Metal exposures in an inner-city neonatal population

ObjectivesWe measured concentrations of lead (Pb), manganese (Mn), chromium (Cr), and copper (Cu) in umbilical cord whole blood and examined sources of environmental Pb exposures in a predominantly African-American population.MethodsBetween April and July 2006, we collected reproductive histories, questionnaires, and blood samples from 102 women, aged 16–45 years, who delivered at a Memphis, TN hospital.ResultsThe prevalence of preeclampsia and low birth weight infancy in the study population was 11% and 10%, respectively. Twenty-eight percent of mothers reported living near a potential Pb-contaminated area, while 43% lived in a residence built before 1978. Geometric mean (GM) concentrations for umbilical cord blood in the study population were 1.3, 3.5, 9.0, and 52.0 µg/dL for Pb, Mn, Cr, and Cu, respectively. Six neonates had cord blood Pb (CBL) concentrations above 10 µg/dL, while 20 had CBL concentrations ≥ 2 µg/dL. GM umbilical CBL levels were higher in neonates born to women living near a potential Pb-contaminated area (2.2 vs. 1.1 µg/dL) and those with friends, family or household members exposed to lead products (1.6 vs. 1.1 μg/dL). Some evidence of an exposure–response relationship was also detected between all four metal concentrations and an increasing number of maternal lead exposures. After adjustment for confounding, proximity to a Pb-contaminated area was the strongest environmental determinant of CBL levels among neonates with CBL concentrations of ≥ 2 µg/dL (odds ratio = 5.1; 95% CI = 1.6, 16.7).ConclusionsMetal concentrations were elevated in this population, and CBL levels were associated with proximity to Pb-contaminated areas.     

Use of Predictive Weather Uncertainties in an Irrigation Scheduling Tool Part I: A Review of Metrics and Adjoint Methods

Irrigation management consists of many components. In this work we review and recommend rainfall forecast performance metrics and adjoint methodologies for the use of predictive weather data within the Colorado State University Water Irrigation Scheduler for Efficient Application (WISE). WISE estimates crop water uses to optimize irrigation scheduling. WISE and its components, input requirements, and related software design issues are discussed. The use of predictive weather allows WISE to consider economic opportunity‐costs of decisions to defer water application if rainfall is forecast. These capabilities require an assessment of the system uncertainties and use of weather prediction performance probabilities. Rainfall forecasts and verification performance metrics are reviewed. In addition, model data assimilation methods and adjoint sensitivity concepts are introduced. These assimilation methods make use of observational uncertainties and can link performance metrics to space and time considerations. We conclude with implementation guidance, summaries of available data sources, and recommend a novel adjoint method to address the complex physical linkages and model sensitivities between space and time within the irrigation scheduling physics as a function of soil depth. Such tool improvements can then be used to improve water management decision performance to better conserve and utilize limited water resources for productive use. Editor’s note : This paper is part of the featured series on Optimizing Ogallala Aquifer Water Use to Sustain Food Systems. See the February 2019 issue for the introduction and background to the series.     

Monitoring and assessment of wetlands using Earth Observation: the GlobWetland project

The overall objective of the Ramsar Convention, signed in 1971, is the conservation and wise use of wetlands by national action and international cooperation as a means to achieving sustainable development. This complex and challenging task requires national, local and international bodies involved in the implementation of the convention to rely on suitable geo-information to better understand wetland areas, complete national inventories, perform monitoring activities, carry out assessments and put in practice suitable management plans based on updated and reliable information. In the last years, Earth Observation (EO) technology has been revealed as a key tool and unique information source to support the environmental community in different application domains, including wetlands' conservation and management. In this context, the European Space Agency (ESA) in collaboration with the Ramsar Secretariat launched in 2003 the "GlobWetland" project in order to demonstrate the current capabilities of Earth Observation technology to support inventorying, monitoring, and assessment of wetland ecosystems. This paper collects the main results and findings of the "GlobWetland" project, providing an overview of the current capabilities and limits of EO technology as a tool to support the implementation of the Ramsar Convention. The project was carried out in collaboration with several regional, national and local conservation authorities and wetland managers, involving 50 different wetlands across 21 countries on four continents. This large range of users provided an excellent test bed to assess the potential of this technology to be applied in different technical, economic and social conditions.     

How do long-term development and periodical changes of river-floodplain systems affect the fate of contaminants? Results from European rivers

In many densely populated areas, riverine floodplains have been strongly impacted and degraded by river channelization and flood protection dikes. Floodplains act as buffers for flood water and as filters for nutrients and pollutants carried with river water and sediment from upstream source areas. Based on results of the EU-funded “AquaTerra” project (2004-2009), we analyze changes in the dynamics of European river-floodplain systems over different temporal scales and assess their effects on contaminant behaviour and ecosystem functioning. We find that human-induced changes in the hydrologic regime of rivers have direct and severe consequences on nutrient cycling and contaminant retention in adjacent floodplains. We point out the complex interactions of contaminants with nutrient availability and other physico-chemical characteristics (pH, organic matter) in determining ecotoxicity and habitat quality, and draw conclusions for improved floodplain management.     

Study of the spatial variation of the biodegradation rate of the herbicide bentazone with soil depth using contrasting incubation methods

Vertical and horizontal spatial variability in the biodegradation of the herbicide bentazone was compared in sandy-loam soil from an agricultural field using sieved soil and intact soil cores. An initial experiment compared degradation at five depths between 0 and 80 cm using sieved soil. Degradation was shown to follow the first-order kinetics, and time to 50% degradation (DT(50)), declined progressively with soil depth from 56 d at 0-10 cm to 520 d at 70-80 cm. DT(50) was significantly correlated with organic matter, pH and dehydrogenase activity. In a subsequent experiment, degradation rate was compared after 127 d in sieved soil and intact cores from 0 to 10 and 50 to 60 cm depth from 10 locations across a 160x90 m portion of the field. Method of incubation significantly affected mean dissipation rate, although there were relatively small differences in the amount of pesticide remaining in intact cores and sieved soil, accounting for between 4.6% and 10.6% of that added. Spatial variability in degradation rate was higher in soil from 0 to 10 cm depth relative to that from 50 and 60 cm depth in both sieved soil and intact core assessments. Patterns of spatial variability measured using cores and sieved soil were similar at 50-60 cm, but not at 0-10 cm depth. This could reflect loss of environmental context following processing of sieved soil. In particular, moisture content, which was controlled in sieved soil, was found to be variable in cores, and was significantly correlated with degradation rate in intact topsoil cores from 0 to 10 cm depth.     

Environmental benefits and economic costs of manure incorporation on dairy waste application fields

Model simulations performed representing dairies in a 93000 ha watershed in north central Texas suggest that manure incorporation results in reduced phosphorus (P) losses at relatively small to moderate cost to producers. Simulated manure incorporation with a tandem disk on fields double-cropped with sorghum/winter wheat resulted in up to 33, 45, and 37% reductions in per hectare sediment-bound, soluble, and total P losses in edge-of-field runoff, relative to simulated surface manure applications. The effects of incorporation were evaluated at three different manure application rates. On aggregate across all three manure application rates, significant declines in P losses were obtained with incorporation except for sediment-bound P losses under the N-based manure application rate scenario.We found that the practice of incorporating manure shortly after it has been broadcast on the soil surface could help reduce P losses in such situations where P-based rates alone prove inadequate. The cost the producer incurs when manure is incorporated is on average about 1% of net returns when manure is applied at the N rate and 2-3% when it is applied at alternative P-based rates. In practice the costs could be lower because producers may substitute the manure incorporation operation for a tandem disk operation performed prior to manure application. As more and more dairy producers switch to the use of sorghum and corn silage in dairy rations and consequent on-farm production of these forages, the practice of manure incorporation may help to reduce phosphorus losses resulting from dairy manure applications to fields with these forage crops.     

北京市西北城区取暖期环境大气中PM10的物理化学特征

根据监测资料探讨了北京市西北城区取暖期PM₁₀的逐日变化规律和日变化规律.分别使用X射线衍射仪(XRD)和扫描电镜(SEM)研究PM₁₀中的矿物成分及其微观形貌特征.结果表明夜间PM₁₀浓度普遍高于白天.XRD分析显示颗粒物粒度越细,其中所含的矿物种类越少.SEM研究得出,单个PM₁₀颗粒类型可初步分为有链状集合体、簇状集合体、圆球状、片状和不规则形状等5类.从数量上看,PM₁₀主要来自燃煤和汽车尾气.     

Ecological niche and in-situ control of MIB producers in source water

Odor problems in source water caused by 2-methylisoborneol (MIB) have been a common issue in China recently, posing a high risk to drinking water safety. The earthy-musty odorant MIB has an extremely low odor threshold (4–16 ng/L) and is hard to remove via conventional processes in drinking water plants (DWP), and therefore could easily provoke complaints from consumers. This compound is produced by a group of filamentous cyanobacteria, mainly belonging to Oscillatoriales. Different from the well-studied surface-blooming Microcystis, filamentous cyanobacteria have specific niche characteristics that allow them to stay at a subsurface or deep layer in the water column. The underwater bloom of these MIB producers is therefore passively determined by the underwater light availability, which is governed by the cell density of surface scum. This suggests that drinking water reservoirs with relatively low nutrient contents are not able to support surface blooms, but are a fairly good fit to the specialized ecological niche of filamentous cyanobacteria; this could explain the widespread odor problems in source water. At present, MIB is mainly treated in DWP using advanced treatment processes and/or activated carbon, but these post-treatment methods have high cost, and not able to deal with water containing high MIB concentrations. Thus, in situ control of MIB producers in source water is an effective complement and is desirable. Lowering the underwater light availability is a possible measure to control MIB producers according to their niche characteristics, which can be obtained by either changing the water level or other measures.     

Restoration of the Kissimmee River, Florida: Water Quality Impacts from Canal Backfilling

The planned restoration of the Kissimmee River ecocystem will backfill approximately 35 km of flood control canal (C-38) that cuts through the meandering river channel, re-establish natural flow patterns, and restore the river/floodplain ecosystem. Water quality monitoring, including nutrients, total suspended solids (TSS), turbidity, dissolved oxygen (DO), and mercury, was conducted during a pilot `test fill' project to determine if soil disturbance during canal backfilling would negatively impact these water quality constituents. Surface water nutrient concentrations varied little between sites. Generally, highest concentrations occurred prior to construction, with lowest concentrations occurring during and after construction. During construction, TSS concentrations increased at sites immediately upstream, downstream, and adjacent to the construction area. Increased turbidity was generally restricted to areas immediately upstream and downstream of the test plug, with maximum levels occurring during the initial construction phase. Some downstream increases in turbidity were observed; however, impacts were short-term, lasting less than 24 h. Depresssed DO levels (<2 mg/l) were observed upstream of the test plug following completion of the initial plug across C-38. Dissolved oxygen levels remained low for approximately 6 weeks, with no apparent ecological impacts. Total mercury (HgT) within canal sediment ranged from 9.2–180 ng/g and methylmercury concentrations ranged from 0.037–0.708 ng/g. Concentration of total mercury and total methylmercury (MeHgT) in the backfill material were much lower than concentrations in the canal sediment. No significant change in aqueous HgT concentrations occurred over the sampling period, although construction-induced turbidity could have temporarily caused a slightly elevated concentration immediately downstream of the construction site. Methylmercury concentrations in the water column ranged from 0.033–0.518 ng/l. No significant differences in mean MeHgT concentrations occured between sites or between sampling dates, except at one downstream site where MeHgT declined significantly over the sampling period.     

Identifying ozone-sensitive communities of (semi-)natural vegetation suitable for mapping exceedance of critical levels

Using published data on the responses of individual species to ozone, 54 EUNIS (European Nature Information System) level 4 communities with six or more ozone-sensitive species (%OS) and c. 20% or more species tested for ozone sensitivity, were identified as potentially ozone-sensitive. The largest number of these communities (23) was associated with Grasslands, with Heathland, scrub and tundra, and Mires, bogs and fens having the next highest representation at 11 and 8 level 4 communities each respectively. Within the grasslands classification, E4 (Alpine and sub-alpine grasslands), E5 (Woodland fringes and clearings) and E1 (Dry grasslands) were the most sensitive with 68.1, 51.6 and 48.6%OS respectively. It is feasible to map the land-cover for these and other communities at level 2, but it may not be currently possible to map the land-cover for all communities identified to be ozone-sensitive at levels 3 and 4.