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51.
Per-and polyfluoroalkyl substances(PFASs) are ubiquitous in sludge and water from waste water treatment plants, as a result of their incorporation in everyday products and industrial processes. In this study, we measured several classes of persistent PFASs,precursors, transformation intermediates, and newly identified PFASs in influent and effluent sewage water and sludge from three municipal waste water treatment plants in Sweden, sampled in 2015. For sludge, samples from 2012 and 2014 were analyzed as well.Levels of precursors in sludge exceeded those of perfluoroalkyl acids and sulfonic acids(PFCAs and PFSAs), in 2015 the sum of polyfluoroalkyl phosphoric acid esters(PAPs) were 15–20 ng/g dry weight, the sum of fluorotelomer sulfonic acids(FTSAs) was 0.8–1.3 ng/g,and the sum of perfluorooctane sulfonamides and ethanols ranged from non-detected to 3.2 ng/g. Persistent PFSAs and PFCAs were detected at 1.9–3.9 ng/g and 2.4–7.3 ng/g dry weight, respectively. The influence of precursor compounds was further demonstrated by an observed substantial increase for a majority of the persistent PFCAs and PFSAs in water after waste water treatment. Perfluorohexanoic acid(PFHxA), perfluorooctanoic acid(PFOA), perfluorohexane sulfonic acid(PFHxS), and perfluorooctane sulfonic acid(PFOS)had a net mass increase in all WWTPs, with mean values of 83%, 28%, 37% and 58%,respectively. The load of precursors and intermediates in influent water and sludge combined with net mass increase support the hypothesis that degradation of precursor compounds is a significant contributor to PFAS contamination in the environment. 相似文献
52.
Formic acid was used for the nitrate reduction as a reductant in the presence of Pd:Cu/γ-alumina catalysts. The surface characteristics of the bimetallic catalyst synthesized by wet impregnation were investigated by SEM, TEM-EDS. The metals were not distributed homogeneously on the surface of catalyst, although the total contents of both metals in particles agreed well with the theoretical values. Formic acid decomposition on the catalyst surface, its influence on solution pH and nitrate removal efficacy was investigated. The best removal of nitrate (50 ppm) was obtained under the condition of 0.75 g/L catalyst with Pd:Cu ratio (4:1) and two fold excess of formic acid. Formic acid decay patterns resembled those of nitrate removal, showing a linear relationship between kf (formic acid decay) and k (nitrate removal). Negligible amount of ammonia was detected, and no nitrite was detected, possibly due to buffering effect of bicarbonate that is in situ produced by the decomposition of formic acid, and due to the sustained release of H2 gas. 相似文献
53.
Jingzhou Zhao Hang Li Hongseok Choi Wayne Cai Jeffrey A. Abell Xiaochun Li 《Journal of Manufacturing Processes》2013,15(1):136-140
Real-time monitoring and control of temperature in ultrasonic joining of battery tabs and coupons are important for the quality improvement and cost reduction of battery assembly. However, there have always been difficulties in accurate and real-time measurement of temperature by conventional sensors for practical implementation. In this study, an innovative method is developed to provide an enabling technology for the in situ transient temperature monitoring, which could provide reliable feedback signals for potential control of ultrasonic joining processes. Micro thin film thermocouples (TFTCs) were fabricated on thin silicon substrates, which were then inserted in the welding anvil as a permanent feature so that the sensors were always located about 100 μm directly under the welding spot during joining of multilayer Ni-coated Cu thin sheets for battery assembly. Good repeatability was demonstrated while a temperature rise of up to 650 °C was obtained due to the closeness of the sensors to the welding spot. The inserts with thin film sensors remained functional after welding experiments. This method has a great potential for in situ transient temperature monitoring, and thus the control of ultrasonic joining processes to realize a practical smart joining system. 相似文献
54.
Antonella?De?DonnoEmail author Tiziana?Grassi Francesco?Bagordo Adele?Idolo Francesca?Serio Giovanni?Gabutti 《Food and environmental virology》2012,4(2):81-88
The purpose of this study was to demonstrate that shellfish can be used to detect enteric viruses in marine waters where they
are present at very low concentrations. Aqua-cultured mussels were placed in the sea just off the mouth of a drainage channel
affected by human and animal faecal contamination. Samples were taken from the channel, the sea and the mussels at intervals
over two 4-week periods. The samples were tested to verify the presence of both rotaviruses and E. coli. Rotaviruses were detected by Real Time-PCR, typed by multiplex PCR and subsequently sequenced. E. coli was enumerated in water matrices by a filtering method and in mussels by the MPN method. The presence of E. coli in the examined matrices demonstrates contamination of faecal origin throughout the studied environments. Rotaviruses were
recorded in channel waters, but not in sea water. In both experiments, rotaviruses were detected in mussels 21 and 28 days
after being placed in the sea water off the channel mouth. The use of mussels thus enabled the detection of rotaviruses in
waters where the high dilution rendered direct investigation impossible. This study indicates that mussels can be used in
marine virological surveillance programs. 相似文献
55.
Simon?BrinerEmail author Michael?Hartmann Robert?Finger Bernard?Lehmann 《Mitigation and Adaptation Strategies for Global Change》2012,17(4):337-355
We assessed the economic suitability of 4 greenhouse gas (GHG) mitigation options and one GHG offset option for an improvement
of the GHG balance of a representative Swiss suckler cow farm housing 35 Livestock units and cultivating 25 ha grassland.
GHG emissions per kilogram meat in the economic optimum differ between the production systems and range from 18 to 21.9 kg
CO2-eq./kg meat. Only GHG offset by agroforestry systems showed the potential to significantly reduce these emissions. Depending
on the production system agroforestry systems could reduce net GHG emissions by 66% to 7.3 kg CO2-eq./kg meat in the most intensive system and by 100% in the most extensive system. In this calculation a carbon sequestration
rate of 8 t CO2/ha/year was assumed. The potential of a combination of the addition of lipids to the diet, a cover of the slurry tank and
the application of nitrification inhibitors only had the potential to reduce GHG emissions by 12% thereby marginal abatement
costs are increasing much faster than for agroforestry systems. A reduction of the GHG emissions to 7.5 kg CO2-eq./kg meat—possible with agroforestry only—raised costs between 0.03 CHF/kg meat and 0.38 CHF/kg meat depending on the production
system and the state of the system before the reduction. If GHG emissions were reduced maximally average costs ranged between
0.37 CHF/kg meat, if agroforestry had the potential to reduce net GHG emissions to 0 kg CO2-eq., to 1.17 CHF/kg meat if also other options had to be applied. 相似文献
56.
Population dynamics and regulation in the cave salamander <Emphasis Type="Italic">Speleomantes strinatii</Emphasis> 总被引:1,自引:0,他引:1
Salvidio S 《Die Naturwissenschaften》2007,94(5):396-400
Time series analysis has been used to evaluate the mechanisms regulating population dynamics of mammals and insects, but has
been rarely applied to amphibian populations. In this study, the influence of endogenous (density-dependent) and exogenous
(density-independent) factors regulating population dynamics of the terrestrial plethodontid salamander Speleomantes strinatii was analysed by means of time series and multiple regression analyses. During the period 1993–2005, S. strinatii population abundance, estimated by a standardised temporary removal method, displayed relatively low fluctuations, and the
autocorrelation function (ACF) analysis showed that the time series had a noncyclic structure. The partial rate correlation
function (PRCF) indicated that a strong first-order negative feedback dominated the endogenous dynamics. Stepwise multiple
regression analysis showed that the only climatic factor influencing population growth rate was the minimum winter temperature.
Thus, at least during the study period, endogenous, density-dependent negative feedback was the main factor affecting the
growth rate of the salamander population, whereas stochastic environmental variables, such as temperature and rainfall, seemed
to play a minor role in regulation. These results stress the importance of considering both exogenous and endogenous factors
when analysing amphibian long-term population dynamics. 相似文献
57.
Vullo R 《Die Naturwissenschaften》2011,98(6):545-549
Sharks are known to have been ammonoid predators, as indicated by analysis of bite marks or coprolite contents. However, body
fossil associations attesting to this predator–prey relationship have never been described so far. Here, I report a unique
finding from the Late Jurassic of western France: a complete specimen of the Kimmeridgian ammonite Orthaspidoceras bearing one tooth of the hybodont shark Planohybodus. Some possible tooth puncture marks are also observed. This is the first direct evidence of such a trophic link between these
two major Mesozoic groups, allowing an accurate identification of both organisms. Although Planohybodus displays a tearing-type dentition generally assumed to have been especially adapted for large unshelled prey, our discovery
clearly shows that this shark was also able to attack robust ammonites such as aspidoceratids. The direct evidence presented
here provides new insights into the Mesozoic marine ecosystem food webs. 相似文献
58.
Some emerging technologies are expected to be pivotal for solving many of the environmental challenges faced today, especially those related to energy. However, many of these technologies may incur significant environmental impacts over their life cycle, while having environmental benefits during their use. This paper presents results of a Life Cycle Assessment (LCA) of a proposed type of nanophotovoltaic, quantum dot photovoltaic (QDPV) module. The LCA is confined to the stages of raw materials acquisition, manufacturing, and use. The impacts of QDPV are compared with other types of PV modules and energy sources - both renewable and nonrenewable. To provide a comprehensive comparative assessment, QDPV modules were compared with mature as well as emerging PV types for which data are available. Comparative assessment with other types of energy sources includes coal, oil, lignite, natural gas, diesel, nuclear, wind, and hydropower.QDPV modules may have the potential to overcome two current barriers of solar technology: low efficiencies and high manufacturing costs. If higher efficiencies are realized, QDPV modules could pave the way to large scale implementation of solar energy, helping nations move toward greater energy independence. On the other hand, candidate materials as quantum dots for solar cell applications are mostly compound semiconductors such as cadmium selenide, cadmium telluride, and lead sulfide which may be toxic and for which renewable options are limited. Toxic effects of these materials may be exacerbated by their nanoscale features.The LCA was carried out using the software SimaPro, and the Ecoinvent Life Cycle Inventory (LCI) database supplemented with available literature and patent information. Our results indicate that while QDPV modules have shorter Energy PayBack Time (EPBT), lower Global Warming Potential (GWP), SOx and NOx emissions than other types of PV modules, they have higher heavy metal emissions, underscoring the need for investigation of emerging technologies, especially nano-based ones, from a life cycle perspective. QDPV modules are better in all impact categories assessed than carbon-based energy sources but they have longer EPBT than wind and hydropower and higher GWP. 相似文献
59.
Predicting the transfer of 137Cs to rice plants by a dynamic compartment model with a consideration of the soil properties 总被引:1,自引:0,他引:1
The factors governing chlorine transfer from Phaeozem and Greyzem soils to various important crop species (foodstuff and forage) were determined in natural conditions in the Kiev region of Ukraine. The stable chlorine concentration ratio (CR) values were the lowest in apple (0.5+/-0.3) and strawberry (2+/-1), higher in vegetables (5+/-3), seeds (15+/-7) and reached a maximum in straw (187+/-90). The average CR values of 36Cl were estimated for the most important crops using all experimental data on 36Cl and stable chlorine transfer into plants from various soils. It was experimentally shown that boiling potatoes in water leads to an equilibrium between 36Cl specific content in the water and moisture in the cooked potato. The 36Cl processing factor (PF) for boiling various foodstuffs is equal to the ratio of water mass in the cooked foodstuff to the total water mass (in the food and the decoction). 36Cl PF for cereal flour can be estimated as 1. The 36Cl processing factor for dairy products is equal to the ratio of residual water mass in the product to initial water mass in milk. At a 36Cl specific activity in soil of 1 Bq kg-1, the estimated annual dietary 36Cl intake into human organism (adult man) is about 10 kBq. Sixty to seventy percent of the above amount will be taken in via milk and dairy products, 7-16% via meat, 14-16% via bread and bakery items and 8-12% via vegetables. The highest annual 36Cl intake, 10.7 kBq, is predicted for 1-year-old children. The expected effective doses from annual 36Cl intake are higher for younger age groups, increasing from 0.008 mSv in adults to 0.12 mSv in 1-year-old children. 相似文献
60.
Seepage from Hg mine wastes and calcines contains high concentrations of mercury (Hg). Hg pollution is a major environmental
problem in areas with abandoned mercury mines and retorting units. This study evaluates factors, especially the hydrological and
sedimentary variables, governing temporal and spatial variation in levels and state of mercury in streams impacted by Hg contaminated
runo . Samples were taken during di erent flow regimes in theWanshan Hg mining area in Guizhou Province, China. In its headwaters
the sampled streams/rivers pass by several mine wastes and calcines with high concentration of Hg. Seepage causes serious Hg
contamination to the downstream area. Concentrations of Hg in water samples showed significant seasonal variations. Periods of
higher flow showed high concentrations of total Hg (THg) in water due to more particles being re-suspended and transported. The
concentrations of major anions (e.g., Cl??, F??, NO3?? and SO4
2??) were lower during higher flow due to dilution. Due to both sedimentation
of particles and dilution from tributaries the concentration of THg decreased from 2100 ng/L to background levels (< 50 ng/L) within
10 km distance downstream. Sedimentation is the main reason for the fast decrease of the concentration, it accounts for 69% and 60%
for higher flow and lower flow regimes respectively in the upper part of the stream. Speciation calculation of the dissolved Hg fraction
(DHg) (using Visual MINTEQ) showed that Hg(OH)2 associated with dissolved organic matter is the main form of Hg in dissolved
phase in surface waters in Wanshan (over 95%). 相似文献