Preliminary Evaluation of the Use of Phosphogypsum for Reef Substrate. I. A Laboratory Study of Bioaccumulation of Radium and Six Heavy Metals in an Aquatic Food Chain

Phosphogypsum (PG), a solid by-product of phosphoric acid production, contains radionuclides and trace metals in concentrations which may pose a potential hazard to human health and the environment. to investigate the possibility of bioaccumulation of radium and six heavy metals over time when aquatic organisms experience both trophic and environmental exposure to PG, we designed a laboratory experiment representing three levels of an aquatic food chain. During the 135 day experiment, a meiobenthic copepod species (Amphiascoides atopus) was cultured in the presence of PG. the copepods were subsequently fed to grass shrimp (Palaemonetes vulgaris and P. pugio) which were in turn fed to gulf killifish (Fundulus grandis); both the grass shrimp and the killifish also experienced an environmental PG exposure. Other than elevated radium levels in the experimental grass shrimp, the experiment demonstrated little effect of environmental or trophic exposure to PG on microinvertebrates, macroinvertebrates, or fishes that could be attributed to PG. in all cases where increased concentrations were indicated within the experimental group, roughly equivalent increases in metal concentrations also occurred in the control group.     

An assessment of the air pollution data from two monitoring stations in Kuwait

This article assesses the air pollution data from two monitoring stations in Kuwait. The measurements cover major pollutants, i.e., CO, CO₂, methanated and non-methanated hydrocarbons, NO _x , SO₂, O₃, and particulate matter (PM10). The data also includes meteorological parameters, i.e., solar intensity, temperature, wind speed, and wind direction, and has been collected over a period 4 years, from 2001 to 2004. Data analysis includes the assessment of annual hourly averages and 1-h maxima. Typical pollutant concentration trends, similar to those previously reported for Kuwait and for other locations around the world, are observed except for particulate matter measurements, which have higher values because of proximity to the desert. Emissions of nitrogen oxides show a consistent increase over the years. This is caused by the increase in the number of motor vehicles and the expansion in power generation and industrial activities. The data collected is a subset of the air quality criteria, as defined by the US EPA (United States Environmental Protection Agency).     

Standard purity and response factors of perfluorinated compounds

It has been reported that the relative response factors of isotopically labeled standards and unlabeled standards of the same perfluorinated compounds could be different. Individual (100 ng mL^?1) solutions of perfluorooctanoic acid (PFOA) and perfluorooctane sulfonate (PFOS) were analyzed using high-performance liquid chromatography tandem mass-spectrometry under negative-ion electrospray to detect any impurities present down to 0.5%–0.1% relative to the major component. Purity of the standards ranged from approximately 86% to ≥ 97%. Standard solutions of unlabeled and isotopically labeled materials were analyzed to compare the response factors of isotopically labeled analytes versus their nonlabeled counterparts in three different matrices at equivalent concentrations: organic solvent (methanol), serum extract, and water present individually and concurrently. Not all labeled analytes have the same response factor as their nonlabeled complement, and in at least one case the matrix in which the standard is present may cause significant suppression of response. Standard solutions of electrochemical fluorination produced PFOA and PFOS were quantified under multiple reaction monitoring mode, using calibration curves prepared from standards consisting primarily of linear standards only. The use of linear only standards may cause under-prediction of concentrations, and that the working range of these standards may be limited.     

Measurement of watershed phosphorus: A review

Eutrophication control programs are based on phosphorus management which, in turn, requires a detailed quantification of the watershed phosphorus budget. This involves an assessment of non‐point sources of phosphorus, a key element of which is determining the fraction of soil‐P and sediment‐P available to support algal growth. This paper presents a review of the state‐of‐the‐art of estimating algal available‐P from non‐point sources, and an analysis of pertinent data. The need to employ multi‐interval algal bioassays in developing phosphorus management systems is stressed.     

Lead uptake by Eichhornia Crassipes

Factors influencing uptake of lead(II) by the water hyacinth (Eichhornia Crassipes), were examined. Two phases of uptake were observed for the concentration range investigated (0.01–1000 ppm). The initial, rapid uptake phase of about 4 hours is followed by a slower, near linear phase extending past 24 hours. Stirring the solution enhanced uptake, suggesting that lead removal is in part diffusion limited. In the range of 4–8, pH has little effect on uptake where as outside this range, uptake is reduced. Increased solution volume or rootmass results in more metal being removed by the plant. The presence of strong complexers blocks the initial rapid uptake phase as does the presence of Zn(II), Cd(II), Hg(II), and Fe(III). Strong complexers can also strip a portion of any lead already removed from solution by the plant.     

Comparative Toxicities of Polar and Non-Polar Organic Fractions From Sediments Affected By the Exxon Valdez Oil Spill in Prince William Sound,Alaska

Abstract

Standardized tests were applied to aromatic and polar fractions of sediment extracts to determine whether polar constituents or oxidative degradation products contributed significantly to the toxicity of sediments oiled by the Exxon Valdez spill. Intertidal sediment and pore-water samples were collected in September 1990 from two heavily oiled sites and an unoiled site in Prince William Sound (PWS). Methylene chloride extracts from these samples were fractionated by liquid chromatography into aliphatic, aromatic and polar fractions, and the aromatic and polar fractions were tested for toxicity using the Microtox^R test, bivalve larval mortality and development (Mytilus); several measures of genotoxicity in Mytilus, including SOS Chromotest^R, anaphase aberrations and sister chromatid exchange; and survival, anaphase aberrations and teratogenicity in coho salmon (Onchorhynchus kisutch). Microtox^R and SOS Chromotest^R protocols were applied in a screening mode to all samples, whereas other tests were applied only to selected fractions from two sites. Samples from Bay of Isles (oiled) were consistently more toxic (usually only 2 to 5-fold) than the Mooselips Bay (unoiled) samples, which gave very low responses in all tests. for both sites, however, responses to polar and aromatic fractions were about the same in most tests, suggesting that while the overall toxicity of the oil was low in these samples, at least part of that toxicity was derived from polar constituents. Compared to the parent hydrocarbons, polar oxidation products partition preferentially into pore-water and are more rapidly diluted and dispersed in the water column. These results suggest that polar oxidation products of petroleum hydrocarbons pose little risk to marine organisms, except possibly for infauna continuously exposed to pore-water in heavily oiled sediments. Independent surveys showed that sediment toxicity in PWS declined during 1989–1991 to near background levels, in accord with previous understanding of oil weathering and toxicity.     

Comparative aspects of mountain land resources management and sustainability: Case studies from India and Canada

India and Canada share a common heritage in natural resources management. Both have a colonial background, settlers and indigenous peoples; there is a history of management agencies with utilitarian attitudes, and a history of treating public lands as commodities for commerce rather than as resources for local livelihoods. This historical context guided the overall goal of this study, which was policy development for the sustainable use of mountain environments. Interviews, workshops and seminars were held with local people and resource management professionals in a comparative case study in two regions; the Kullu area in Himachal Pradesh, India and the Arrow Lakes area in British Columbia, Canada. The paper is organized around two main objectives of the work relating to the successes and failures of mountain environment resource management policies and the development of criteria for assessing and monitoring sustainability in mountain environments, in particular, criteria for examining relevant crosscultural dimensions of sustainable development in these environments. By way of conclusion the paper considers further ways in which traditional resource policy development and implementation is being challenged by changing values and priorities; ecosystems management with people; and co-management and public participation.     

Facilitating sustainable development in Chile: a survey of suitable energy technologies

Sustainable development in developing countries is the main aim of the Kyoto Protocol's Clean Development Mechanism (CDM). However, in the present context, uncertainty prevails as to whether the CDM is actually achieving its aims in terms of achieving sustainable development and to what extent. Chile has several renewable energy and energy efficiency options with significant greenhouse gas (GHG) emissions abatement potential that are not yet financially and economically competitive. In order to be able to identify potential CDM projects and to formulate a series of possible investment strategies with a sustainable development component, it is crucial to establish a clear understanding of the host country's needs and priorities and the suitable sustainable energy technologies to meet these needs. The main scope of this paper is to present results obtained from an elaborated stakeholder assessment on Chile's high priority energy needs and sustainable energy technologies fulfilling these needs in order to assist Chile in finding ways of encouraging technology transfer that would contribute to low-carbon sustainable energy development.     

Economics of additionality for environmental services from agriculture

We present a model of additionality for offsets sold from agriculture to industrial sector sources regulated by cap-and-trade. We consider a potential policy where agricultural sources would not be covered by cap-and-trade requirements but would be eligible to receive offsets whenever their emissions fall below a policy-specified baseline, and would not be penalized for emissions above their baseline. Major results are: (1) The optimal baseline should be set above the average counterfactual emissions of participating farms, an unexpected result that has been missing from the literature. (2) The optimal trading ratio should be greater than one (a ton of offsets counts for less than a ton of covered emissions) even under emissions certainty. Previous research has justified such trading ratios by emissions uncertainty. (3) Emissions uncertainty does not justify a change in the baseline if the accompanying emissions model is unbiased. (4) An optimal combination of policies is to subsidize offsets and tighten the baseline relative to the no-subsidy case.