Assessing Ecological Resources for Remediation and Future Land Uses on Contaminated Lands

Increasingly, the public and governmental agencies are concerned about remediating and reclaiming contaminated sites. Understanding the ecological resources on-site and valuing those resources in terms of future uses is important for determining suitable future land uses. In this article, we suggest the major categories of natural resource information required by managers, policy makers, and the general public for making initial future land-use determinations. We then use a dataset of 25 Department of Energy (DOE) sites slated for remediation to explore whether such data are readily available and whether the data can be used to assess natural resource value. Although information is available for almost all sites on federally endangered and threatened species, this information is less available for state-listed species. Biodiversity information is available only for some sites for birds (N = 17), mammals (N = 15), reptiles (N = 14), amphibians (N = 13), and plants (N = 11) and is almost nonexistent for invertebrates (N = 2). Some information is available for invasive species (N = 9). The number of available habitats is directly related to total acres and nonindustrial acres. Biodiversity of birds, mammals, and reptiles (but not amphibians) is directly related to both total acres and total nonindustrial acres of sites. These data suggest that even over a wide geographical area (from eastern to western United States), biodiversity relates to habitat size and number of habitats available. This information will be useful not only to DOE managers but also to natural resource trustees, ecologists, state and federal regulators, and the general public in the discourse over future uses of these lands.*Published online Author to whom correspondence should be addressed; Joanna Burger     

Characterization of visibility impacts related to fine particulate matter in Canada

Canada has recently established standards for the management of particulate matter (PM) air quality. National networks currently measure PM mass concentrations and chemical speciation. Methods used in the U.S. IMPROVE network are applied to the 1994--2000 Canadian fine PM data to obtain a regional reconstruction of the visibility based on particle composition. Nationally, the greatest light extinction occurs in the Windsor-Quebec City corridor. Variations in the dominant chemical species responsible for the reduction in visibility are presented for regions across the country. In most regions, sulfate and nitrate contribute most greatly to reduced visibility. The visibility implications of achieving the Canada-Wide Standard (CWS) across the country are evaluated, with the greatest improvement in visibility associated with achieving the CWS in southern Ontario. Elsewhere in the country, achieving the CWS will actually result in deteriorating air quality. Improving current estimates of visibility requires higher spatially and temporally resolved measurements of organic and elemental carbon fractions and particulate nitrate.     

Chemical (polycyclic aromatic hydrocarbon and heavy metal) levels in contaminated stormwater and sediments from a motorway dry detention pond drainage system

Chemical (polycyclic aromatic hydrocarbon - PAH and heavy metal) levels in stormwater and sediment samples collected from the London Orbital (M25) motorway drainage dry detention pond at Oxted, Surrey, UK were determined. Such chemicals are derived from vehicular combustion products and the wear and tear materials deposited onto the motorway surface. Gas chromatography-mass spectrometry (GC-MS) was used for the qualitative and quantitative determination of 16 USEPA priority PAHs in motorway drainage sediments. The GC-MS method, incorporating a solid phase extraction step, provides detection limits ranging from 0.17 to 0.41 mg kg(-1)(dry weight). Almost all of the 16 USEPA listed PAHs were detected. Phenanthrene, fluoranthene, pyrene, benzo(a)anthracene, chrysene, benzo(b)fluoranthene, benzo(a)pyrene and benzo(g,h,i)perylene (PAH numbers 5, 7, 8, 9, 10, 11, 13 and 16) were among the PAHs found at "higher" levels (ranging from 0.3-10.2 mg kg(-1), dry weight) in the sediment samples. PAH levels show little change along the motorway drainage silt trap (facility for reducing the levels of suspended particulate matter in the stormwater). PAH concentrations are considerably higher in the dry detention pond outflow interceptor. Statistical analysis showed that significant correlation coefficients (based on a t-test at the 95% confidence interval) were obtained between those PAHs found at high concentrations over all of the sampling sites. Several PAHs were dispersed beyond the treatment facility and accumulation in the sediment of the deer park resulted in levels ranging from 0.3-1.6 mg kg(-1), dry weight. These PAHs found beyond the treatment facility (in the local farm deer park) may contribute a serious health threat to farm animals or even fish in the aquatic environment. Heavy metal levels (V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Mo, Cd, Sb and Pb) of the drainage stormwater and sediments were determined by inductively coupled plasma mass spectrometry (ICP-MS), with quality control evaluation using two certified reference materials. Typical detection limits were found to be below 0.1 [micro sign]g l(-1) for stormwater and 0.005 mg kg(-1) for acid digested sediments. Raised heavy metal levels were found throughout the dry detention pond facility and only decrease when the stormwater is diluted following discharge into the river Eden. Statistical analysis also confirms that some significant correlations exist between various heavy metals and PAHs. However, no overall conclusive trend is found indicating that a particular PAH is deposited in sediment relative to a specific heavy metal/s. These results raise some serious concerns about the dispersion and accumulation of chemicals in the sediments of motorway stormwater drainage systems and the need for maintenance and clean-up of contaminated material from such systems.     

Mental models of safety: do managers and employees see eye to eye?

PROBLEM: Disagreements between managers and employees about the causes of accidents and unsafe work behaviors can lead to serious workplace conflicts and distract organizations from the important work of establishing positive safety climate and reducing the incidence of accidents. METHOD AND RESULTS: In this study, the authors examine a model for predicting safe work behaviors and establish the model's consistency across managers and employees in a steel plant setting. Using the model previously described by Brown, Willis, and Prussia (2000), the authors found that when variables influencing safety are considered within a framework of safe work behaviors, managers and employees share a similar mental model. The study then contrasts employees' and managers' specific attributional perceptions. Findings from these more fine-grained analyses suggest the two groups differ in several respects about individual constructs. Most notable were contrasts in attributions based on their perceptions of safety climate. When perceived climate is poor, managers believe employees are responsible and employees believe managers are responsible for workplace safety. However, as perceived safety climate improves, managers and employees converge in their perceptions of who is responsible for safety. IMPACT ON INDUSTRY: It can be concluded from this study that in a highly interdependent work environment, such as a steel mill, where high system reliability is essential and members possess substantial experience working together, managers and employees will share general mental models about the factors that contribute to unsafe behaviors, and, ultimately, to workplace accidents. It is possible that organizations not as tightly coupled as steel mills can use such organizations as benchmarks, seeking ways to create a shared understanding of factors that contribute to a safe work environment. Part of this improvement effort should focus on advancing organizational safety climate. As climate improves, managers and employees are likely to agree more about the causes of safe/unsafe behaviors and workplace accidents, ultimately increasing their ability to work in unison to prevent accidents and to respond appropriately when they do occur. Finally, the survey items included in this study may be useful to organizations wishing to conduct self-assessments.     

SENSITIVITY OF A PRAIRIE WETLAND TO INCREASED TEMPERATURE AND SEASONAL PRECIPITATION CHANGES1

ABSTRACT: We assessed the potential effects of increased temperature and changes in amount and seasonal timing of precipitation on the hydrology and vegetation of a semi-permanent prairie wetland in North Dakota using a spatially-defined, rule-based simulation model. Simulations were run with increased temperatures of 2°C combined with a 10 percent increase or decrease in total growing season precipitation. Changes in precipitation were applied either evenly across all months or to individual seasons (spring, summer, or fall). The response of semi-permanent wetland P1 was relatively similar under most of the seasonal scenarios. A 10 percent increase in total growing season precipitation applied to summer months only, to fall months only, and over all months produced lower water levels compared to those resulting from the current climate due to increased evapotranspiration. Wetland hydrology was most affected by changes in spring precipitation and runoff. Vegetation response was relatively consistent across scenarios. Seven of the eight seasonal scenarios produced drier conditions with no open water and greater vegetation cover compared to those resulting from the current climate. Only when spring precipitation increased did the wetland maintain an extensive open water area (49 percent). Potential changes in climate that affect spring runoff, such as changes to spring precipitation and snow melt, may have the greatest impact on prairie wetland hydrology and vegetation. In addition, relatively small changes in water level during dry years may affect the period of time the wetland contains open water. Emergent vegetation, once it is established, can survive under drier conditions due to its ability to persist in shallow water with fluctuating levels. The model's sensitivity to changes in temperature and seasonal precipitation patterns accentuates the need for accurate regional climate change projections from general circulation models.     

Modeling human-induced climatic change: A summary for environmental managers

The rapid increase in atmospheric concentrations of greenhouse gases has caused concern because of their potential to alter the earth's radiation budget and disrupt current climate patterns While there are many uncertainties associated with use of general circulation models (GCMs), GCMs are currently the best available technology to project changes in climate associated with elevated gas concentrations. Results indicate increases in global temperature and changes in global precipitation patterns are likely as a result of doubled CO₂. GCMs are not reliable for use at the regional scale because local scale processes and geography are not taken into account. Comparison of results from five GCMs in three regions of the United States indicate high variability across regions and among models depending on season and climate variable. Statistical methods of scaling model output and nesting finer resolution models in global models are two techniques that may improve projections. Despite the many limitations in GCMs, they are useful tools to explore climate-earth system dynamics when used in conjunction with water resource and ecosystem models. A variety of water resource models showed significant alteration of regional hydrology when run with both GCM-generated and hypothetical climate scenarios, regardless of region or model complexity. Similarly, ecological models demonstrate the sensitivity of ecosystem production, nutrient dynamics, and distribution to changes in climate and CO₂ levels. We recommend the use of GCM-based scenarios in conjunction with water resource and ecosystem models to guide environmental management and policy in a “no-regrets” framework or as part of a precautionary approach to natural resource protection.     

Economic and equity implications of land-use zoning in suburban agriculture

A cash-flow viability model is used to evaluate the impacts of land-use zoning on farm households in New Jersey. Findings suggest that zoning results in increased production expenses, lower efficiency and profitability, and the devaluation of land assets. Cash flow and economic viability are, thus, reduced. Impacts of zoning on farm incomes, off-farm incomes, revenues from land sales, indebtedness, and farm sizes were not statistically significant. The results suggest that the use of land-use zoning statutes to guarantee the existence of agriculture may not be equitable unless transferable development rights or other methods of compensating farmers for their losses are simultaneously implemented.     

Methods development and use of macroinvertebrates as indicators of ecological conditions for streams in the Mid-Atlantic Highlands Region

The Mid-Atlantic Highlands Assessment (MAHA) included the sampling of macroinvertebrates from 424 wadeable stream sites to determine status and trends, biological conditions, and water quality in first through third order streams in the Mid-Atlantic Highlands Region (MAHR) of the United States in 1993–1995. We identified reference and impaired sites using water chemistry and habitat criteria and evaluated a set of candidate macroinvertebrate metrics using a stepwise process. This process examined several metric characteristics, including ability of metrics to discriminate reference and impaired sites, relative scope of impairment, correlations with chemical and habitat indicators of stream disturbance, redundancy with other metrics, and within-year variability. Metrics that performed well were compared with metrics currently being used by three states in the region: Pennsylvania, Virginia, and West Virginia. Some of the metrics used by these states did not perform well when evaluated using regional data, while other metrics used by all three states in some form, specifically number of taxa, number of EPT taxa, and Hilsenhoff Biotic Index, performed well overall. Reasons for discrepancies between state and regional evaluations of metrics are explored. We also provide a set of metrics that, when used in combination, may provide a useful assessment of stream conditions in the MAHR.     

Comparison of macroinvertebrate sampling methods for nonwadeable streams

Bioassessment of nonwadeable streams in the United States is increasing, but methods for these systems are not as well-developed as for wadeable streams. In this study, we compared six macroinvertebrate field sampling methods for nonwadeable streams adapted from those used by three major programs: the U.S. Environmental Protection Agencys Environmental Monitoring and Assessment Program-Surface Waters, the U.S. Geological Surveys National Water Quality Assessment Program, and the Ohio Environmental Protection Agency, Division of Surface Water Biocriteria Program. We performed all six methods at 60 sites across four rivers and measured water chemistry and physical habitat at each site to assess abiotic conditon. Sites were divided into two groups: those influenced by navigational lock and dam structures (restricted flow, or RF) and those free-flowing or with lowhead dams (run-of-the-river, or ROR). Metrics based on passive Hester-Dendy artificial substrate samplers differed greatly from active sampling methods (i.e., using nets) but represented abiotic conditions well in both ROR and RF sites. Although metric values were similar across certain sampling methods, the metrics significantly correlated with abiotic variables varied among methods and between ROR and RF sites. These results emphasize that methods are not interchangeable, and the ability to detect certain stressors depends on sampling method.The U.S. Governments right to retain a non-exclusive, royalty free licence in and to any copyright is acknowledged.