Trends in motor-vehicle related air pollutants in central London

Results of intermittent monitoring of six aromatic hydrocarbons (benzene, toluene, ethyl-benzene, m-xylene, p-xylene and o-xylene), carbon monoxide and oxides of nitrogen over a thirteen year period at a site in central London (Exhibition Road) are presented. Four monitoring regimes were undertaken; namely, 1979, 1982/83, 1986/87 and 1991/92. The summertime daytime mean ambient concentrations of the measured parameters at this site are presented. The reported concentrations show a reduction from 1979 to 1992 by approximately a factor of two, despite national increases in motor fuel consumption and the volume of traffic. Relevant European Community legislation covering emissions from motor-vehicles are outlined and comparisons are made with emissions from motor vehicles predicted from the UK national inventory. The importance of the frequency of measurements was also noted.     

Methane emissions from natural wetlands

Methane is considered one of the most important greenhouse gases in the atmosphere. Because of the strict anaerobic conditions required by CH₄-generating microorganisms, natural wetland ecosystems are one of the main sources of biogenic CH₄. The total natural wetland area is estimated to be 5.3 to 5.7 × 10¹² m², making up less than 5% of the Earth's land surface. However, natural wetland plays a disproportionately large role in CH₄ emissions. Wetlands are likely the largest natural sources of CH₄ to the atmosphere, accounting for about 20% of the current global annual emission. Out of the total amount of CH₄ emitted, northern wetlands contribute 34%, temperate wetlands 5%, and tropical systems about 60%.Because of the unique characteristics and high productivity, wetland ecosystems are important in the global carbon cycle. Natural wetlands are permanently or temporarily saturated. Strict anaerobic conditions consequently develop, which allows methanogenesis to occur. But the thin oxic layer and the oxic plant rhizophere promote activity of CH₄-oxidizing bacteria or methanotrophs. Thus, both CH₄ formation and consumption in wetland systems are microbiological processes and are controlled by many factors. Eight of the controlling factors, including carbon supply, soil oxidation-reduction status, pH, temperature, vegetation, salinity and sulfate content, soil hydrological conditions and CH₄ oxidation are discussed in this paper.     

Overstory mortality as an indicator of forest health in California

The interagency Forest Health Monitoring Program involves a network of about 4200 forest plots on a triangular grid across the United States. We present data on recent mortality of trees 27.9 cm diameter from the first three years of measurements in California (1992–1994). Three plot designs were used to collect data representative of a 1-ha stand at each site; the designs differed primarily in total area sampled (0.067, 0.4 and 1.0 ha). Approximately 50 sites were visited each year yielding a total of about 150. Field tallies showed few cases of recent mortality in the smallest plot size. Cumulative distribution functions of recent dead tree densities in the 0.067-ha plots differed significantly from those generated by tallies from entire 1-ha stands. We conclude that an area of 0.067 ha is unsuitable to assess and monitor overstory mortality in Pacific Coast forests.The U.S. government right to retain a non-exclusive, royalty free licence in and to any copyright is acknowledged.     

Study of heat exposure in the work environment in Jeddah

The present work was conducted to define the magnitude of the problem of heat exposure in Jeddah and the role of both the climatic and the industrial factors on the total heat load. Indoor heat exposure was studied in an industrial complex of 5 plants for cables' manufacturing. Outdoor heat exposure was studied in shaded and unshaded operations in Jeddah Islamic Port (JIP). The heat exposure parameters, including air temperature (Ta), wet bulb temperature (Tw), and globe temperature (Tg), as well as the wet bulb globe temperature (WBGT) heat stress index, the relative humidity and the air velocity, were assessed at representative locations. Results of the study indicated that:

Estimating Trophic State Proportions of a Regional Lake Population: Are Larger Samples Always Better?

During the summers of 1991–1994, the Environmental Monitoringand Assessment Program (EMAP) sampled 344 lakes throughout thenortheastern United States using a proportional stratified sampling design based on lake size. Approximately one-quarter ofthe 344 lakes were sampled each year (4 years) for totalphosphorus to determine the proportion (and associated95% confidence intervals) of the northeast lake population 1ha (11,076 ± 1,699 lakes) that was in oligotrophic,mesotrophic, eutrophic, or heupereutropic (4 classes) conditionaccording to the total phosphorus criteria of the North AmericaLake Manegement Society. Estimates for the second, third, andfourth yr were developed as cumulative of the previous yrsamples and the current yr samples for the northeast as a wholeand for each of its three ecoregions (4 regions). New confidence intervals were computed for each cumulative yrcondition estimate. This produced a total (4 years × 4classes × 4 regions) of 64 cumulative yr tropic conditionestimates. Confidence intervals for 21% of these estimates didnot shorten with increased sample size. This phenomena raisedquestions about the accuracy of estimates based on cumulativesampling procedures. We explain why and how the phenomenon comesabout with both straight random and proportional randomsampling. Further, we present an example of the effects thisphenomenon has on lake tropic state condition estimates in thenortheastern United States.     

Adsorption characteristics of a phenoxy acetic acid herbicide on activated carbon

The adsorption of 2,4-dichlorophenoxyacetic acid (2,4-D) by two powdered coal activated carbons was studied in aqueous solution. The modelling of the adsorption equilibrium showed that the adsorption of 2,4-D fitted a Langmuir isotherm. Adsorption was influenced by the activated carbon type, adsorbent concentration and solution characteristics. The adsorption was found to decrease with an increase in pH over the range 1.5-9. Maximum adsorption occurred at pH approximately 2.5, which corresponds to the 2,4-D pKa value. The amount of 2,4-D adsorbed was also found to depend on the NaCl concentration.     

Indoor and outdoor formaldehyde concentrations in homes in residential areas in Greater Cairo

Indoor and outdoor measurements of formaldehyde were conducted at seven flats located in residential areas in Greater Cairo, during spring and summer seasons 1999. The mean daytime formaldehyde concentrations in kitchens, bedrooms and living rooms were 89, 100 and 100 ppb, respectively, in the seven flats. Significant positive correlations were found between the concentrations of formaldehyde found in these three rooms. On the other hand, no significant differences were found between the mean formaldehyde concentrations in these three rooms. The maximum mean concentration of formaldehyde (147 ppb) was recorded in a new flat, while the minimum concentration (43 ppb) was observed in an old flat. The maximum hourly and daytime concentrations were 350 and 225 ppb, respectively. Air temperature, relative humidity and the age of the flat are factors affecting the emission and concentration of formaldehyde. The maximum indoor and outdoor formaldehyde concentrations were recorded during the summer season. During the spring, 38% of the samples indicated that the concentration of formaldehyde in the seven flats exceeded 0.1 ppm, the American Society of Heating, Refrigerating, and Air Conditioning Engineers' (ASHRAE) standard; in the summer, this figure increased to 53%.     

Evaluation of airborne lead in the welding working environment

Manual and automatic welding machines (which use leaded alloys) are considered to be important sources of the emission of lead fumes into the general air of the working environment. Three workplaces at a television factory were selected for the present study, to determine the control class of the working unit. The concentrations of conventional measurements ("A" sampling points) were lower than the administrative control level (statutory standard of lead, 150 microg m(-3)), whereas the maximum concentration of 264.1 microg m(-3) ("B" sampling point) was higher at one working unit than the administrative control level. However, the control classes varied between class III (bad) and class I (good).     

Young northern pike,yellow perch and crayfish as bioindicators in a mercury contaminated watercourse

Young-of-the-year and yearling northern pike (Esox lucius), yearling yellow perch (Perca flavescens) and adult crayfish (Orconectes virilis) were collected in the mercury-contaminated Wabigoon/English/Winnipeg River System, Ontario, and analyzed for total mercury. Analysis of mercury concentrations in these organisms produced consistent geographical trends; i.e. mercury concentrations in biota downstream of Dryden > English River system > Winnipeg River system > control sites. In the Wabigoon River system the bioavailability of mercury increases with distance downstream of the historical point source. Mercury concentrations in the biota studied were highly correlated with mercury concentrations in fish species which are of sport and commercial interest. The locations where young fish obtain their bodyburdens are known typically within 100 m. The biota studied compare favourably with the criteria proposed by Phillips (1980) as prerequisites for biological indicators. The wide distribution of young pike, perch and crayfish in North America, Europe and Asia may enhance their appeal as biomonitors.The views expressed are those of the authors and do not necessarily reflect the views of the Ontario Ministry of the Environment. No endorsement should be inferred.