Sustainability indicators of water sharing compacts

There is an increasing crisis of fresh water availability throughout the world. Sharing the available water resources in a sustainable manner among numerous stakeholders in the backdrop of this crisis is more challenging. Very often water conflicts are triggered out in this challenging scenario. These conflicts are sometimes reconciled with compacts on sharing. Water sharing compacts on both surface and aquifer resources are very common. Whether these compacts are founded on postulates of sustainability is the important question we want to investigate. Conflicts resurface when the sustainability of a compact is at stake. In this paper, we are reviewing three compacts on surface water sharing to understand their sustainability perspectives and how it has helped addressing conflicts. An introduction to various legal instruments promulgated aiming water conflict abatement is given first. Different types of water sharing agreements being signed in the current water management practice are also looked into. Theoretical background of sustainability analysis, both quantitative and qualitative, applicable in the case of water sharing models is then discussed. This is followed by specific case study analysis of three interstate water sharing agreements executed in basins of different agro-climatic regions across the world. It includes the Colorado basin (USA), Murray Darling basin (Australia) and the Parambikulam Aliyar Project (PAP) basins (India). Interstate water sharing agreement of these basins is critically examined and compared to comment on its sustainability perspective. The Murray Darling basin and its compact appear to be better in its overall considerations of sustainability. Compared to Colorado and Murray Darling, PAP requires major revisions in its sustainability context. E flows and stochastic modeling are the thrust areas of PAP that require major revision.     

Effects of meteorology on ground-level ozone (GLO) concentrations and identifying the hot spots having significantly higher GLO concentration in a semi-urban area

The present study aims to analyse the influences of five meteorological parameters (temperature, wind speed, barometric pressure, rainfall, and solar radiations) on ground-level ozone (GLO) concentrations over the region of Ranchi Municipal Corporation (Jharkhand, India). The diurnal variation of GLO concentration and the meteorological parameters were analysed in each month to understand the associations. The results indicated that the correlation coefficients of GLO concentration with SR, AT, and DPT are found to be positive in each month and also statistically significant. But, the association between WS and GLO concentration was not uniform between the study days. Furthermore, the study also demonstrates an approach for identifying the hot spots that are having the higher level of GLO concentration. The hot spot maps were produced for each month to understand the shifting of the locations of hot spot locations. The results reveal that the hot spot locations are changes frequently in each case. Since the hot spot analysis was conducted with limited data, the presented hot spots are indicative and dependent on the meteorological conditions of the specific period and cannot be considered as a robust epidemiological study.     

Exploring dynamism of cultural ecosystems services through a review of environmental education research

The field of cultural ecosystem services (CES) explores the non-material benefits that ecosystems provide to people. Human perceptions and valuations change, for many reasons and in many ways; research on CES, however, rarely accounts for this dynamism. In an almost entirely separate academic world, research on environmental education (EE) explores how EE programming affects peoples’ attitudes and values toward the natural world. In this review of 119 EE research publications, we explore whether CES (and the adjacent concept of relational values) can be dynamic. We approach this via two lines of inquiry that explore whether EE may instigate this change. First, we investigate whether the EE community measures (and tries to affect) CES-related outcomes. Second, we ask: Has EE research detected changes in CES-related outcomes? We find the EE programs measure many CES outcomes (e.g., aesthetic appreciation, social connectedness), and that in most cases studies observe increases in these outcomes after EE experiences.     

The search for an alternative to piped water and sewer systems in the Alaskan Arctic

Forty-two communities in rural Alaska are considered unserved or underserved with water and sewer infrastructure. Many challenges exist to provide centralized piped water and sewer infrastructure to the homes, and they are exacerbated by decreasing capital funding. Unserved communities in rural Alaska experience higher rates of disease, supporting the recommendation that sanitation infrastructure should be provided. Organizations are pursuing alternative solutions to conventional piped water and sewer in order to maximize water use and reuse for public health. This paper reviews initiatives led by the State of Alaska, the Alaska Native Tribal Health Consortium, and the Yukon Kuskokwim Health Corporation to identify and develop potential long-term solutions appropriate and acceptable to rural communities. Future developments will likely evolve based on the lessons learned from the initiatives. Recommendations include Alaska-specific research needs, increased end-user participation in the design process, and integrated monitoring, evaluation, and information dissemination in future efforts.     

Contamination of marine fauna by chlordecone in Guadeloupe: evidence of a seaward decreasing gradient

Chlordecone is an organochlorine pesticide, used in the Lesser Antilles from 1972 to 1993 to fight against a banana weevil. That molecule is very persistent in the natural environment and ends up in the sea with runoff waters. The objective of the present study is to evaluate the level of contamination in several trophic groups of marine animals according to their distance from the source of pollution. Samples of suspended matter, macroalgae, herbivorous fishes, detrivorous crustaceans, zooplanktivorous fishes, first- and second-order of carnivorous fishes, and piscivorous fishes have been collected in two sites, located downstream the contaminated sites (Goyave and Petit-Bourg), in three marine habitats (coastal mangroves, seagrass beds located 1.5 km from the shoreline, and coral reefs at 3 km offshore). Animals collected in mangroves were the most contaminated (mean concentrations 193 μg kg^?1 in Goyave and 213 μg kg^?1 in Petit-Bourg). Samples from seagrass beds presented intermediate concentrations of chlordecone (85 μg kg^?1 in Goyave and 107 μg kg^?1 in Petit-Bourg). Finally, samples from coral reefs were the less contaminated (71 μg kg^?1 in Goyave and 74 μg kg^?1 in Petit-Bourg). Reef samples, collected 3 km offshore, were two to three times less contaminated than those collected in mangroves.     

Trace analysis of parabens preservatives in drinking water treatment sludge,treated, and mineral water samples

Parabens have been widely used as antimicrobial agents, mainly in food products, pharmaceuticals, and cosmetics. Although they are known as safe preservatives, they also cause some harm to human health, which has been discussed lately. Therefore, the aim of this study was to evaluate the occurrence of nine parabens (including isomers) in mineral and drinking waters, besides in drinking water treatment sludge (DWTS) samples with determination by liquid chromatography tandem mass spectrometry (LC-MS/MS). Both methods solid phase extraction (SPE) and QuEChERS were validated. Calibration curves showed a correlation coefficient of 0.99 for all compounds. LOQ values ranged from 0.04 to 4 μg L^?1 in aqueous matrices and from 5 to 500 ng g^?1 in DWTS. Recoveries between 70 and 115% were reached with RSD below 20% for all compounds in SPE whereas recoveries between 62 and 119% were found with RSD below 20% for almost all compounds in QuEChERS. Matrix effect had low values (<?20%); it was only above 20% for methylparaben in the SPE and for pentylparaben in the QuEChERS. Using a quick and simple extraction procedures with SPE, QuEChERS, and LC-MS/MS analyses, these methods proved to be selective and sensitive. They were successfully applied to real samples (treated water, mineral water, and sludge), and methylparaben was detected at concentration levels below 0.242 μg L^?1 in mineral and treated water samples and 10 ng g^?1 in DWTS samples.     

PCB exposure and potential future cancer incidence in Slovak children: an assessment from molecular finger printing by Ingenuity Pathway Analysis (IPA®) derived from experimental and epidemiological investigations

The risk of cancer due to PCB exposure in humans is highly debated. In eastern Slovakia, high exposure of the population to organochlorines (especially PCBs) was associated with various disease and disorder pathways, viz., endocrine disruption, metabolic disorder & diabetes, and cancer, thereby disturbing several cellular processes, including protein synthesis, stress response, and apoptosis. We have evaluated a Slovak cohort (45-month children, at lower and higher levels of PCB exposure from the environment) for disease and disorder development to develop early disease cancer biomarkers that could shed new light on possible mechanisms for the genesis of cancers under such chemical exposures, and identify potential avenues for prevention.

Microarray studies of global gene expression were conducted from the 45-month-old children on the Affymetrix platform followed by Ingenuity Pathway Analysis (IPA®) to associate the affected genes with their mechanistic pathways. High-throughput qRT-PCR TaqMan low-density array (TLDA) was performed to further validate the selected genes on the whole blood cells of the most highly exposed children from the study cohort (n = 71).

TP53, MYC, BCL2, and LRP12 differential gene expressions suggested strong relationships between potential future tumor promotion and PCB exposure in Slovak children. The IPA analysis further detected the most important signaling pathways, including molecular mechanism of cancers, prostate cancer signaling, ovarian cancer signaling, P53 signaling, oncostatin M signaling, and their respective functions (viz., prostate cancer, breast cancer, progression of tumor, growth of tumor, and non-Hodgkin’s disease). The results suggest that PCB exposures, even at the early age of these children, may have lifelong consequences for the future development of chronic diseases.

     

A multivariate examination of ‘artificial mussels’ in conjunction with spot water tests in freshwater ecosystems

Metal pollution in aquatic systems is considered a serious environmental issue globally due to their ability to accumulate in aquatic environments. Wetlands are vulnerable to this pollution as they are known to trap toxins, removing them from the water. Artificial mussel technology, originally developed for marine environments, was applied to this freshwater system and spot water samples were collected. The Nyl River floodplain (Ramsar classified) is one of the largest and most ecologically significant wetlands in South Africa. The aims of this study were to determine metal contamination along the Nyl River system by means of artificial mussels (AM) and water ICP-MS analysis and to determine whether the use of AMs in conjunction with spot water testing could give more insight into the pollution in freshwater wetlands. The concentrations of Al, Cd, Cr, Co, Cu, Fe, Mn, Ni, Pb and Zn were determined at seven sites. It was determined that the levels accumulated by the AMs differed in spatial and temporal trends when compared to spot water samples. It was determined that there were high levels of some metals found in the spot water tests that were not corroborated by the AMs results, which could indicate isolated pollution events. The use of AMs in conjunction with spot water testing was determined to be beneficial in gaining deeper insight into water metal conditions in dynamic freshwater systems.     

Multivariate analyses of the effect of an urban wastewater treatment plant on spatial and temporal variation of water quality and nutrient distribution of a tropical mid-order river

Freshwater resources are increasingly scarce due to human activities, and the understanding of water quality variations at different spatial and temporal scales is necessary for adequate management. Here, we analyze the hypotheses that (1) the presence of a wastewater treatment plant (WWTP) and (2) a polluted tributary that drains downstream from the WWTP change the spatial patterns of physicochemical variables (pH, turbidity, dissolved oxygen, and electrical conductivity) and nutrient concentrations (reactive soluble phosphorus, total phosphorus, nitrogen series, total nitrogen, and total dissolved carbon) along a mid-order river in SE Brazil and that these effects depend on rainfall regime. Six study sites were sampled along almost 4 years to evaluate the impacts of human activities, including sites upstream (1–3) and downstream (5–6) from the WWTP. The impacts were observed presenting an increasing trend from the source (site 1) towards Água Quente stream (site 4, the polluted tributary), with signs of attenuation at site 5 (downstream from both WWTP and site 4) and the river mouth (site 6). Input of nutrients by rural and urban runoff was observed mainly at sites 2 and 3, respectively. At sites 4 and 5, the inputs of both untreated and treated wastewaters increased nutrient concentrations and changed physicochemical variables, with significant impacts to Monjolinho River. Seasonal variations in the measured values were also observed, in agreement with the pluviometric indexes of the region. Univariate analyses suggested no effect of the WWTP for most variables, with continued impacts at sites downstream, but non-parametric multivariate analysis indicated that these sites were recovering to chemical characteristics similar to upstream sites, apparently due to autodepuration. Therefore, multivariate methods that allow rigorous tests of multifactor hypotheses can greatly contribute to determine effects of both point and non-point sources in river systems, thus contributing to freshwater monitoring and management.     

The probabilistic tsunami hazard assessment along Karnataka Coast from Makran Subduction Zone,west coast of India

Coastal tsunami amplitudes were calculated to identify areas susceptible to tsunami hazard at selected locations of the coast of Karnataka, west of India, due to earthquakes in the Makran Subduction Zone. This is the first time that the probabilistic tsunami hazard assessment along this study area has been attempted. A series of earthquake source scenarios with magnitudes of Mw 8.0, Mw 8.5, and a mega thrust of Mw 9.1 were modeled by using the Community Model Interface for Tsunami interface with the MOST model of Titov and Synolakis (J. Waterway, Port, Coastal and Ocean Engineering, 121(6), 308–316, 1995). As per the previous occurrences, the two least magnitudes are probable, while Mw 9.1 is a worst-case scenario as described by Heidarzadeh et al. (Ocean Engineering, 36(5), 368–376, 2009) and the same is reported by Burbidge et al. (Geoscience Australia Professional Opinion No. 2009/11) as high magnitude. These are not at all historical earthquakes or specifically from historical catalogues. The results of modeling show that all the seven coastal locations are inundated barely in our worst-case scenario with maximum water levels in the range of 100–200 cm. The first tsunami wave strikes the coast within 4–5 h of earthquake occurrence.