World diamond industry: 1970–2000

The diamond cartel has remained effective in controlling diamond supplies and prices for a longer period than any other major minerals cartel in the twentieth century. This paper examines the diamond pipeline from mine to the jewellery market. Particular attention is given to the characteristics of diamonds and of the industry structure that make the long-term stability of the cartel possible. The strategies of De Beers Consolidated Diamond Mines in controlling rough gem supplies and prices are examined, and projections are made to 2000. The paper shows that in spite of a projected decrease in the share of total diamond production sold through the De Beers' cartel in the 1990s, the cartel is expected to continue effectively to control supplies and prices.     

Case study: Browning-ferris industries' computerized system for managing audit and environment performance

While some companies have established scoring systems within their audit programs, few utilize the full potential for measurement of the information gathered and subsequently produced from audits. In this article, the use of a computerized tracking system developed and used by Browning-Ferris Industries is discussed, along with a data report that details the completion of audit items and helps assure that action plans resulting from environmental audits are completed. This and other summary reports from the computer tracking system have provided meaningful measures of individual facilities' and overall company performance.     

COMPARISON OF PROCESS‐BASED AND ARTIFICIAL NEURAL NETWORK APPROACHES FOR STREAMFLOW MODELING IN AN AGRICULTURAL WATERSHED1

ABSTRACT: The performance of the Soil and Water Assessment Tool (SWAT) and artificial neural network (ANN) models in simulating hydrologic response was assessed in an agricultural watershed in southeastern Pennsylvania. All of the performance evaluation measures including Nash‐Sutcliffe coefficient of efficiency (E) and coefficient of determination (R²) suggest that the ANN monthly predictions were closer to the observed flows than the monthly predictions from the SWAT model. More specifically, monthly streamflow E and R² were 0.54 and 0.57, respectively, for the SWAT model calibration period, and 0.71 and 0.75, respectively, for the ANN model training period. For the validation period, these values were ?0.17 and 0.34 for the SWAT and 0.43 and 0.45 for the ANN model. SWAT model performance was affected by snowmelt events during winter months and by the model's inability to adequately simulate base flows. Even though this and other studies using ANN models suggest that these models provide a viable alternative approach for hydrologic and water quality modeling, ANN models in their current form are not spatially distributed watershed modeling systems. However, considering the promising performance of the simple ANN model, this study suggests that the ANN approach warrants further development to explicitly address the spatial distribution of hydrologic/water quality processes within watersheds.     

Software tools to support incident reporting in safety-critical systems

Incident reporting systems are playing an increasingly important role in the development and maintenance of safety-critical applications. The perceived success of the FAA's Aviation Safety Reporting System (ASRS) and the FDA's MedWatch has led to the establishment of similar national and international schemes. These enable individuals and groups to report their safety concerns in a confidential or anonymous manner. Unfortunately, many of these systems are becoming victims of their own success. The ASRS and MedWatch have both now received over 500,000 submissions. In consequence, the administrators of incident reporting systems increasingly rely upon software tools to support the administration of their systems. In the past, these systems have relied upon ad hoc applications of conventional database technology. However, there are several reasons why this technology is inadequate for many large-scale reporting schemes. In particular, the problems of query formation often result in poor precision and recall. This, in turn, has profound implications for safety-critical applications. Users may fail to identify similar incidents within national or international collections. These ad hoc approaches also neglect the opportunities provided by recent developments in computer assisted interviewing and in the monitoring of retrieval activities to build models of user behavior. These techniques offer a number of potential benefits. For instance, it is possible to automatically detect potential biases in the way that investigators analyze particular incidents.     

Visualizing reductive dechlorination in support of intrinsic bioremediation using multivariate plots and GIS

Demonstrating intrinsic bioremediation requires not only that the right types of evidence be gathered, but also that those data be analyzed at an appropriate level of detail and presented in a manner that clearly illustrates the key trends to the target audience. The goal of this study was to develop one type of multivariate pattern diagram, the pie diagram, for clearly and efficiently presenting data demonstrating the occurrence of reductive dechlorination at sites contaminated by chlorinated ethenes. The pie diagrams were created using normalized ethenes molar concentrations to estimate and illustrate the changes in the concentrations of contaminants and metabolic intermediates that could be attributed to biodegradative processes. Spatial pie‐diagram maps illustrating the normalized chlorinated‐ethenes data were produced using geographic information system (GIS) software. Application of this visualization tool is demonstrated using an example data set and is compared with a conventional x‐y graph of the data. The trends elucidated on the basis of the pie diagrams, coupled with additional site evidence of natural attenuation (e.g., electron donor and acceptor data), are shown to provide a consistent interpretation of the site data. © 2002 Wiley Periodicals, Inc.     

Regional Representativeness of Swedish Reference Lakes

/ Recent focus has been placed on ecoregion delineations for providing an appropriate framework for monitoring and assessment of region-specific attainable water/habitat quality. Using an ecoregion approach to stratify variance, this study was conducted to determine whether earlier (subjectively) selected Swedish reference lakes may be considered as regionally representative reference sites when compared with a randomly selected lake population. Predictive modeling by discriminant function analysis with lakes classified by ecoregion and lake surface area and six physicochemical variables showed that the greater majority of reference lakes may be considered as regionally representative. The highest proportion of lake "misclassifications" occurred in the boreonemoral ecoregion, a relatively diverse ecoregion of southern Sweden. This apparent bias may be in part be due to the criteria used in selecting regional reference lakes. In the earlier selection of reference lakes emphasis was placed on lakes not being adversely affected by land usage or pollutant discharges, consequently forest lakes were often overrepresented and sites in agricultural areas underrepresented in the selected reference sites. As a complement to predictive modeling, PCA ordination showed the placement of reference lakes within the random lake population and indicated where reference sites might be missing along potentially important ecological gradients. KEY WORDS: Regionalization; Ecoregion; Representativeness; Reference; Ordination; Modeling; Temperate lakes     

Diel variation of TCO2 in the upper layer of oceanic waters reflects microbial composition,variation and possibly methane cycling

Six diel TCO₂ cycles determined by infrared (IR) photometry from five drift stations occupied between 24 February and 16 March 1979 in the mixed layer of the northwestern Caribbean Sea are examined. Comparison of TCO₂ variation with coincident salinity and O₂ variation demonstrated that TCO₂ often co-varied with these independently measured variables. During five diel cycles TCO₂ variation was characterized by nocturnal production and diurnal consumption. The inverse, diurnal production of CO₂, occurred downstream from Misteriosa Bank, whose corals apparently contributed to a water mass having a twofold increase of POC and a sixfold larger population of heterotrophic nanoplankters. For the five diel studies carried out in waters with balanced or nearly blanced heterotrophic and phototrophic components of the nanoplankton, CO₂ consumption at constant salinity always occurred between 06.00 and 09.00 hrs. Net uptake often continued through 15.00 hrs, but not always in the absence of significant salinity changes. At constant salinity net O₂ evolution never exceeded 0.5 mol l^-1 h^-1 while net CO₂ uptake consistently averaged 3 mol l^-1 h^-1 for an apparent net production of 36 mg C m^-3 h^-1, which greatly exceeds the O₂ changes and open ocean ¹⁴C estimates from the literature. Diurnal consumption was apparently balanced by nocturnal production of CO₂ so that no significant net daily change in TCO₂ was observed. Departures from theoretical PQ and RQ and the possibility of nocturnal variations in formaldehyde and carbonate alkalinity imply that chemotrophs, both methane producers and methane oxidizers, play a significant role in CO₂ cycling. This could be through the metabolism of the nonconservative gases CH₄, CO, and H₂, and a link between chemotrophy and phototrophy through these gases is hypothesized. These open system measurements were subject to diffusion and documentable patchiness, but temporal TCO₂ changes appear to indicate the net direction of microbiological activity and join a growing body of literature showing dynamic variation in CO₂ and O₂ that exceeds estimates by ¹⁴C bottle assays of carbon fixation.     

Dissolved phosphorus retention and release from a coastal plain in-stream wetland

Dissolved phosphorus (DP) can be released from wetlands as a result of flooding or shifts in water column concentrations. Our objectives were to determine the long-term (1460 d) DP retention and release characteristics of an in-stream wetland, and to evaluate how these characteristics respond to flooding, draining, and changes in DP concentrations. The studied in-stream wetland drains an agriculturally intensive subwatershed in the North Carolina Coastal Plain region. The wetland's DP retention and release characteristics were evaluated by measuring inflow and outflow DP concentrations, DP mass balance, and DP movement across the sediment-water column interface. Phosphorus sorption isotherms were measured to determine the sediment's equilibria P concentration (EPCo), and passive samplers were used to measure sediment pore water DP concentrations. Initially, the in-stream wetland was undersized (0.31 ha) and released 1.5 kg of DP. Increasing the in-stream wetland area to 0.67 ha by flooding resulted in more DP retention (28 kg) and low outflow DP concentrations. Draining the in-stream wetland from 0.67 to 0.33 ha caused the release of stored DP (12.1 kg). Shifts both in sediment pore water DP concentrations and sediment EPCo values corroborate the release of stored DP. Reflooding the wetland from 0.33 to 0.85 ha caused additional release of stored DP into the outflowing stream (10.9 kg). We conclude that for a time period, this in-stream wetland did provide DP retention. During other time periods, DP was released due to changes in wetland area, rainfall, and DP concentrations.