
960.
John E. Kemnitzer Richard A. Gross Stephen P. McCarthy John Liggat David J. Blundell Mike Cox 《Journal of Polymers and the Environment》1995,3(1):37-47
Predominantly syndiotactic poly(-hydroxybutyrate), syn-PHB, of variable syndioregularity (syndyad fractions 0.59, 0.62, 0.64, and 0.71) and molecular weight was prepared by the dibutyltin dimethoxide catalyzed ring opening of racemic-butyrolactone (BL). The crystallization behavior of the syn-PHB polymers was investigated by DSC and X-ray diffraction analyses. DSC of films after melting and annealing showed at least one, and often two distinct melting transitions occuring over a broad (often 40°C) temperature range. These results indicate that syn-PHB chain segments of variable syndioregularity form crystalline regions with very different thermodynamic stabilities. Maximum degrees of crystallinity for melt annealed 0.64- and 0.71-syn-PHB was observed at an annealing temperature (T
c
) of 30°C. AtT
c
values at 45°C and higher, crystallization of relatively lower syndioregular chain segments was apparently excluded to variable degrees dependent onT
c
and sample syndiotactic dyad content. After crystallization of syn-PHB samples at elevated temperatures, ambient temperature annealing resulted in an observed lower temperature melting transition at 50°C. This result showed little to no dependence on syn-PHB syndio-regularity andT
c
. Both solution precipitated 0.62-syn-PHB and 0.71-syn-PHB have WAXS patterns with poorly resolved crystalline reflections superimposed on amorphous haloes indicating low levels of crystallinity (17% and 25%, respectively) and poorly formed crystals. Isothermal crystallization monitored by DSC showed that the syn- and natural origin PHB showed fastest crystallization rates at temperatures between 50°C and 70°C and 60°C and 90°C, respectively. From the dependence of the higher melting transition onT
c
it was determined that the equilibrium melting temperatures for 0.62-syn-PHB (M
n
=83,700 g/mol) and a 0.64-syn-PHB (M
n
=11,900 g/mol) were 157 and 154°C, respectively. An Avrami analysis of syn-PHB yielded results similar to that found for natural origin PHB indicating that crystal growth occurs by a two-dimensional mechanism.Guest Editor: Dr. Graham Swift, Rohm & Haas. 相似文献