焦作市中马村矿土壤重金属污染调查评价

对焦作市中马村矿矸石山周围土壤中5种重金属(Cu、Cr、Pb、Zn、Mn)的含量、分布特征及其污染状况进行了调查与评价。结果表明,矿区土壤不同程度地受到5种重金属的污染,依次为Zn>Pb>Cu>Cr>Mn;土壤综合污染指数为1. 74,属轻污染; 5种重金属元素中Zn、Pb相关性显著,其余均为低度相关。     

总磷测定中两种稀释方法的对照

在过硫酸钾消解－钼蓝比色法测定总磷中，当显色液吸光值超出校准曲线范围时，进行了显色液稀释后再行测定的试验，试验结果与水样稀释重新消解[测定所得结果作统计检验，两者间无显著性差异，稀释倍数最大不宜超过4倍。     

四川青衣江上游若壁小沟泥石流及其防治对策

若壁小沟为四川青衣江上游左岸的一级支沟,该沟处于深切割高山峡谷区,地形坡度陡,构造发育,岩石破碎,加之较为丰富的降雨,使该沟具备泥石流暴发的条件。该沟如果暴发泥石流,将对某电站拟建厂房产生威胁。该沟泥石流具有成灾快、危害严重、松散固体物质以坡面崩塌补给为主、活动频率中等等特征。通过野外考察和取样分析,该沟泥石流的性质和类型为中频率—中~大规模—低~高粘度泥石质泥石流。分析预测了该沟泥石流在强烈地震条件下、近期出现不同频率暴雨情况下及人类活动影响下的发展趋势。在此基础上,提出了该沟泥石流减灾工程规划方案。     

黄龙景区红岩关沟的泥石流及防治

红岩关沟为四川松潘县黄龙风景名胜区内涪江上游一条支沟,曾发生过严重的泥石流灾害.该地的泥石流具有活动频繁、危害严重、容重大、固体物质粒径粗、以及主要以沟岸滑坡、崩塌、沟床堆积物补给为主等特点.本文分析了该地泥石流的形成、流体性质、类型等基本特征,预测了泥石流的发展趋势,提出了治理措施.     

"深圳-巴彦浩特"地理样带土地利用与水旱灾害研究

在建立1990-2000年“深圳-巴彦浩特“地理样带水旱灾害数据库的基础上,结合样带1995、2000年两期的土地利用数据,分析了样带水旱灾害的区域差异,及其与样带土地利用时空格局的关系.结果表明,样带水旱灾害呈现较强的南北差异,北方以旱灾为主,南方以水灾为主;土地利用结构对样带水旱灾害有较强的影响,土地利用类型复杂的县市有较高的水旱灾害发生率,而土地利用类型单一的县市则受水旱灾害影响较小.水灾主要出现在样带南部多种土地利用类型混杂的县市,特别是城镇建设用地比例较高的地区,水灾相对更为频繁;旱灾在缺乏灌溉水源且以耕地和草地为主要土地利用类型的区域发生频率较高.     

Sulfamethoxazole sorption by sediment fractions in comparison to pyrene and bisphenol A

The environmental behavior of antibiotics has attracted great research attention. However, their sorption mechanisms in soils/sediments are still unknown. Comparison of the sorption properties between the widely-studied hydrophobic organic contaminants (HOCs) and antibiotics may provide valuable insight to antibiotic sorption mechanisms. Thus, in this study batch experiments for pyrene (PYR), bisphenol A (BPA), and sulfamethoxazole (SMX) sorption were conducted on a sediment sample and its separated fractions. Our results showed the high sorption of PYR on black carbon and organic matter. Although high sorption of SMX was observed for both separated organic fractions (humic acids) and inorganic mineral particles, the original sediment particles showed relatively low sorption. Competitive sorption between SMX and dissolved humic acid on mineral particles was observed in this study. This competitive interaction is a unique process for antibiotic sorption in soils/sediments compared with apolar HOCs and may be one of the important factors controlling the antibiotic sorption.     

造纸中段废水与生活污水合并深度处理工艺

采用水解酸化 CAST 混凝 复合滤池与水解酸化 接触氧化 混凝 复合滤池2种组合工艺对造纸中段废水与生活污水进行合并处理对照试验.结果表明,两种工艺都是切实可行的,二级出水均可达到<污水综合排放标准>(GB8978-1996)二级标准,深度处理出水可达中水水质要求.其中以水解酸化 CAST 混凝 复合滤池组合工艺效果最好.     

上海市机动车尾气VOCs组成及其化学反应活性

采用钢罐采样-气相色谱/质谱法,采集并分析了上海市主要交通干道和隧道废气样品中挥发性有机物(VOCs)的污染水平。分析结果表明,交通干道和隧道废气样品的总挥发性有机污染物(TVOC)质量浓度分别为(227.1±40.9)、(2209.9±1228.0)μg/m3;隧道废气样品中的TVOC浓度是交通干道平均浓度的4.3～15.2倍;交通干道废气样品中VOCs主要组分与隧道废气样品中VOCs主要组分非常类似,说明交通干道废气样品中VOCs主要来源于机动车尾气排放。交通干道废气样品中TVOC的.OH消耗速率为(17.21±4.49)s-1,延安东路隧道和打浦路隧道废气样品中TVOC的.OH消耗速率分别为(300.37±120.78)、(138.09±25.30)s-1,烯烃对TVOC的.OH消耗速率贡献最大,其对废气化学反应活性贡献率在70%以上。交通干道和隧道废气样品中关键活性组分是C2～C5的烯烃组分,这些组分也是机动车尾气中的特征污染物,因此可以判断机动车尾气是上海市大气化学反应活性的最大贡献者。     

水环境中26种类固醇激素的分析方法研究

建立了固相萃取-超高效液相-串联质谱法同时测定水环境中26种类固醇激素的分析方法。明确了取样体积为500 m L,Cleanert PEP为富集柱,乙酸乙酯为洗脱剂,甲醇为溶剂进行提取操作。选择了正离子模式,以0. 1%甲酸/甲醇-水为流动相,负离子模式以0. 1%氨水/乙腈-水为流动相,试样经AcquityTMUPLC BEH C18色谱柱分离后,选用质谱检测模式进行定性、定量分析。通过方法验证,26种类固醇激素的方法检出限为0. 3～1. 5 ng/L,测定下限为1. 2～6. 0 ng/L,代表性样品测定结果的相对标准偏差为2. 6%～13. 7%(n=6),加标回收率为71. 2%～121%。该方法操作便捷,灵敏度高,精密度和准确度良好,可适用于水环境中多种痕量、超痕量类固醇激素的定性定量分析。     

Trace elements in muscle of three fish species from Todos os Santos Bay,Bahia State,Brazil

In this study, an analysis was performed on the concentrations of the trace elements Al, As, Ba, Cd, Co, Cr, Cu, Fe, Mn, Ni, Pb, V, and Zn in muscle of two carnivorous and one planktivorous fish species collected at Todos os Santos Bay (BTS). The accumulation order of the trace elements in Lutjanus analis was Al >Zn >Fe >Cr >Ba >Ni. In Cetengraulis edentulus, the order was Al >Fe >Zn >Cr >Ni >Mn >As. In the species Diapterus rhombeus, the order was Al >Fe >Zn >Cr >Ni >Mn >Cd. To determine the risk related to the consumption of fish, toxicity guidelines were used as standard references. It was observed that the species C. edentulus contained concentrations of As exceeding WHO limits, but these concentrations were acceptable according to the Agência Nacional de Vigilância Sanitária (ANVISA) guidelines. Cd levels were found only in D. rhombeus and in low concentrations according to the determinations of WHO and ANVISA. Pb levels were not detected in any of the three fish species. The analyzed elements did not differ statistically according to the species and feeding habits. The results point to possible risks of human contamination by As related to the consumption of the fish species C. edentulus from the BTS.