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31.
Norman S. Allen Robert McIntyre Julie Maltby Kerrod Claire Hill Michele Edge 《Journal of Polymers and the Environment》2018,26(11):4243-4257
Surface treated macro and nanoparticle TiO2 samples have been prepared, characterised and their efficiency as UV blockers evaluated in clear coatings and paints. The particle size of the ‘base’ TiO2 has been optimised to block UV radiation and the surface treatment developed to deactivate the photocatalytic activity of the surface of the TiO2 particles. The resultant UV blockers have been evaluated in both solvent and water-based clear coatings. Nanoparticle TiO2 has been prepared from ‘seed’ and the particle size was controlled by calcination. It was found that the choice of particle size is a compromise between UVA absorption, UVB absorption, visible transmission and photoactivity. It has been demonstrated that TiO2 with a crystallite size of 25 nm yields a product with the optimum properties. A range of dispersants was successfully used to disperse and mill the TiO2. Both organic and inorganic dispersants were used; 2-amino-2-methyl-1-propanol and 1-amino-2-propanol (MIPA) and P2O5 and Na2SiO3 respectively. The surface of the nano-TiO2 was coated with mixed oxides of silicon, aluminium, zirconium and phosphorous. Addition of the resultant coated nano-rutiles to an Isocyanate Acrylic clear coating prolonged the lifetime of that coating compared to the blank. Generally, a surface treatment based on SiO2, Al2O3 and P2O5 was more successful than one based on ZrO2, Al2O3 and P2O5. Higher addition levels of the surface treatment were beneficial for protecting the polymeric coating. The UV blocker products were also evaluated in a water-based acrylic, first a water-based dispersion of the UV blocker was prepared before addition to the acrylic. The dispersions and resultant acrylic thin films were evaluated using UV/Vis spectroscopy and durability assessed. The ratio of absorbance at 300:500 nm for the water-based dispersion was shown to be a good predictor of both the transparency of the resultant acrylic thin film and the durability of that film, in terms of weight loss. Macro grade titanium dioxide pigments were also prepared and coated with treatments of silica, alumina and siloxane and their photo-stabilising activity in alkyd paint film assessed and found to be directly related to the electron–hole pair mobility and trapping as determined by micro-wave spectroscopy. 相似文献
32.
Chris Pratt Adrian S. Walcroft Julie Deslippe Kevin R. Tate 《Waste management (New York, N.Y.)》2013,33(2):412-419
Landfills that generate too little biogas for economic energy recovery can potentially offset methane (CH4) emissions through biological oxidation by methanotrophic bacteria in cover soils. This study reports on the CH4 oxidation efficiency of a 10-year old landfill cap comprising a volcanic pumice soil. Surface CH4 and CO2 fluxes were measured using field chambers during three sampling intervals over winter and summer. Methane fluxes were temporally and spatially variable (?0.36 to 3044 mg CH4 m?2 h?1); but were at least 15 times lower than typical literature CH4 fluxes reported for older landfills in 45 of the 46 chambers tested. Exposure of soil from this landfill cover to variable CH4 fluxes in laboratory microcosms revealed a very strong correlation between CH4 oxidation efficiency and CH4/CO2 ratios, confirming the utility of this relationship for approximating CH4 oxidation efficiency. CH4/CO2 ratios were applied to gas concentrations from the surface flux chambers and indicated a mean CH4 oxidation efficiency of 72%. To examine CH4 oxidation with soil depth, we collected 10 soil depth profiles at random locations across the landfill. Seven profiles exhibited CH4 removal rates of 70–100% at depths <60 cm, supporting the high oxidation rates observed in the chambers. Based on a conservative 70% CH4 oxidation efficiency occurring at the site, this cover soil is clearly offsetting far greater CH4 quantities than the 10% default value currently adopted by the IPCC. 相似文献
33.
Hummingbird with modern feathering: an exceptionally well-preserved Oligocene fossil from southern France 总被引:1,自引:0,他引:1
Louchart A Tourment N Carrier J Roux T Mourer-Chauviré C 《Die Naturwissenschaften》2008,95(2):171-175
Hummingbirds (Trochilidae) today have an exclusively New World distribution, but their pre-Pleistocene fossil record comes from Europe only. In this study, we describe an exceptionally preserved fossil hummingbird from the early Oligocene of southeastern France. The specimen is articulated, with a completely preserved beak and feathering. Osteological characters allow to identify it as Eurotrochilus sp. This genus is a stem group representative of Trochilidae and was recently described from the early Oligocene of southern Germany. The new fossil reveals that these European Trochilidae were remarkably modern in size, skeletal proportions and the shape of the wing, tail and beak and hyoid bones. These features confirm the early acquisition of the abilities of hovering and nectarivory in hummingbirds, probably before the Oligocene. In several morphological characteristics, they resemble members of the 'true hummingbirds' (subfamily Trochilinae) and differ from hermits (Phaethornithinae). These features, which include a short and square tail and a moderately long, almost straight beak, appear to be primitive within the family Trochilidae. 相似文献
34.
Adrien Brié Ravo Razafimahefa Julie Loutreul Aurélie Robert Christophe Gantzer Nicolas Boudaud Isabelle Bertrand 《Food and environmental virology》2017,9(2):149-158
Heat and free chlorine are among the most efficient and commonly used treatments to inactivate enteric viruses, but their global inactivation mechanisms have not been elucidated yet. These treatments have been shown to affect at least the capsid proteins of viruses and thus may affect the surface properties (i.e. electrostatic charge and hydrophobicity) of such particles. Our aim was to study the effects of heat and free chlorine on surface properties for a murine norovirus chosen as surrogate for human norovirus. No changes in the surface properties were observed with our methods for murine norovirus exposed to free chlorine. Only the heat treatment led to major changes in the surface properties of the virus with the expression of hydrophobic domains at the surface of the particles after exposure to a temperature of 55 °C. No modification of the expression of hydrophobic domains occurred after exposure to 60 °C, and the low hydrophobic state exhibited by infectious and inactivated particles after exposure to 60 °C appeared to be irreversible for inactivated particles only, which may provide a means to discriminate infectious from inactivated murine noroviruses. When exposed to a temperature of 72 °C or to free chlorine at a concentration of 50 mg/L, the genome became available for RNases. 相似文献
35.
The problem of resolving the homology of the digits of the avian hand has been framed as a conflict between paleontological and embryological evidence, the former thought to support a hand composed of digits I, II, III, because of similarity of the phalangeal formulae of the earliest known bird Archaeopteryx to that of Mesozoic pentadactyl archosaurs, while embryological evidence has traditionally favored a II, III, IV avian hand. We have identified the critical developmental period for the major features of the avian skeleton in a primitive bird, the ostrich. Analysis of digit anlagen in the avian hand has revealed those for digits/metacarpals I and V, thus confirming previous embryological studies that indirectly suggested that the avian hand comprises digits II, III, IV, and was primitively pentadactyl. 相似文献
36.
Karen Hardy Stephen Buckley Matthew J. Collins Almudena Estalrrich Don Brothwell Les Copeland Antonio García-Tabernero Samuel García-Vargas Marco de la Rasilla Carles Lalueza-Fox Rosa Huguet Markus Bastir David Santamaría Marco Madella Julie Wilson ángel Fernández Cortés Antonio Rosas 《Die Naturwissenschaften》2012,99(8):617-626
Neanderthals disappeared sometime between 30,000 and 24,000?years ago. Until recently, Neanderthals were understood to have been predominantly meat-eaters; however, a growing body of evidence suggests their diet also included plants. We present the results of a study, in which sequential thermal desorption-gas chromatography-mass spectrometry (TD-GC-MS) and pyrolysis-gas chromatography-mass spectrometry (Py-GC-MS) were combined with morphological analysis of plant microfossils, to identify material entrapped in dental calculus from five Neanderthal individuals from the north Spanish site of El Sidrón. Our results provide the first molecular evidence for inhalation of wood-fire smoke and bitumen or oil shale and ingestion of a range of cooked plant foods. We also offer the first evidence for the use of medicinal plants by a Neanderthal individual. The varied use of plants that we have identified suggests that the Neanderthal occupants of El Sidrón had a sophisticated knowledge of their natural surroundings which included the ability to select and use certain plants. 相似文献
37.
Joke Muys Bettina Blaumeiser Yves Jacquemyn Claude Bandelier Nathalie Brison Saskia Bulk Patrizia Chiarappa Winnie Courtens Anne De Leener Marjan De Rademaeker Julie Désir Anne Destrée Koenraad Devriendt Annelies Dheedene Annelies Fieuw Erik Fransen Jean-Stéphane Gatot Philip Holmgren Mauricette Jamar Sandra Janssens Kathelijn Keymolen Damien Lederer Björn Menten Marije Meuwissen Benoit Parmentier Bruno Pichon Sonia Rombout Yves Sznajer Ann Van Den Bogaert Kris Van Den Bogaert Olivier Vanakker Joris Vermeesch Katrien Janssens 《黑龙江环境通报》2018,38(13):1120-1128
38.
Physical and Chemical Connectivity of Streams and Riparian Wetlands to Downstream Waters: A Synthesis 下载免费PDF全文
Ken M. Fritz Kate A. Schofield Laurie C. Alexander Michael G. McManus Heather E. Golden Charles R. Lane William G. Kepner Stephen D. LeDuc Julie E. DeMeester Amina I. Pollard 《Journal of the American Water Resources Association》2018,54(2):323-345
Streams, riparian areas, floodplains, alluvial aquifers, and downstream waters (e.g., large rivers, lakes, and oceans) are interconnected by longitudinal, lateral, and vertical fluxes of water, other materials, and energy. Collectively, these interconnected waters are called fluvial hydrosystems. Physical and chemical connectivity within fluvial hydrosystems is created by the transport of nonliving materials (e.g., water, sediment, nutrients, and contaminants) which either do or do not chemically change (chemical and physical connections, respectively). A substantial body of evidence unequivocally demonstrates physical and chemical connectivity between streams and riparian wetlands and downstream waters. Streams and riparian wetlands are structurally connected to downstream waters through the network of continuous channels and floodplain form that make these systems physically contiguous, and the very existence of these structures provides strong geomorphologic evidence for connectivity. Functional connections between streams and riparian wetlands and their downstream waters vary geographically and over time, based on proximity, relative size, environmental setting, material disparity, and intervening units. Because of the complexity and dynamic nature of connections among fluvial hydrosystem units, a complete accounting of the physical and chemical connections and their consequences to downstream waters should aggregate over multiple years to decades. 相似文献
39.
Charles T. Garten Deanne J. Brice Hector F. Castro Robin L. Graham Melanie A. Mayes Jana R. Phillips Wilfred M. Post Christopher W. Schadt Stan D. Wullschleger Donald D. Tyler Phillip M. Jardine Julie D. Jastrow Roser Matamala R. Michael Miller Kelly K. Moran Timothy W. Vugteveen R. Cesar Izaurralde Allison M. Thomson Tristram O. West James E. Amonette Jeffrey L. Smith 《Agriculture, ecosystems & environment》2011,140(1-2):289-297
Switchgrass (Panicum virgatum) is a perennial, warm-season grass that has been identified as a potential biofuel feedstock over a large part of North America. We examined above- and belowground responses to nitrogen fertilization in “Alamo” switchgrass grown in West Tennessee, USA. The fertilizer study included a spring and fall sampling of 5-year old switchgrass grown under annual applications of 0, 67, and 202 kg N ha?1 (as ammonium nitrate). Fertilization changed switchgrass biomass allocation as indicated by root:shoot ratios. End-of-growing season root:shoot ratios (mean ± SE) declined significantly (P ≤ 0.05) at the highest fertilizer nitrogen treatment (2.16 ± 0.08, 2.02 ± 0.18, and 0.88 ± 0.14, respectively, at 0, 67, and 202 kg N ha?1). Fertilization also significantly increased above- and belowground nitrogen concentrations and decreased plant C:N ratios. Data are presented for coarse live roots, fine live roots, coarse dead roots, fine dead roots, and rhizomes. At the end of the growing season, there was more carbon and nitrogen stored in belowground biomass than aboveground biomass. Fertilization impacted switchgrass tissue chemistry and biomass allocation in ways that potentially impact soil carbon cycle processes and soil carbon storage. 相似文献
40.
Nicolas Nantel-Fortier Ann Letellier Virginie Lachapelle Philippe Fravalo Yvan L’Homme Julie Brassard 《Food and environmental virology》2016,8(4):296-304
Viral contamination along the production chain is a significant concern in both food safety and livestock health. Pigs have been reported to act as a reservoir for zoonotic viruses, sometimes emerging ones, and epidemiological studies have shown direct links between the consumption of uncooked pork offal and cases of hepatitis caused by the hepatitis E virus (HEV) genotype 3 in humans. The presence of HEV in swine herds has been reported, but its dissemination in pork production environments is still unknown. To investigate viral contamination sources in the swine industry, 452 environment and fecal samples, including samples from livestock transportation vehicles, were collected over a period of 11 months from ten farms and one slaughterhouse that together represent a single production network. Hepatitis E virus RNA was detected by nested RT-PCR in 32 samples from both inside and outside farm buildings, on trucks, and, mostly, from fomites collected in the slaughterhouse yard, such as on a utility vehicle. Phylogenetic analysis showed a wide diversity of HEV genotype 3 strains, similar to human and swine strains previously found. According to the results of this study, the movements of trucks and utility vehicles might play an important role in HEV dissemination on a slaughterhouse site and throughout an entire network. 相似文献