Urban Development and Air Quality in San Luis City, Argentina

Some factors such as the high population growth, along with insufficient housing, health and sanitary services, obsolete industrial technology and the lack of environmental management programs, give rise to contamination in Latin-American cities. Owing to the urban characteristics of San Luis, a detailed analysis of air quality was planned as part of a more comprehensive study, in order to make an environmental diagnosis of the city after the demographical and economic upgrowth over the last 15 years. It has been concluded that air pollution levels in San Luis are higher than those expected for a medium-size city. The reported high levels were attributed to important industrial activity, responsible not only for the direct of polluting gases to the atmosphere but also as the principal cause of the urban expansion. The levels of CO and SO₂ (ppm) found in the city can be considered as high. Some weeks during the sampling measure values were appreciably higher than the maximum tolerance levels established. The urban area under study was separated into five defined areas, which allowed to make comparisons in order to identify specific contamination problems. The slopes corresponding to the plot polluting substances concentration vs. wind speed were lower than the expected values. Because of the urban area characteristics, different micrometeorological effects facilitating a low air exchange can be generated, and consequently increasing the contamination levels. Thus, it is correct to conclude that the degradation processes are not occurring in a single environmental plane. Accordingly, air contamination rate in San Luis city could be considered as evidence of other upper-scale regional environmental degradation processes.     

Non-immunological hydrops fetalis and intrapericardial teratoma: Case report and review

A large intrapericardial teratoma was found at necropsy in a 38−week stillborn fetus, in which prenatal diagnosis of hydrops fetalis and an ehogenic cardiac mass had been made. Clinical and pathological data are reported. In utero intrapericardial teratomata lead to different outcomes depending on whether fetal hydrops is associated. When generalized fetal hydrops is not present, the outcome is good, even in cases with large pericardial effusions. When generalized fetal hydrops occurs, it often results in a poor outcome. In our literature review, we have found eight perinatal deaths in nine similar cases reported.     

Nitrate toxicity to aquatic animals: a review with new data for freshwater invertebrates

Published data on nitrate (NO3-) toxicity to freshwater and marine animals are reviewed. New data on nitrate toxicity to the freshwater invertebrates Eulimnogammarus toletanus, Echinogammarus echinosetosus and Hydropsyche exocellata are also presented. The main toxic action of nitrate is due to the conversion of oxygen-carrying pigments to forms that are incapable of carrying oxygen. Nitrate toxicity to aquatic animals increases with increasing nitrate concentrations and exposure times. In contrast, nitrate toxicity may decrease with increasing body size, water salinity, and environmental adaptation. Freshwater animals appear to be more sensitive to nitrate than marine animals. A nitrate concentration of 10 mg NO3-N/l (USA federal maximum level for drinking water) can adversely affect, at least during long-term exposures, freshwater invertebrates (E. toletanus, E. echinosetosus, Cheumatopsyche pettiti, Hydropsyche occidentalis), fishes (Oncorhynchus mykiss, Oncorhynchus tshawytscha, Salmo clarki), and amphibians (Pseudacris triseriata, Rana pipiens, Rana temporaria, Bufo bufo). Safe levels below this nitrate concentration are recommended to protect sensitive freshwater animals from nitrate pollution. Furthermore, a maximum level of 2 mg NO3-N/l would be appropriate for protecting the most sensitive freshwater species. In the case of marine animals, a maximum level of 20 mg NO3-N/l may in general be acceptable. However, early developmental stages of some marine invertebrates, that are well adapted to low nitrate concentrations, may be so susceptible to nitrate as sensitive freshwater invertebrates.     

Contribution of Spanish-American silver mines (1570-1820) to the present high mercury concentrations in the global environment: a review

In this review I evaluate the contribution of Spanish-American silver mines during the period 1570-1820 (a Spanish colonial period of 250 years) to the present high mercury concentrations in the global environment. The evaluation is based upon the following bibliographic information: (1) total amount of mercury consumed in Spanish-American silver mines between 1570 and 1820; (2) percentage of the total amount of mercury consumed in Spanish-American silver mines that may have been emitted to the atmosphere; (3) global natural input of mercury to the atmosphere; (4) worldwide anthropogenic emissions of mercury to the atmosphere; (5) residence time of mercury in the atmosphere; and (6) capacity of mercury to be deposited in the sediments of aquatic systems. From all this information, and owing to the relatively long time that has passed since Spanish-American silver mines were operational, I conclude that most of the mercury lost during the refining of silver via the patio amalgamation process is now sequestered into the sediments of aquatic systems, mainly in marine sediments. The high mercury concentrations now being reported in the global environment essentially are a consequence of the huge pollution caused by human activities during the past 20th century.     

Effects of plant densities and management of purple nutsedge on sugarcane yield and effect of growth stages and main way of herbicides contact and absorption on the control of tubers

Field experiments carried out with Cyperus rotundus L. at low (58-246), medium (318-773), and high (675-1198 shoots/m2) densities showed sugarcane yield reductions of 13.5, 29.3, and 45.2%, respectively in relation to the control. In the second field experiment, the integration of a mechanic method with two sequences of plowing and disking operations in the dry season, and complementary applications of trifloxysulfuron-sodium + ametrine and sulfentrazone (rainy season) was studied. Average of the chain connected to original shoot showed 92, 95, and 65% of reduction with trifloxysulfuron-sodium + ametrine and surfactant, at the application stages "early," preflowering, and full flowering, respectively.     

Preparation of jet engine range fuel from biomass pyrolysis oil through hydrogenation and its comparison with aviation kerosene

The Bio-oil was produced from the pyrolysis of agricultural wastes (Eucalyptus sawdust) and discarded soybean frying oil. The temperature of the pyrolysis system was initiated at 28°C and increased to 850°C. Atmospheric distillation of crude bio-oil was performed and a fraction at a temperature range 160–240°C (pyrolysis oil) was separated and subjected to GC-MS, ¹H-NMR, TGA and FTIR analysis to identify the different properties and compounds present in pyrolysis oil. It was noticed that there was an abundance of oxygen and nitrogen containing compounds as well as other reactive species in pyrolysis oil. To reduce the amount of these species, the pyrolysis oil was subjected to hydrogenation in the presence of NiMo as a catalyst. After hydrogenation, the atmospheric distillation of hydrogenated bio-oil was performed and another fraction at temperature range 160–240°C (hydrogenated bio-oil) was separated and analyzed by the same techniques. It was noticed that during hydrogenation, more than 60% oxygenated and other reactive species were converted into hydrocarbons. Hydrogenated bio-oil showed very similar physico-chemical properties such as distillation curve, density, viscosity, freezing point, flash point, the presence of hydrocarbons and enthalpy of combustion as aviation kerosene also known as QAV-1.     

Assessing the extent and nature of wildlife trade on the dark web

Use of the internet as a trade platform has resulted in a shift in the illegal wildlife trade. Increased scrutiny of illegal wildlife trade has led to concerns that online trade of wildlife will move onto the dark web. To provide a baseline of illegal wildlife trade on the dark web, we downloaded and archived 9852 items (individual posts) from the dark web, then searched these based on a list of 121 keywords associated with illegal online wildlife trade, including 30 keywords associated with illegally traded elephant ivory on the surface web. Results were compared with items known to be illegally traded on the dark web, specifically cannabis, cocaine, and heroin, to compare the extent of the trade. Of these 121 keywords, 4 resulted in hits, of which only one was potentially linked to illegal wildlife trade. This sole case was the sale and discussion of Echinopsis pachanoi (San Pedro cactus), which has hallucinogenic properties. This negligible level of activity related to the illegal trade of wildlife on the dark web relative to the open and increasing trade on the surface web may indicate a lack of successful enforcement against illegal wildlife trade on the surface web.     

Comparative evaluation of nitrogen oxides and ozone passive diffusion tubes for exposure studies

Passive diffusion tubes are recognised as a cost-effective sampling method for characterising the spatial variability, as well as the seasonal and annual trends, of NO₂ concentrations in urban areas. In addition, NO_X and O₃ passive diffusion tubes have been developed and deployed in urban and rural areas. Despite their many advantages (e.g. low operational and analysis cost, small size and no need for power supply), they have certain limitations mainly related to their accuracy and precision. In particular, the absorbent solution used, the length of the exposure period, the exact location and use of protective devices, and other environmental conditions (e.g. wind, ambient temperature and relative humidity) may have a significant impact on the performance of passive diffusion tubes. The aim of this study is to evaluate the performance of co-located NO₂, NO_X and O₃ diffusion tubes in an urban environment.A one-year passive sampling campaign was carried out in Birmingham (UK) for this purpose. NO₂, NO_X and O₃ diffusion tubes (including triplicate sets of each) were co-located at one urban background and two roadside permanent air quality monitoring stations equipped with standard gas analysers. In addition, meteorological data, such as wind speed and direction, ambient temperature and relative humidity, were obtained during the same period of time. A thorough QA/QC procedure, including storage and laboratory blanks was followed throughout the campaign. The analysis of results showed a very good agreement of NO₂ passive samplers with co-located chemiluminescence analysers, but substantial underestimations of total NO_X levels by the diffusion tubes. The O₃ diffusion sampler appeared to marginally overestimate the automatic UV analyser results, especially during warm weather periods.