Gas Transfer Coefficient Evaluation in the Mediterranean Sea Using Bomb Produced Radiocarbon

A study on the carbon dioxide exchange at the water-air interface in the Western Mediterranean Sea was carried out. the attention was focused on the mean air-sea flux estimations by radiocarbon profiles and bomb ¹⁴C concentration atmospheric data. Sampling techniques and analytical methods are reported; mass balance evaluations on data recorded during the MED'92 cruise are presented and discussed briefly.     

The Water Quality of Kingston Harbour: Evaluating the Use of the Planktonic Community and Traditional Water Quality Indices

Abstract

Kingston Harbour has been experiencing increased levels of organic pollution since initial ecological assessments in 1971. to develop a new baseline of eutrophication in the Harbour 20 years later, and determine the most appropriate indices to be used in the continued monitoring the area, the water quality of Kingston Harbour was reassessed between December 1992 and 1993, by contemporaneous sampling of traditional water column parameters and planktonic communities at 28 stations within the Harbour. Indices used for water quality assessment were temperature, salinity, light penetration, dissolved oxygen, BOD and nutrients (nitrates-N, phosphate-P and ammonia-N). Results indicated that the planktonic community provided the most reliable index of increased eutrophication and changes in water quality. While physical variables indicated little change in Harbour waters and chemical variables indicated significant but erratic changes, the planktonic community displayed the classic characteristics of eutrophication. Phytoplankton biomass (a maximum of 148 mg m^?3 chlorophyll a) was 5 to 10 times greater than in 1971 while zooplankton abundances (maximum of 80,000 animals m^?3) were 4 times greater. in both cases the community composition had altered and there were fewer taxa than previously found.     

Trace Metals in Fish and Crustaceans - Identifying Heavier Polluted Areas in the Ghanaian Continental Shelf

Abstract

The concentrations of four trace metals, namely copper, lead, cadmium and manganese, were determined in six fish species and three crustaceans collected from five sites spanning over 70% of the Ghanaian coastline.

Copper and lead were determined in Barracuda (Spraena spraena), the Ribbon fish (Trichiurus lepturus), the Sardine (Sardinella spp), the Sole (Cynoflossus senegalensis), the Sea Bream (Pagrus coupei) and the Soldier fish (Cynapastas marmuratus). Cadmium and manganese were analyzed in the Blue Crab (Callinectes sepidus), the Spiny lobster (Panilirus regius) and the edible shrimp (Crago septempinosus). Sampling sites included Takoradi, Elmina, Cape Coast, Accra and Tema.

Lead and copper in the fishes ranged 0.25-0.94 μgg^?1 fresh weight and 0.40-2.54 μgg^?1 dry weight (FW) respectively whilst cadmium and manganese in the crustaceans ranged 0.05-0.083 μgg^?1 FW and 0.554-1.404 μgg^?1 FW respectively.

The Barracuda accumulated the greatest amount of metals whilst the sardine accumulated the least. with the crustaceans, there was a significant difference between the amounts of the metals accumulated. the blue crab accumulated the greatest and the edible shrimp the least.

The analysis showed that: (i) there was a positive correlation between the metals bioconcentrated and the extent of pollution of the marine waters and (ii) along the Ghanaian Continental Shelf, the extent of pollution was of the increasing order as: Elmina = Cape Coast < Takoradi < Accra < Tema. Pollution of the marine waters could be minimized by control of flow of pollutants from land based activities.     

Origin and Distribution of Suspended Organic Matter As Inferred From Carbon Isotope Composition in A Mediterranean Semi-Enclosed Marine System

Abstract

The origin and distribution of suspended organic matter, the trophic features and the stable carbon isotopic composition of particulate organic carbon (POC) were studied monthly in a Western Mediterranean semi-enclosed basin. Sampling stations were selected as a function of wind-exposure and the degree of vegetation cover and then compared with an adjacent unvegetated site. the predominant vegetation was seagrass (Posidonia oceanica and Cymodocea nodosa) and Caulerpa prolifera. Water samples were analyzed for total suspended matter (inorganic and organic fractions), photosynthetic pigments (chlorophyll-a and phaeopigments), dissolved organic carbon, particulate organic carbon and their isotopic composition. Temperature and salinity were also measured at the same sampling sites within range of Mediterranean limits. the suspended organic matter concentration was 1.77 ± 1.55 mg l^?1; the chlorophyll-a concentration was low (0.35 ± 0.24 μg l^?1); the disolved organic carbon concentration was 2,140 ± 2,010 μg l^?1; the particulate organic carbon concentration was 212 ± 106 μg l^?1 and the isotopic composition was 18.77 ± 2.51%_°. There were significant temporal differences except for phaeopigments, POC and its POC isotopic composition, and there were no spatial differences other than for δ¹³C. This picture highlighted a general seasonal trend and trophical features similar to adjacent sea.

Spatial differences in δ¹³C showed that the source of suspended organic matter was different between stations as that between sources and wind-hydrodynamic constraints. In     

Volatile halogenated organics in swimming pools

This survey undertaken in Greece (Mytilene town) has shown that Volatile halogenated organics (VHO) are present in swimming pool water. Analysis was performed by purge‐and‐trap (PAT) gas chromatographic (GC) technique and samples from two public indoor swimming pools in Mytilene were analyzed for VHO. Water samples were collected every week for a period of three months, and have shown the occurrence of chloroform, dichlorobromomethane, chlorodi‐bromomethane, bromoform (all four are trihalomethanes [THMs]), as a result of the chlorination and the occurrence of tetrachloroethylene and 1,1,1,2‐tetrachloroethane is assigned to their introduction as impurities during the process treatment of water. The levels of concentrations ranged from 4.0 to 26.0 μg/1 for chloroform, from 0.26 to 7.0 μg/1 for dichlorobromomethane, from 0.5 to 3.0 μg/1 for chlorodibromomethane, from 0.07 to 0.9 μg/1 for bromoform, from no detectable levels to 0.07 μg/1 for tetrachloroethylene and from no detectable levels to 0.2 μg/1 for 1,1,1,2‐tetrachloroethane.     

The distribution,metabolism and toxicity of 14c-DDT in model aquarium tanks with fish and sediment simulating a tropical marine environment

Studies conducted on the distribution, fate and metabolism of DDT in a model ecosystem simulating a tropical marine environment of fish, Gobious nudiceps, Lethrinus harak, Gobious keinesis, Gobious nebulosis and white shrimp (Panaeus setiferus), show that DDT concentration in the water decreases rapidly within the first 24?h. Rapid accumulation of the pesticide in the biota also reaches a maximum level in 24?h before gradually declining. The bioaccumulation factors calculated for the fish species (G. keinesis) and white shrimp (P. Setiferus) were 270 and 351, respectively, after 24?h. There was a steady build up of DDT residues in the sediment during the first 24?h which continued to a maximum concentration of 6.66?ng/g in the seawater/fish/sediment ecosystem after 3 weeks and 5.27?ng/g in the seawater/shrimps/sediment ecosystem after 2.7 days. The depuration of the accumulated pesticide was slow with only 54% lost in G. nudiceps within 3 days of exposure in fresh sea water. By contrast, depuration was fast in the white shrimp, which lost 97% of the accumulated pesticide under the same conditions. DDT was found to be toxic to two of the fish species (G. nebulosis and L. harak) and to white shrimp, and the degree of toxicity was dependent on the particular species. The 24?h LC₅₀ at room temperature for the fish species G. nebulosis and white shrimp was found to be 0.011 and 0.116?mg/kg, respectively. These levels are comparable to the ones recorded for the temperate organisms. Degradation of DDT to its primary metabolites, DDE and DDD, was found in all the compartments of the ecosystem with DDE being the major metabolite in the fish, shrimps and sediment, while in seawater, DDD dominated as the major metabolite.     

Effect of white African mineral hair dye on the activities of phosphatases and malondialdehyde level in selected tissues of albino rats

The effect of white African mineral dye Yombofita (YF) on the activities of alkaline phosphatase (ALP), acid phosphatase (ACP) and malondialdehyde (MDA) levels in the skin, liver, kidney and serum of albino rats was investigated. The chemical analysis of the dye was first carried out using solubility test, pH determination and X-ray fluorescence (XRF) elemental analysis. Six different concentrations (0.05, 0.15, 0.25, 0.5, 0.75 and 1.00%) of the dye were prepared using hydrogen peroxide (30 volume) as solvent. A total of 80 albino rats (Rattus norvegicus) were used for the study. The rats were divided into 8 groups of 10 each and were maintained on commercial feed for the period of the experiment i.e. 30 days. In group 1, the control group, the animals were applied distilled water on their heads, whereas in group 2 the vehicle i.e. hydrogen peroxide was applied. In groups 3 to 8 various concentrations of YF (white) dye ranging from 0.05, 0.15, 0.25, 0.5, 0.75 to 1.00% was applied respectively. At the end of the experiment, blood samples were collected and portions of the selected tissues were excised for the determination of ALP and ACP activities. The MDA level was also determined in the skin of experimental animals. The results revealed a significant decrease (p?p?相似文献   

Removal of selenite using ‘waste’ Fe(III)/Cr(III) hydroxide: Adsorption kinetics and isotherms

Removal of selenite [Se (IV)] from aqueous solution on to industrial solid ‘waste’ Fe(III)/Cr(III) hydroxide as adsorbent was investigated in the present article. Maximum adsorption was found to be at pH 4.0. Pretreated Fe(III)/Cr(III) hydroxide was found to be more efficient for the removal of selenite compared to untreated adsorbent. Langmuir and Freundlich isotherms have been studied. The Langmuir adsorption capacity (Q ₀) of the pretreated and untreated adsorbents was found to be 15.63 and 6.04?mg?g^?1, respectively. The adsorption process fit into the second-order kinetics. Thermodynamic parameters show that the adsorption process is spontaneous and endothermic in the temperature range 32 to 60°C. Coexisting anions vanadate and phosphate significantly affect the adsorption of selenite for both the pretreated and untreated adsorbents. Molybdate, thiocyanate, sulphate, nitrate and chloride do not significantly affect the removal of selenite for pretreated adsorbent.     

Determination of types of interactions exhibited by binary mixtures of heavy metals tested against the hermit crab,Clibanarius africanus

Single and joint action toxicity of heavy metal compounds (ZnCO₃, CuSO₄ and CdSO₄) were carried out against the hermit crab, Clibanarius africanus in laboratory bioassays. On the basis of 96?h LC₅₀ values, CuSO₄ (96?h LC₅₀?=?0.03?mM) was found to be the most toxic followed by CdSO₄ and ZnCO₃ (96?h LC₅₀?=?0.24?mM) in decreasing order of toxicity. The evaluation of the metal compounds in mixtures of ZnCO₃–CuSO₄, ZnCO₃–CdSO₄ and CdSO₄–CuSO₄ in pre-defined molar ratios revealed that interactions between Zn–Cu and Zn–Cd test mixtures were in conformity with the models of antagonism (reduction in toxicity of constituent metals). The synergistic ratios (S.R.s) and relationship between observed/predicted 96?h LC₅₀ values (relative toxic unit, RTU) were consistently below 1, indicating antagonistic interactions. Analysis using isobolograms also indicated the interactions between the mixture components to be antagonistic. However, with regards to CdSO₄–CuSO₄ test mixtures, the interactions between these metals were mainly in conformity with the model of synergism. The S.R. and RTU values were largely above 1, indicating synergistic interactions. The importance of the joint action evaluations for the management and protection of aquatic ecosystems, particularly in the setting up of water quality criteria was discussed.