Ecological effects of particulate matter

Atmospheric particulate matter (PM) is a heterogeneous material. Though regulated as un-speciated mass, it exerts most effects on vegetation and ecosystems by virtue of the mass loading of its chemical constituents. As this varies temporally and spatially, prediction of regional impacts remains difficult. Deposition of PM to vegetated surfaces depends on the size distribution of the particles and, to a lesser extent, on the chemistry. However, chemical loading of an ecosystem may be determined by the size distribution as different constituents dominate different size fractions. Coating with dust may cause abrasion and radiative heating, and may reduce the photosynthetically active photon flux reaching the photosynthetic tissues. Acidic and alkaline materials may cause leaf surface injury while other materials may be taken up across the cuticle. A more likely route for metabolic uptake and impact on vegetation and ecosystems is through the rhizosphere. PM deposited directly to the soil can influence nutrient cycling, especially that of nitrogen, through its effects on the rhizosphere bacteria and fungi. Alkaline cation and aluminum availability are dependent upon the pH of the soil that may be altered dramatically by deposition of various classes of PM. A regional effect of PM on ecosystems is linked to climate change. Increased PM may reduce radiation interception by plant canopies and may reduce precipitation through a variety of physical effects. At the present time, evidence does not support large regional threats due to un-speciated PM, though site-specific and constituent-specific effects can be readily identified. Interactions of PM with other pollutants and with components of climate change remain important areas of research in assessment of challenges to ecosystem stability.     

The Triad approach: A catalyst for maturing remediation practice

Many individual scientific and technical disciplines contribute to the multidisciplinary field of remediation science and practice. Because of the relative youth of this enterprise, disciplinary interests sometimes compete and conflict with the primary goal of achieving protective, cost‐effective, efficient projects. Convergence of viewpoints toward a more mature, common vision is needed. In addition, cleanup programs are changing under the influence of Brownfields initiatives and the needs of environmental insurance underwriters. Investigations and cleanups increasingly need to be affordable, yet transparent and defensible. Disciplinary goals and terminology need to better reflect real‐world site conditions while being more supportive of project needs. Yet, technical considerations alone will not ensure project success; better integration of human factors into project management is also required. The Triad approach is well placed to catalyze maturation of the remediation field because it emphasizes (1) a central theme of managing decision uncertainty; (2) unambiguous technical communications; (3) shortened project life‐cycles and multidisciplinary interactions that rapidly build professional expertise and provide feedback to test and perfect programmatic and field practices; and (4) concepts from “softer” sciences (such as economics, cognitive psychology, and decision theory) to capture important human factors. Triad pushes the cleanup industry toward an integrated, practical, second‐generation paradigm that can successfully manage the complexities of today's cleanup projects. © 2004 Wiley Periodicals, Inc.     

Pure-culture and enzymatic assay for starch-polyethylene degradable plastic biodegradation withStreptomyces species

Eleven starch-polyethylene degradable plastic films were prepared from masterbatches from Archer Daniels Midland Inc. (ADM), EcoStar Inc. (SLS), and Fully Compounded Plastic Inc. The biodegradability of initial and 70°C heat-treated materials was determined using a pure-culture assay withStreptomyces badius 252,S. setonii 75Vi2, orS. viridosporus T7A or without bacterial culture (control). Films were treated with 10-foldS. setonii culture concentrates and compared with inactive enzyme controls. Changes in each films mechanical property, molecular weight distribution, and Fourier-transformed infrared spectrum (FT-IR) were determined, and results were evaluated for significant differences by analysis of variance. Cell mass accumulation on each film was quite pronounced. In pure-culture studies, biodegradation was demonstrated for ADM-7 and SLS-2 initial films and for ADM-6 heat-treated films, whereas after 3-week treatment with activeS. setonii culture concentrates (enzyme assay), reductions in mechanical properties and changes in FT-IR spectrum were illustrated by all the films except SLS-2. Thus the absence of biofilm formation on the film surface permitted enzymatic attack of the materials. Furthermore, inhibition of chemical oxidative degradation in the pure-culture assay was demonstrated for ADM-11, SLS-5, and SLS-10 initial materials and for ADM-4, ADM-7, SLS-8, and SLS-10 heat-treated films. These data suggest that biological and chemical degradation were directly affected by the reduction in oxygen tension on the plastic film surface due to cell mass accumulation. This same phenomenon could be the cause for slow degradation rates in nature.Journal Paper No. J-15061 of the Iowa Agriculture and Home Economics Experiment Station, Ames, Iowa. Project Nos. 0178 and 2889.     

DESIGNATION OF WETLANDS BY WEIGHTED AVERAGES OF VEGETATION DATA: A PRELIMINARY EVALUATION1

ABSTRACT: Weighted averages (WA) was investigated as a vegetation-based method for wetland designation, to be used in conjunction with the wetland indicator status of plants from Wetland Plants of the United States of America 1986 (Reed, 1986). Ecological indices were assigned to indicator groups and were used to compute weighted averages for quantitative data obtained from four studies of wetland vegetation conducted in various regions of the United States. Weighted averages of vegetation data proved to be a useful tool for assessing wetland status of the vegetation types included in our study: (1) rankings of vegetation stands or types by WA correlated well with their positions on environmental moisture gradients; and (2) the results of WA could be used, together with a wetland/upland break-point, to designate vegetation types as wetland or upland in a way that agreed well, in three of the four studies, with an alternative classification of wetland habitats. The variation of weighted averages among the sampling units representing a vegetation type was generally small relative to the range of ecological indices assigned. However, designations based on weighted average scores close to the break-point should be considered provisional and must be verified with supplementary data on soils and hydrology.     

The use of regression equations for quality control in a pesticide physical property database

Quality control is a crucial aspect of database management, particularly for physicochemical parameters that are widely used in modeling environmental fate processes. Complete rechecking of original studies to verify environmental fate parameters is time consuming and difficult. This paper evaluates an alternative, more efficient approach to identifying database errors. The approach focuses verification efforts on a targeted subset of entries by making use of the relationship between water solubility (S) and soil organic carbon partition coefficient (K _oc ). Two regression equations, one selected from the literature and one calculated from entries in the database, were used to evaluate the reasonableness of (S, K _oc ) pairs among control compared to the targeted outlier group from a total of 59 pesticides. Our hypothesis was that (S, K _oc ) pairs that lay far from the regression line were more likely to be in error than those that fit the regression. Database values were checked against original studies. Identified errors in the database included coding mistakes, miscalculations, and incorrect chemical identification codes. The error rate in outlier (S, K _oc ) pairs was about twice that of pairs that conformed to the regression equation; however, the error rate differential was probably not large enough to justify the use of this quality control method. Through our close scrutiny of database entries we were able to identify administrative practices that led to mistakes in the data base. Resolution of these problems will significantly decrease the number of future mistakes.     

A case study of urban heat islands in the Carolinas

Urbanization tends to aggravate the negative effects of climate. The objective of this research is to aid in the understanding of the spatial variation of urban heat islands within selected cities in North and South Carolina. This understanding will help guide efforts to cool cities in order to increase human comfort, conserve energy and resources, and reduce air pollution in both of these states.     

MODELING THE LONG TERM IMPACTS OF USING RIGID STRUCTURES IN STREAM CHANNEL RESTORATION1

Abstract: Natural channel designs often incorporate rigid instream structures to protect channel banks, provide grade control, promote flow deflection, or otherwise improve channel stability. The long term impact of rigid structures on natural stream processes is relatively unknown. The objective of this study was to use long term alluvial channel modeling to evaluate the effect of rigid structures on channel processes and assess current and future stream channel stability. The study was conducted on Oliver Run, a small stream in Pennsylvania relocated due to highway construction. Field data were collected for one year along the 107 m reach to characterize the stream and provide model input, calibration, and verification data. FLUVIAL-12 was used to evaluate the long term impacts of rigid structures on natural channel adjustment, overall channel stability, and changing form and processes. Based on a consideration of model limitations and results, it was concluded that the presence of rigid structures reduced channel width-to-depth ratios, minimized bed elevation changes due to long term aggradation and degradation, limited lateral channel migration, and increased the mean bed material particle size throughout the reach. Results also showed how alluvial channel modeling can be used to improve the stream restoration design effort.     

DEVELOPMENT OF WATER QUALITY MANAGEMENT INDICES1

ABSTRACT: In a joint undertaking by The MITRE Corporation and the EPA Office of Water Programs Operations, three indices were developed: (1) An index of water quality; (2) An index of the need for abatement action; and (3) An index of the need for water quality management planning. These indices were evaluated for some 1000 planning areas (sub basins, regional planning jurisdictions, metropolitan areas, etc.) which together cover essentially all of the area of the 48 contiguous states.     

Characterization of Infiltration Rates from Landfills: Supporting Groundwater Modeling Efforts

The purpose of this paper is to review the literature to characterize infiltration rates from landfill liners to support groundwater modeling efforts. The focus of this investigation was on collecting studies that describe the performance of liners 'as installed' or 'as operated'. This document reviews the state of the science and practice on the infiltration rate through compacted clay liner (CCL) for 149 sites and geosynthetic clay liner (GCL) for 1 site. In addition, it reviews the leakage rate through geomembrane (GM) liners and composite liners for 259 sites. For compacted clay liners (CCL), there was limited information on infiltration rates (i.e., only 9 sites reported infiltration rates.), thus, it was difficult to develop a national distribution. The field hydraulic conductivities for natural clay liners range from 1 x 10(-9) cm s(-1) to 1 x 10(-4) cm s(-1), with an average of 6.5 x 10(-8) cm s(-1). There was limited information on geosynthetic clay liner. For composite lined and geomembrane systems, the leak detection system flow rates were utilized. The average monthly flow rate for composite liners ranged from 0-32 lphd for geomembrane and GCL systems to 0 to 1410 lphd for geomembrane and CCL systems. The increased infiltration for the geomembrane and CCL system may be attributed to consolidation water from the clay.