分子筛在铅污染土壤修复中的应用研究

采用溶液试验,从待选钝化材料中初步筛选出对Pb具有较好钝化效果的钝化材料,运用经典混料设计的试验方法,将优选出的13X分子筛、凹凸棒土、粉煤灰三种钝化材料复配成钝化剂,添加到Pb含量为1 500mg/kg的污染土中,添加量为污染土的20％,并保持土壤的含水率35％,3天后取钝化后土壤,采用(HJ/T 300-2007)(固体废物浸出毒性浸出方法醋酸缓冲溶液法)测其浸出液中的重金属Pb含量,采用Minitab软件对混料设计试验数据进行处理,优选出钝化重金属Pb的最佳钝化剂配方:分子筛25％,凹凸棒土42.6％,粉煤灰32.4％,钝化后浸出液中重金属Pb含量为0.027 1 mg/L,明显低于地表水质量标准的Ⅲ类标准0.05 mg/L.     

基于两高司法解释的突发环境事件应急监测风险管理的思考

突发环境污染事故的发生,往往伴随着环境违法行为,因此突发性环境污染监测涉刑的可能性更大.因此环境监测站在实施突发性环境污染事件监测工作时,在环境监测环节及时收集可能的违法证据,形成证据链,为复现环境污染事件提供证据,为司法界入及时提供技术支持.根据风险管理原则,采用矩阵法对涉刑下的突发性环境事件应急监测进行了风险事件识别和风险评价,详细地对涉刑情形下的突发性环境事件应急监测进行环境分析,并提出了相应的风险应对措施,为环境监测系统防范和规避风险提供参考.     

A cross‐level model of shared leadership,meaning, and individual creativity

Research on leadership and creativity is dominated by the study of leadership from people in formal leadership positions. The very nature of creativity requires self‐direction, however. This points to shared leadership, a process in which members dynamically share the leadership role, as a particularly relevant influence to consider. Drawing on psychological empowerment theory, we develop the shared leadership perspective on individual creativity. We argue that shared leadership has a cross‐level influence on individual creativity that is mediated by the experience of meaning of work and moderated by individual differences in power distance value: for individuals lower on power distance, shared leadership has a positive linear relationship with individual creativity; for individuals higher on power distance, shared leadership has a curvilinear relationship with individual creativity that is decreasingly positive. Using a sample of 623 members from 95 teams in 34 Chinese organizations, we find support for this multilevel model. Findings offer theoretical implications for shared leadership and creativity research and provide managerial implications.     

生态修复技术在富营养化水库水质改善中的应用研究

2006年初对广东省大镜山水库实施了生态修复工程,工程运行一年后,对该生态修复工程的效果进行了分析,结果表明：生态修复技术实施一年后,大镜山水库富营养化水平明显降低。与进水口（C区）相比,生态修复工程区（A、B区）透明度增加,氮、磷营养盐含量都有不同程度的降低。生态修复工程区TN、NH4-N与C区同期比最大降幅分别达19.6%、90.4%,TP、PO4-P同期比最大降幅分别达49.5%、67.5%,同时生态修复工程区内的叶绿素浓度也明显低于C区。     

模拟纳污水体底质参数变化

本文介绍了模拟纳污水体中ＷＡＲ，ＷＭＲ，ＷＣＨ，ＳＡＲ，ＳＭＲ，ＳＳＦ和ＲＯＣ的变化。过程曲线表明水体污染时底质参数出现累积现象。     

Detection of geosmin and 2-methylisoborneol by liquid-liquid extraction-gas chromatograph mass spectrum (LLE-GCMS) and solid phase extraction-gas chromatograph mass spectrum (SPE-GCMS)

Two sample preparation methods were introduced and compared in this paper to establish a simple, quick and exact analysis of geosmin and 2-methylisoborneol. LC-18 column was employed in solid phase extraction (SPE), 1.0 mL of hexane was adopted in liquid-liquid extraction (LLE), and the extracts were analyzed by gas chromatograph mass spectrum (GCMS) in selected ion mode. Mean recoveries of SPE were low for 2-methylisoborneol (2-MIB) and geosmin (GSM) with values below 50%. For LLE, the recoveries were satisfyingly above 50% for 2-MIB and 80% for GSM. Detection limits of the LLE method were as low as 1.0 ng/L for GSM and 5.0 ng/L for 2-MIB. A year-long investigation on odor chemicals of drinking water in Shanghai demonstrated that in the summer, there was a serious odor problem induced by a high concentration of 2-MIB. The highest concentration of 152.82 ng/L appeared in July in raw water, while GSM flocculation was minimal with concentrations below odor threshold.     

城市生活垃圾中酞酸酯的微生物降解

从酞酸酯生产厂排污沟中分离到４株酞酸酯降解菌，分属镰孢属（Ｆｕｓａｒｉｕｍ　ｓｐ．）、醇母属（Ｓａｃｃｈａｒｏｍｙｃｅｓ　ｓｐ．）、不动杆菌属（Ａｃｉｎｅｔｏｂａｃｔｅｒ　ｓｐ．）、黄单孢菌属（Ｘａｎｔｈｏｍｏｎａｓ　ｓｐ．）。在酞酸酯剂量为５０、２５μｇ／ｍＬ水平的纯培养条件下，４株单菌对酞酸酯的降解率达到７２％－７７％，混合菌的降解率还可提高近１０％。在垃圾堆肥中酞酸酯剂量为１９７μｇ／ｇ的水平下，将降解菌回接堆肥后，不动杆菌属和混合菌对酞酸酯的降解率最高，分别达到７２％和６９％。     

不同农业措施对稻田甲烷排放通量的影响

经过三年的田间试验发现,稻田甲烷排放通量随着农业措施的不同而大幅度地变化。在1990年至1992年的三个晚稻生长季节里,试验地块的甲烷排放通量分别为10.83、25.18及19.85mg/m~2·h。半旱式栽培使甲烷排放量减少了约1/3;施用硫酸铵、烤田、间歇灌溉亦可显著地降低甲烷排放通量。高有机肥与长期淹水是造成稻田甲烷排放量大的主要原因。控制稻田甲烷排放的关键在于调节灌溉水。只要采用合适的灌溉制度。有机肥用量的增加不一定引起甲烷排放量的增大。     

水样中塔崩和磷酸乙酯的气相色谱—质谱测定方法的研究

本文对水样中的塔崩及其降解产物磷酸乙酯的提取方法进行了研究，试验了不同的萃取剂及萃取时溶液的ｐＨ值，优化了萃取条件，在ｐＨ＝９时，二氧甲烷萃取塔崩的回收率较高，三次测定的变异系数小于３．０％，用气相色谱－质谱（ＥＩ方式）法测定了水样中的塔崩和磷酸乙酯。     

污水排海工程设计的初步研究

本文结合我国国情根据混合区边缘污染物背景值以及海域功能，从而确定允许的污染物最大增加值，并具此推算出扩散器长度和起始稀释度。