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We started the monitoring for PCDD/Fs in ambient air and soil in August 2001, and co-PCBs in January 2002. Decreasing of PCDD/Fs and co-PCBs levels in ambient air were observed. The higher PCDD/Fs levels were found in winter and lower in autumn. We found that the industrial incinerators influenced the PCDD/Fs levels in ambient air. In the 2,3,7,8-substituted PCDD/Fs concentration profiles, the three major congeners occupied 67% of the total mass. In case of co-PCBs, PCB#118, #105 and #77 were observed as the main congeners. Five cluster groups discriminated by ratio of four components, O(8)CDD, 1,2,3,4,6,7,8-H(7)CDD, 1,2,3,4,6,7,8-H(7)CDF and O(8)CDF, were obtained from HCA (hierarchical cluster analysis). 相似文献
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Dae-Woon Jeong Won-Jun Jang Jae-Oh Shim Won-Bi Han Kyung-Won Jeon Yong-Chil Seo Hyun-Seog Roh Jae Hoi Gu Yong Taek Lim 《Journal of Material Cycles and Waste Management》2014,16(4):650-656
A comparative study on Fe/Al, Fe/Al/Cu, and Fe/Al/Ni catalysts in high-temperature water–gas shift reaction (HT–WGS) using simulated waste-derived synthesis gas has been carried out. The metal oxide (Cu and Ni) and aluminum incorporated Fe catalysts were designed to get highly active HT–WGS catalysts. Despite the high CO concentration in the simulated waste-derived synthesis gas, Fe/Al/Cu catalyst exhibited the highest CO conversion (84 %) and 100 % selectivity to CO2 at a very high gas hourly space velocity (GHSV) of 40,057 h?1. The outstanding catalytic performance is mainly due to easier reducibility, the synergy effect of Cu and Al, and the stability of the magnetite. 相似文献
15.
Liang Peng Yanqing Ren Jidong Gu Pufeng Qin Qingru Zeng Jihai Shao Ming Lei Liyuan Chai 《Environmental science and pollution research international》2014,21(12):7631-7640
Novel magnetic carbonaceous bio-char was hydrothermal prepared from microalgae under different loadings of iron and its structures and surface chemistry were characterized with Fourier transform infrared (FTIR), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), and nitrogen adsorption-desorption isotherm (BET). The morphology of bio-char changed from sheet to particle as iron loading increased and its surface area also increased. When 3.0 g of dried microalgae and 6.0 mmol iron salt ((NH4)2SO4·FeSO4·6H2O) were mixed and treated, the obtained bio-char possessing the highest amount of oxygen-containing functional groups resulted in the best adsorption performance on tetracycline (TC). This adsorption process was fitted to Langmuir adsorption isotherm and the maximum adsorption capacity was 95.86 mg/g, which is higher than other bio-char reported. The iron loading contributed to the higher adsorption capacity of bio-char, which may be due to three factors, the high surface area, more hydrogen bonding, and bridging effects of the structural Fe for TC. Our data suggest that bio-char may have more important role in stabilization of pollutants in the environment. 相似文献
16.
Distribution and relationships of As,Cd, Pb and Hg in freshwater fish from five French fishing areas
Laurent Noël Rachida Chekri Sandrine Millour Mathilde Merlo Jean-Charles Leblanc Thierry Guérin 《Chemosphere》2013,90(6):1900-1910
The concentrations of arsenic, cadmium, mercury and lead in 149 muscle samples of eight freshwater fish species (European eel, bream, common carp, European catfish, roach, perch, pike and pikeperch) from five different French fishing areas from contaminated and control sites were measured by inductively coupled plasma mass spectrometry after microwave digestion under pressure. No significant correlation was found between the condition factor (CF), based on the length–mass relationship, and As, Cd and Pb levels in all the samples analysed, but a positive correlation was detected between CF and Hg levels (P < 0.0001, R = 0.49). Positive correlations with body length were only found for Hg in roach (P < 0.05, R = 0.32) and Pb in bream (P < 0.05, R = 0.48) and correlations with both body weight and length were also found for Hg in pike (P < 0.05, R = 0.90 and 0.86) and Cd in European eel (P < 0.01, R = ?0.35 and ?0.37). The average content and the standard deviation in fish muscle samples was 0.007 ± 0.012, 0.102 ± 0.077, 0.142 ± 0.097 and 0.035 ± 0.053 mg kg?1 of wet mass for Cd, As, Hg and Pb, respectively. Significant differences were established between groups of predatory fish and non-predatory fish for Hg and Pb, and between control and contaminated sites in the whole selection and also within feeding guilds, i.e. the values of Hg in the benthophagic fish were significantly different between these sites. Finally, these results were also compared for each species with previous French and European studies. 相似文献
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Investigation on the interaction between triclosan and bovine serum albumin by spectroscopic methods
Jiali Gu Siyao Zheng Heng Zhao 《Journal of environmental science and health. Part. B》2020,55(1):52-59
AbstractMulti-spectroscopic and molecular docking methods were used to study the interaction between triclosan (TCS) and bovine serum albumin (BSA). The results indicated that the fluorescence quenching of BSA by TCS was due to the formation of TCS–BSA complex through static quenching. This result was also demonstrated by time-resolved fluorescence experiment. The binding constants and number of binding sites between TCS and BSA were 1.30?×?105 M?1 and 1.17 at 298?K, respectively. The thermodynamic parameters were studied in detail which suggested that hydrophobic forces and hydrogen bond played major roles in the TCS–BSA interaction. Moreover, the site marker competitive experiments and docking studies revealed that TCS could bind BSA into site I in subdomain IIA. All the results of UV–vis spectrophotometry, circular dichroism spectroscopy and synchronous fluorescence spectroscopy showed that interaction between TCS and BSA induced conformation changes of BSA. 相似文献
19.
1国内外公共安全形势与城市公共安全的新挑战
进入21世纪,国际公共安全形势日趋严峻,城市面临的灾害形势从传统的自然灾害、火灾、瘟疫等为主扩大到传统灾害和生命线系统故障、信息安全、恐怖事件等非传统灾害共同影响的情况,呈现出以下特点:重大自然灾害的发生频率、量级加大,经济损失更严重;随着工业化、现代化和城市化的发展,事故灾难以及复合型事件的影响日益突出;生物和公共卫生危机严重威胁和影响公众健康;恐怖主义威胁呈现出新型化、大规模化和强灾难性的特点;经济危机连锁反应,各种社会危机交相激荡.…… 相似文献
20.
膜生物反应器生物降解与膜分离共作用特性研究 总被引:29,自引:0,他引:29
膜生物反应器实质是生物降解与膜分离相互影响,共同作用的过程,污泥浓度与通量之间存在一定的相关关系,膜分离对生和性能尤其是细菌活性有着重要的影响,而生物反应器内细菌胞外聚合物,溶解性有机物及微细胶体可能成为形成凝胶层导致通量下降的主要因素。 相似文献