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501.
Use of Descriptors of Ecosystem Functioning for Monitoring a National Park Network: A Remote Sensing Approach 总被引:1,自引:0,他引:1
Baseline assessments and monitoring of protected areas are essential for making management decisions, evaluating the effectiveness
of management practices, and tracking the effects of global changes. For these purposes, the analysis of functional attributes
of ecosystems (i.e., different aspects of the exchange of matter and energy) has advantages over the traditional use of structural
attributes, like a quicker response to disturbances and the fact that they are easily monitored through remote sensing. In
this study, we described the spatiotemporal patterns of different aspects of the ecosystem functioning of the Spanish national
parks and their response to environmental changes between 1982 and 2006. To do so, we used the NOAA/AVHRR-GIMMS dataset of
the Normalized Difference Vegetation Index (NDVI), a linear estimator of the fraction of photosynthetic active radiation intercepted
by vegetation, which is the main control of carbon gains. Nearly all parks have significantly changed during the last 25 years:
The radiation interception has increased, the contrast between the growing and nongrowing seasons has diminished, and the
dates of maximum and minimum interception have advanced. Some parks concentrated more changes than others and the degree of
change varied depending on their different environmental conditions, management, and conservation histories. Our approach
identified reference conditions and temporal changes for different aspects of ecosystem functioning, which can be used for
management purposes of protected areas in response to global changes. 相似文献
502.
A compilation has been undertaken of data which can be used to derive animal product transfer coefficients for radionuclides, including an extensive review of Russian language information. The resultant database has been used to provide recommended transfer coefficient values for a range of radionuclides to (i) cow, sheep and goat milk, (ii) meat (muscle) of cattle, sheep, goats, pigs and poultry and (iii) eggs. The values are used in a new IAEA handbook on transfer parameters which replaces that referred to as ‘TRS 364’. The paper outlines the approaches and procedures used to identify and collate data, and assumptions used. There are notable differences between the TRS 364 ‘expected’ values and the recommended values in the revised Handbook from the new database. Of the recommended values, three milk values are at least an order of magnitude higher than the TRS 364 values (Cr, Pu (cow) Pu (sheep)) and one milk value is lower (Ni (cow)). For meat, four values (Am, Cd, Sb (beef) I (pork)) are at least an order of magnitude higher than the TRS 364 values and eight values are at least an order of magnitude lower (Ru, Pu (beef), Ru, Sr, Zn (sheep), Ru, Sr (pork), Mn (poultry)). Many data gaps remain. 相似文献
503.
Mohammednoor Altarawneh Daniel Carrizo Artur Ziolkowski Eric M. Kennedy Bogdan Z. Dlugogorski John C. Mackie 《Chemosphere》2009,74(11):1435-1443
This article reports the computational and experimental results of the thermal decomposition of permethrin, a potential source of dibenzo-p-dioxins (PCDD) and polychlorinated dibenzofurans (PCDF). We have performed a quantum chemical analysis by applying density functional theory to obtain the decomposition pathways of permethrin and the formation mechanism of dibenzofuran. We have conducted the pyrolysis experiments in a tubular reactor and identified the pyrolysis products to demonstrate the agreement between the experimental measurements and quantum chemical calculations. The initiation of the decomposition of permethrin involves principally the aromatisation of permethrin into 3-phenoxyphenylacetic acid, 2-methylphenyl ester (J) and concomitant loss of 2HCl. This rearrangement is followed by the rupture of the O–CH2 linkage in J, with a rate constant derived from the quantum chemical results of 1 × 1015 exp(−68 kcal/mol/RT) s−1 for temperatures between 700 and 1300 K. This is confirmed by finding that the rate constant for unimolecular rearrangement of permethrin into J is 1.2 × 1012 exp(−53 kcal/mol/RT) s−1 over the same range of temperatures and exceeds the direct fission rate constant at all temperatures up to 850 ± 120 °C as well as by the experimental detection of J prior to the detection of the initial products incorporating diphenyl ether, 1-methyl-3-phenoxybenzene, 3-phenoxybenzaldehyde and 1-chloromethyl-3-phenoxybenzene. As the temperature increases, we observe a rise in secondary products formed directly or indirectly (via phenol/phenoxy) including aromatics (naphthalene), biphenyls (biphenyl, 4-methyl-1,1′-biphenyl) and dibenzofuran (DF). In particular, we discover by means of quantum chemistry a direct route from 2-phenoxyphenoxy to naphthalene. We detect no polychlorinated dibenzo-p-dioxins and dibenzofurans. Unlike the case of oxidative pyrolysis [Tame, N.W., Dlugogorski, B.Z., Kennedy, E.M., 2007b. Formation of dioxins in fires of arsenic-free treated wood: Role of organic preservatives. Environ. Sci. Technol. 41, 6425–6432] where significant yields of both PCDD and PCDF were obtained, under non-oxidative conditions the thermal decomposition of permethrin does not form appreciable amounts of PCDD or PCDF and the presence of oxygen (and/or a sizable radical pool) appears necessary for the formation of dibenzo-p-dioxin itself or PCDD/F from phenol/phenoxy. 相似文献
504.
The herbicide paraquat induces alterations in the elemental and biochemical composition of non-target microalgal species 总被引:1,自引:0,他引:1
Huge quantities of pesticides are dispersed in the environment, affecting non-target organisms. Since paraquat affects the photosynthetic process, the biochemical composition of affected species should be altered. The effect of paraquat on Chlamydomonas moewusii, a freshwater non-target species, was studied. After 48 h of herbicide exposure, growth rate, dry weight, and chlorophyll a and protein content were affected by paraquat concentrations above 0.05 μM. C/N ratio was also affected due to a decrease in nitrogen content in the dry biomass, while the carbon content remained constant for all paraquat concentrations assayed. Enzymes involved in nitrogen assimilation were affected by paraquat, being nitrate reductase activity more sensitive to paraquat than nitrite reductase. Based on the results obtained in the present study, paraquat exerts adverse effects upon a common freshwater green microalga, thus the application of this herbicide for weed control must be carried out very carefully, so that any disturbance affecting algae will have severe repercussions on higher trophic levels and on the elemental biogeochemical cycles. 相似文献
505.
Influence of titanium dioxide nanoparticles on speciation and bioavailability of arsenite 总被引:2,自引:0,他引:2
Sun H Zhang X Zhang Z Chen Y Crittenden JC 《Environmental pollution (Barking, Essex : 1987)》2009,157(4):1165-1170
In this study, the influence of the co-existence of TiO2 nanoparticles on the speciation of arsenite [As(III)] was studied by observing its adsorption and valence changing. Moreover, the influence of TiO2 nanoparticles on the bioavailability of As(III) was examined by bioaccumulation test using carp (Cyprinus carpio). The results showed that TiO2 nanoparticles have a significant adsorption capacity for As (III). Equilibrium was established within 30 min, with about 30% of the initial As (III) being adsorbed onto TiO2 nanoparticles. Most of aqueous As (III) was oxidized to As(V) in the presence of TiO2 nanoparticles under sunlight. The carp accumulated considerably more As in the presence of TiO2 nanoparticles than in the absence of TiO2 nanoparticles, and after 25-day exposure, As concentration in carp increased by 44%. Accumulation of As in viscera, gills and muscle of the carp was significantly enhanced by the presence of TiO2 nanoparticles. 相似文献
506.
Study of lead phytoavailability for atmospheric industrial micronic and sub-micronic particles in relation with lead speciation 总被引:1,自引:0,他引:1
Particles from channelled emissions of a battery recycling facility were size-segregated and investigated to correlate their speciation and morphology with their transfer towards lettuce. Microculture experiments carried out with various calcareous soils spiked with micronic and sub-micronic particles (1650 ± 20 mg Pb kg−1) highlighted a greater transfer in soils mixed with the finest particles. According to XRD and Raman spectroscopy results, the two fractions presented differences in the amount of minor lead compounds like carbonates, but their speciation was quite similar, in decreasing order of abundance: PbS, PbSO4, PbSO4·PbO, α-PbO and Pb0. Morphology investigations revealed that PM2.5 (i.e. Particulate Matter 2.5 composed of particles suspended in air with aerodynamic diameters of 2.5 μm or less) contained many Pb nanoballs and nanocrystals which could influence lead availability. The soil-plant transfer of lead was mainly influenced by size and was very well estimated by 0.01 M CaCl2 extraction. 相似文献
507.
Spohn P Hirsch C Hasler F Bruinink A Krug HF Wick P 《Environmental pollution (Barking, Essex : 1987)》2009,157(4):1134-1139
Since the discovery of fullerenes in 1985, these carbon nanospheres have attracted attention regarding their physico/chemical properties. Despite little knowledge about their impact on the environment and human health, the production of fullerenes has already reached an industrial scale. However, the toxicity of C60 is still controversially discussed.The aim of this study was to clarify the biological effects of tetrahydrofuran (THF) suspended C60 fullerene in comparison to water stirred C60 fullerene suspensions. Beyond that, we analyzed the effects on the Crustacea Daphnia magna an indicator for ecotoxicological effects and the human lung epithelial cell line A549 as a simplified model for the respiratory tract.We could demonstrate that water-soluble side products which were formed in THF nC60 suspension were responsible for the observed acute toxic effects, whereas fullerenes themselves had no negative effect regardless of the preparative route on either A549 cell in vitro or D. magna in vivo. 相似文献
508.
S. Fesenko N. Isamov B.J. Howard N.A. Beresford C.L. Barnett N. Sanzharova G. Voigt 《Journal of environmental radioactivity》2009
Over 150 publications reporting studies conducted in the former USSR were reviewed to provide transfer coefficients (Ff) to the muscle of domestic animals from experiments using chronic administration, often for long timescales in large scale experiments. Only a few of these studies were made available in the English language literature or taken into account in international reviews. The values derived have been compared with expected values reported by the IAEA's Handbook of parameter values for the prediction of radionuclide transfer in temperate environments (TRS 364) where possible. The information presented here has been used in the current updating of parameters recommended for environmental assessments by the IAEA. Many of the reported values are for Sr due to the Mayak accident and Cs due to the Chernobyl accident. Nevertheless, the reported data for a wide range of radionuclides, in particular for Ru, Sb, and Zn markedly improve the extent of available data. 相似文献
509.
Use and knowledge of fuelwood in three rural caatinga (dryland) communities in NE Brazil 总被引:1,自引:0,他引:1
I. M. M. Sá e Silva L. C. Marangon N. Hanazaki U. P. Albuquerque 《Environment, Development and Sustainability》2009,11(4):833-851
The woody species known, used, and preferred as fuelwood were examined in three rural communities within the county of Soledade,
Paraíba State, NE Brazil. Ethnobotanical information was collected using semi-structured interviews with more than 90% of
the local households (55 adult residents; 31 women, and 24 males). The interviewees cited 36 plant species as fuelwoods, distributed
among 30 genera and 15 families, in addition to two unidentified plants. The plant families represented by the largest numbers
of species were Euphorbiaceae, Anacardiaceae, Mimosaceae, Caesalpiniaceae, Sapotaceae, and Fabaceae. The species Caesalpinia pyramidalis Tul. (“catingueira”) was cited with the greatest frequency in all three communities. Within the communities we found significant
differences on the number of plants cited and actually used (p < 0.05), indicating that the residents knew more fuelwood species than they effectively harvest. The different distances
from the communities to the urban centers were not related to differences on the use or the size of the stocks of fuelwood.
Additionally, the study revealed that the communities examined still maintain a significant knowledge of the use of energy-providing
plants in spite of the widespread use of liquefied petroleum gas (LPG).
Readers should send their comments on this paper to: BhaskarNath@aol.com within 3 months of publication of this issue. 相似文献
510.
A.A.L. Oiffer J.F. Barker F.M. Gervais K.U. Mayer C.J. Ptacek D.L. Rudolph 《Journal of contaminant hydrology》2009,108(3-4):89-106
An anaerobic plume of process-affected groundwater was characterized in a shallow sand aquifer adjacent to an oil sands tailings impoundment. Based on biological oxygen demand measurements, the reductive capacity of the plume is considered minimal. Major dissolved components associated with the plume include HCO3, Na, Cl, SO4, and naphthenic acids (NAs). Quantitative and qualitative NA analyses were performed on groundwater samples to investigate NA fate and transport in the subsurface. Despite subsurface residence times exceeding 20 years, significant attenuation of NAs by biodegradation was not observed based on screening techniques developed at the time of the investigation. Relative to conservative tracers (i.e., Cl), overall NA attenuation in the subsurface is limited, which is consistent with batch sorption and microcosm studies performed by other authors. Insignificant biological oxygen demand and low concentrations of dissolved As (< 10 µg L− 1) in the plume suggest that the potential for secondary trace metal release, specifically As, via reductive dissolution reactions driven by ingress of process-affected water is minimal. It is also possible that readily leachable As is not present in significant quantities within the sediments of the study area. Thus, for similar plumes of process-affected groundwater in shallow sand aquifers which may occur as oil sands mining expands, a reasonable expectation is for NA persistence, but minimal trace metal mobilization. 相似文献