全文获取类型
收费全文 | 2073篇 |
免费 | 37篇 |
国内免费 | 54篇 |
专业分类
安全科学 | 76篇 |
废物处理 | 105篇 |
环保管理 | 301篇 |
综合类 | 328篇 |
基础理论 | 559篇 |
环境理论 | 1篇 |
污染及防治 | 510篇 |
评价与监测 | 134篇 |
社会与环境 | 134篇 |
灾害及防治 | 16篇 |
出版年
2023年 | 18篇 |
2022年 | 62篇 |
2021年 | 22篇 |
2020年 | 29篇 |
2019年 | 32篇 |
2018年 | 75篇 |
2017年 | 59篇 |
2016年 | 52篇 |
2015年 | 72篇 |
2014年 | 64篇 |
2013年 | 165篇 |
2012年 | 77篇 |
2011年 | 110篇 |
2010年 | 100篇 |
2009年 | 103篇 |
2008年 | 104篇 |
2007年 | 99篇 |
2006年 | 73篇 |
2005年 | 64篇 |
2004年 | 96篇 |
2003年 | 85篇 |
2002年 | 61篇 |
2001年 | 111篇 |
2000年 | 50篇 |
1999年 | 34篇 |
1998年 | 25篇 |
1997年 | 22篇 |
1996年 | 12篇 |
1995年 | 27篇 |
1994年 | 12篇 |
1993年 | 13篇 |
1992年 | 19篇 |
1991年 | 12篇 |
1990年 | 15篇 |
1989年 | 15篇 |
1988年 | 7篇 |
1987年 | 10篇 |
1985年 | 9篇 |
1984年 | 11篇 |
1983年 | 11篇 |
1982年 | 8篇 |
1980年 | 7篇 |
1979年 | 6篇 |
1975年 | 8篇 |
1974年 | 10篇 |
1973年 | 7篇 |
1972年 | 12篇 |
1971年 | 6篇 |
1959年 | 5篇 |
1957年 | 5篇 |
排序方式: 共有2164条查询结果,搜索用时 343 毫秒
861.
This field study was conducted to explore the spatial and seasonal changes in total phosphorus and fraction distribution in relation to land uses. Water samples were collected biweekly at four sampling locations, which represented different potential phosphorus sources along the Upper Peruque Creek in Eastern Missouri. Total phosphorus concentrations of > 0.8 mg/L appeared sporadically at site 2, downstream of a small community, with an average of 0.82 +/- 0.14 mg/L in fall. Particulate phosphorus accounted for approximately 80% of total phosphorus at all sampling sites, except for site 2, where approximately 50 to 75% of dissolved phosphorus was often observed. Approximately 71 and 85% of total phosphorus in the sediment was in the form of iron (III) phosphate at the headwaters and downstream sites, respectively; 29 and 15% was in the form of phytic acid at the two sites. Land uses affect the total phosphorus concentration and alternate phosphorus fraction and speciation in the creek. 相似文献
862.
Liu ZG Berg DR Schauer JJ 《Journal of the Air & Waste Management Association (1995)》2008,58(10):1258-1265
The effects of a zeolite urea-selective catalytic reduction (SCR) aftertreatment system on a comprehensive spectrum of chemical species from diesel engine emissions were investigated in this study. Representative samples were collected with a newly developed source dilution sampling system after an aging process designed to simulate atmospheric dilution and cooling conditions. Samples were analyzed with established procedures and compared between the measurements taken from a baseline heavy-duty diesel engine and also from the same engine equipped with the exhaust aftertreatment system. The results have shown significant reductions for nitrogen oxides (NOx), carbon monoxide, total hydrocarbons, polycyclic aromatic hydrocarbons (PAHs), and organic carbon (OC) emissions. Additionally, less significant yet notable reductions were observed for particulate matter mass and metals emissions. Furthermore, the production of new species was not observed with the addition of the zeolite urea-SCR system joined with a downstream oxidation catalyst. 相似文献
863.
In an earlier paper the ozone-forming potential of n-propyl bromide (NPB) was studied with a new methodology designed to address issues associated with a marginal smog-forming compound. However, the U.S. Environmental Protection Agency (EPA) subsequently revised its policy and now recommends using the Maximum Incremental Reactivity (MIR) scale to rank the ozone-forming potential of all volatile organic compounds (VOCs), including those of marginal ozone productivity. Nevertheless, EPA contemplated exceptions to the box-model-derived MIR scale by allowing use of photochemical grid-model simulations for case specific reactivity assessments. The California Air Resources Board (CARB) also uses the MIR scale and CARB has a Reactivity Scientific Advisory Committee that can consider exceptions to the MIR scale. In this study, grid-model simulations that were recommended by EPA are used to evaluate the incremental ozone impacts of NPB using an update to the chemical mechanism developed in an earlier paper. New methods of analysis of the grid-model output are further developed here to quantify the relative reactivities between NPB and ethane over a wide range of conditions. The new grid-model-based analyses show that NPB is significantly different and generally less in ozone-forming potential (i.e., reactivity) than predicted by the box-model-based MIR scale relative to ethane, EPA's "bright-line" test for non-VOC status. Although NPB has low reactivity compared to typical VOCs on any scale, the new grid-model analyses developed here show that NPB is far less reactive (and even has negative reactivity) compared to the reactivity predicted by the MIR scale. 相似文献
864.
Relationship between atmospheric pollution processes and synoptic pressure patterns in northern China 总被引:3,自引:0,他引:3
Z.H. Chen S.Y. Cheng J.B. Li X.R. Guo W.H. Wang D.S. Chen 《Atmospheric environment (Oxford, England : 1994)》2008,42(24):6078-6087
The air pollution index (API) sequences in 10 cities in northern China and the synoptic pressure patterns during autumn and winter from 2002 to 2006 were analyzed with diagnostic and statistical methods. The results showed that the air qualities in northern China had a prominent correlation with the pressure systems. It revealed that (a) the increasing phase of API was associated with high pressure and the successive low pressure, (b) the preceding part of front (i.e. the retral part of low pressure) was associated with the maximum of API values during a cycle of air pollution process, (c) the pressure systems with high gradient led to the decrease of API, and (d) the synoptic pressure patterns and their evolvements were the main causes of regional air pollution processes. These relations can be used to analyze the variation characteristics and mechanism of regional atmosphere pollution process, and provide important basis for the qualitative prediction, control, and management of regional air pollution problems. 相似文献
865.
Validation of photosynthetic-fluorescence parameters as biomarkers for isoproturon toxic effect on alga Scenedesmus obliquus 总被引:1,自引:0,他引:1
Dewez D Didur O Vincent-Héroux J Popovic R 《Environmental pollution (Barking, Essex : 1987)》2008,151(1):93-100
Photosynthetic-fluorescence parameters were investigated to be used as valid biomarkers of toxicity when alga Scenedesmus obliquus was exposed to isoproturon [3-(4-isopropylphenyl)-1,1-dimethylurea] effect. Chlorophyll fluorescence induction of algal cells treated with isoproturon showed inactivation of photosystem II (PSII) reaction centers and strong inhibition of PSII electron transport. A linear correlation was found (R2>or=0.861) between the change of cells density affected by isoproturon and the change of effective PSII quantum yield (PhiM'), photochemical quenching (qP) and relative photochemical quenching (qP(rel)) values. The cells density was also linearly dependent (R2=0.838) on the relative unquenched fluorescence parameter (UQF(rel)). Non-linear correlation was found (R2=0.937) only between cells density and the energy transfer efficiency from absorbed light to PSII reaction center (ABS/RC). The order of sensitivity determined by the EC-50% was: UQF(rel)>PhiM'>qP>qP(rel)>ABS/RC. Correlations between cells density and those photosynthetic-fluorescence parameters provide supporting evidence to use them as biomarkers of toxicity for environmental pollutants. 相似文献
866.
Tillmann A Englert A Nyari Z Fejes I Vanderborght J Vereecken H 《Journal of contaminant hydrology》2008,95(1-2):57-75
A Cone Penetration Test (CPT) survey with a high spatial resolution was performed in order to investigate the stratigraphy as well as the spatial variability of various soil properties of the Krauthausen test site. Analyses of the CPT measurements showed the subsurface to be dominated by a planar layered structure. Variogram analysis of the various CPT parameters disclosed that within each layer the soil properties have an anisotropic spatial correlation structure. A correlation analysis of the measured CPT data and co-located grain size distributions from soil samples was performed. Since the correlation coefficients were greater equal to 0.7, a reliable empirical relationship between the data sets could be developed. Based on this empirical relationship grain size distributions were estimated at CPT locations. The statistical processing of estimated and measured grain size distributions with respect to their spatial correlation structure disclosed good agreement between the data sets. The estimated grain size distributions from CPT data were used to estimate the hydraulic conductivity in the aquifer. The results provide detailed information of the spatial heterogeneity of the hydraulic conductivity at Krauthausen test site. The validation of these results, using a prior investigation of hydraulic conductivity statistics, suggests the CPT a fast and inexpensive tool for the estimation of three dimensional hydraulic conductivity fields with sufficient accuracy. 相似文献
867.
Kinetic adsorption of application of carbon nanotubes for Pb(II) removal from aqueous solution 总被引:1,自引:0,他引:1
Nassereldeen A Kabbashi Muataz A Atieh Abdullah Al-Mamun Mohamed E S Mirghami MD Z Alam Noorahayu Yahya 《环境科学学报(英文版)》2009,21(4)
The capability of carbon nanotubes (CNTs) to adsorb lead (Pb) in aqueous solution was investigated. Batch mode adsorption experiment was conducted to determine the effects of pH, agitation speed, CNTs dosage and contact time. The removal of Pb(II) was reach to maximum value 85% or 83% at pH 5 or 40 mg/L of CNTs, respectively. Higher correlation coefficients from Langmuir isotherm model indicates the strong adsorptions of Pb(II) on the surface of CNTs (adsorption capacity Xm = 102.04 mg/g). From this study, the results indicates that the highest percentage removal of Pb (96.03%) can be achieved at pH 5, 40 mg/L of CNTs, contact time 80 min, and agitation speed 50 r/min. 相似文献
868.
IntroductionNitrogen(N)andphosphorus(P)inmunicipalsewage ,whichmainlycomefromdomesticwastewaterandsomeindustrialwastewater,willcausemanyharmsandrestrictthenormalfunctionofwaterenvironmentafterenterthewaterbody .Theproblemofnitrogenanphosphoruspollutionha… 相似文献
869.
Laiz L Miller AZ Jurado V Akatova E Sanchez-Moral S Gonzalez JM Dionísio A Macedo MF Saiz-Jimenez C 《Die Naturwissenschaften》2009,96(1):71-79
In the last few years, the microbial colonisation of mural paintings in ancient monuments has been attracting the attention
of microbiologists and conservators. The genus Rubrobacter is commonly found in biodeteriorated monuments, where it has been reported to cause rosy discolouration. However, to date,
only three species of this genus have been isolated, all from thermophilic environments. In this paper, we studied three monuments:
the Servilia and Postumio tombs in the Roman Necropolis of Carmona (Spain), and Vilar de Frades church (Portugal), in search
of Rubrobacter strains. In all cases, biodeterioration and the formation of efflorescences were observed, and five Rubrobacter strains were isolated. These isolates showed different physiology and migration in denaturing gradient gel electrophoresis,
suggesting they might represent new species within this genus. The isolates reproduced some biodeterioration processes in
the laboratory and revealed their biomediation in crystal formation. 相似文献
870.