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21.
Comoretto L Arfib B Talva R Chauvelon P Pichaud M Chiron S Höhener P 《Environmental pollution (Barking, Essex : 1987)》2008,151(3):486-493
A field study on the runoff of pesticides was conducted during the cultivation period in 2004 on a hydraulically isolated rice farm of 120 ha surface with one central water outlet. Four pesticides were studied: Alphamethrin, MCPA, Oxadiazon, and Pretilachlor. Alphamethrin concentrations in runoff never exceeded 0.001 microg L(-1). The three other pesticides were found in concentrations between 5.2 and 28.2 microg L(-1) in the runoff water shortly after the application and decreased thereafter. The data for MCPA compared reasonably well with predictions by an analytical runoff model, accounting for volatilization, degradation, leaching to groundwater, and sorption to soil. The runoff model estimated that runoff accounted for as much as 18-42% of mass loss for MCPA. Less runoff is observed and predicted for Oxadiazon and Pretilachlor. It was concluded that runoff from rice paddies carries important loads of dissolved pesticides to the wetlands in the Ile de Camargue, and that the model can be used to predict this runoff. 相似文献
22.
Brouyère S Batlle-Aguilar J Goderniaux P Dassargues A 《Journal of contaminant hydrology》2008,95(3-4):121-140
Quantification of pollutant mass fluxes is essential for assessing the impact of contaminated sites on their surrounding environment, particularly on adjacent surface water bodies. In this context, it is essential to quantify but also to be able to monitor the variations with time of Darcy fluxes in relation with changes in hydrogeological conditions and groundwater - surface water interactions. A new tracer technique is proposed that generalizes the single-well point dilution method to the case of finite volumes of tracer fluid and water flush. It is called the Finite Volume Point Dilution Method (FVPDM). It is based on an analytical solution derived from a mathematical model proposed recently to accurately model tracer injection into a well. Using a non-dimensional formulation of the analytical solution, a sensitivity analysis is performed on the concentration evolution in the injection well, according to tracer injection conditions and well-aquifer interactions. Based on this analysis, optimised field techniques and interpretation methods are proposed. The new tracer technique is easier to implement in the field than the classical point dilution method while it further allows monitoring temporal changes of the magnitude of estimated Darcy fluxes, which is not the case for the former technique. The new technique was applied to two experimental sites with contrasting objectives, geological and hydrogeological conditions, and field equipment facilities. In both cases, field tracer concentrations monitored in the injection wells were used to fit the calculated modelled concentrations by adjusting the apparent Darcy flux crossing the well screens. Modelling results are very satisfactory and indicate that the methodology is efficient and accurate, with a wide range of potential applications in different environments and experimental conditions, including the monitoring with time of changes in Darcy fluxes. 相似文献
23.
24.
Manuela Carneiro Bruno Colaço Ricardo Brandão Carla Ferreira Nuno Santos Vanessa Soeiro Aura Colaço Maria João Pires Paula A. Oliveira Santiago Lavín 《Environmental monitoring and assessment》2014,186(11):7011-7021
The accumulation of heavy metals in the environment may have a wide range of health effects on animals and humans. Thus, in this study, the concentrations of arsenic (As), cadmium (Cd), lead (Pb), and mercury (Hg) in the blood and tissues (liver and kidney) of Portuguese common buzzards (Buteo buteo) were determined by inductively coupled plasma-mass spectrometer (ICP-MS) in order to monitor environmental pollution to these elements. In general, Hg and As were the elements which appeared in the highest and lowest concentrations, respectively. A highest percentage of non-detected concentration was found for blood Cd (94.6 %) but, in turn, it was the only metal that was detected in all kidney samples. The kidney was the analyzed sample which showed the highest concentrations of each element evaluated. Statistically, significant differences among blood, liver, and kidney samples were observed for As and Cd (P?0.05). Cd concentrations in kidney and liver varied significantly with age: Adults showed higher hepatic and renal Cd concentrations than juveniles. Blood Pb concentration seems to show an association with the hunting season. Although raptors are at the top of the food chain and are thus potentially exposed to any biomagnification processes that may occur in a food web, the individuals evaluated in this study generally had low levels of heavy metals in blood and tissues. However, chronic exposure to these metals was verified. The results presented here lend weight to arguments in favor of continuous biomonitoring of metals and metalloids, since heavy metals may accumulate to levels that will pose a risk to both human health and the environment. 相似文献
25.
de Figueiredo DR Ferreira RV Cerqueira M de Melo TC Pereira MJ Castro BB Correia A 《Environmental monitoring and assessment》2012,184(1):471-485
The information on bacterial community composition (BCC) in Portuguese water bodies is very scarce. Cértima River (central
western Portugal) is known to have high levels of pollution, namely organic. In the present work, the BCC from a set of 16
water samples collected from Cértima River Basin and its main tributaries was characterized using 16S rDNA–denaturing gradient
gel electrophoresis, a culture-independent molecular approach. Molecular data were related to environmental parameters through
multivariate analysis to investigate potential impact of water pollution along the river. Principal component analysis using
environmental data showed a water quality gradient from more pristine waters (at the mountain tributaries) to waters with
increasingly eutrophic potential (such as Fermentelos Lake). This gradient was mainly defined by factors such as organic and
inorganic nutrient sources, electrical conductivity, hydrogen carbonate concentration, and pH. Molecular results showed variations
in BCC along Cértima River Basin but in the main river section, a Bacteroidetes phylotype (Flavobacterium sp.) proved to be dominant throughout the river course. Multivariate analysis suggests that spatial variation of BCC along
the Cértima River Basin depended mainly on parameters such as Chl a, total suspended solid (TSS), total organic carbon, electrical conductivity, and HCO
_boxclose^-_{3}^{-} levels. Bacteroidetes phylotypes were all related to higher electrical conductivity and HCO3-_{3}^{-} levels although some of these were also correlated with high SO42-_{4}^{2-} and others with high soluble reactive phosphorus, nitrate, TN, and Kjeld-N levels. The Gammaproteobacteria occurrence was correlated with high SO42-_{4}^{2-} levels. One of the Betaproteobacteria phylotypes showed to correlate with low redox potential (Eh) and high temperature, pH, TSS, and Chl a levels while another one showed a negative correlation with Chl a values. 相似文献
26.
This article sets out to analyse how and to what degree land use is linked to the physical characteristics of the territory
itself, and the way in which changes in land use are determined by agricultural and socio-demographic dynamics. The study
was conducted within the territorial boundaries of five municipalities surrounding Lake Trasimeno and refers to the periods
1977–2000 for land use and 1971–2001 for socio-demography data. The use of environmental, social, economic and agricultural
indicators demonstrates how a mix of various indicators are useful for monitoring the changes which took place. It also shows
the powerful influence that socio-demographic factors exert upon land use and landscape change. 相似文献
27.
Ana L. De Toffoli Bruno H. Fumes 《Journal of environmental science and health. Part. B》2018,53(7):434-440
On-line in-tube solid phase microextraction (in-tube SPME) coupled to high performance liquid chromatography and tandem mass spectrometry (HPLC-MS/MS) was successfully applied to the determination of selected triazines in water samples. The method based on the employment of a packed column containing graphene oxide (GO) supported on aminopropyl silica (Si) showed that the extraction phase has a high potential for triazines extraction aiming to its physical-chemical properties including ultrahigh specific surface area, good mechanical and thermal stability and high fracture strength. Injection volume and loading time were both investigated and optimized. The method validation using Si-GO to extract and concentrate the analytes showed satisfactory results, good sensitivity, good linearity (0.2–4.0 µg L?1) and low detection limits (1.1–2.9 ng L?1). The high extraction efficiency was determined with enrichment factors ranging from 1.2–2.9 for the lowest level, 1.3–4.9 intermediate level and 1.2–3.0 highest level (n = 3). Although the analytes were not detected in the real samples evaluated, the method has demonstrated to be efficient through its application in the analysis of spiked triazines in ground and mineral water samples. 相似文献
28.
Md. Badiuzzaman Khan Mauro Masiol Caterina Bruno Alberto Pasqualetto Gian Maria Formenton Claudio Agostinelli Bruno Pavoni 《Environmental science and pollution research international》2018,25(32):31987-32000
A yearlong sampling campaign (2012–2013) was conducted in six major cities of the Veneto region to investigate the spatial-temporal trends and the factors affecting the polycyclic aromatic hydrocarbon (PAHs) variations and identify the local sources. Sixty samples per city were collected for analyses in every alternate month (April, June, August, October, December, and February): 10 samples per sampling site in 10 consecutive days of the months selected. Samples were ultrasonically extracted with acetonitrile and processed through high-performance liquid chromatography. Total Σ-PAH concentrations ranged from 0.19 to 70.4 ng m?3 with a mean concentration of 11.5 ng m?3. The mean benzo[a]pyrene (BaP) concentration reached 2.0 ng m?3, which is two-times higher than the limit set by the European Union. BaP contributed for 17.4% to the total concentration of PAHs, which showed the same pattern across the region with maxima during cold months and minima in the warm period. In this study, PAHs showed an inverse relationship with temperature, solar radiation, wind speed, and ozone. According to this study, biomass burning for household heating and cooking, followed by gaseous PAHs absorption on particles due to low atmospheric temperature, were the main reasons for increasing PAHs concentration in winter. Health risk, evaluated as lifetime lung cancer risk (LCR), showed a potential carcinogenic risk from the airborne BaPTEQ six-fold higher in the cold season than in the warm one. Diagnostic ratios and conditional probability functions were used to locate the sources, and results confirmed that local emission, overall domestic heating, and road transport exhausts were responsible for higher concentration rates of PAHs as well as of PM2.5. 相似文献
29.
Benito-Garzón Marta Fady Bruno Davi Hendrik Vizcaíno-Palomar Natalia Fernández-Manjarrés Juan 《Regional Environmental Change》2018,18(5):1427-1437
Regional Environmental Change - The adaptation of social-ecological systems such as managed forests depends largely on decisions taken by forest managers who must choose among a wide range of... 相似文献
30.
Ultrasound effects on the activity of Aspergillus niger lipases in their application in dairy wastewater treatment
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Simone M. Golunski Jessica Mulinari Aline Frumi Camargo Bruno Venturin Daiane P. Baldissarelli Camila Torbes Marques Gean D. L. P. Vargas Luciane Maria Colla Altemir Mossi Helen Treichel 《环境质量管理》2017,27(1):95-101
We evaluated the effect of ultrasound radiation on lipase activity. The experiments were conducted using a low‐cost crude enzyme extract. We then used this lipase to treat dairy effluent. The results of our study presented an increase of approximately 430% in the concentration of free fatty acids. 相似文献