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排序方式: 共有121条查询结果,搜索用时 15 毫秒
11.
Rainer?HaasEmail author Katrin?Scheibner Martin?Hofrichter 《Environmental Sciences Europe》2003,15(4):224
Degradation of organo-arsenical chemical warfare agents by fungal enzyme manganese peroxidase. The fungal enzyme manganese peroxidase was used to degrade different organo-arsenical chemical warfare agents in cell-free reaction mixtures (in vitro). The decrease in the concentration of arsenical chemical warfare agents was determined by gas chromatography after derivatization with thiols. All organo-arsenical compounds tested were converted by room temperature for more than 90%. Aliphatic arsenical compounds were attacked more rapidly than aromatic derivatives. 相似文献
12.
Katrin Palitzsch Sabine Göllner Kristina Lupa Jörg Matschullat Corinna Messal Kirsten Pleßow Mandy Schipek Ivonne Schnabel Christian Weller Frank Zimmermann 《Environmental Sciences Europe》2005,17(4):231-241
The trend of rising ozone concentrations in forest ecosystems and the phytotoxicity of ozone demand a realistic risk assessment according to an internationally accepted and flux-based quality standard. Ozone fluxes within the canopy are influenced by chemical gas-phase reactions with nitrogen oxide and biogenic hydrocarbons and by surface deposition processes. Therefore, a differentiation of the ozone flux within the canopy is needed between stomatal uptake and other transport pathways. The Eddy Covariance technique is the method of choice for the determination of trace gas fluxes relevant for ozone chemistry. This method is also used for stomatal conductance measurements based on evapotranspiration fluxes and for emission measurements of biogenic hydrocarbons by PTR-MS. Although considerably research efforts were directed to canopy measurements in recent years, the underlying processes are not fully understood yet. Thus, major differences occur in the ratios of stomatal ozone uptake, non-stomatal deposition and gas-phase chemistry between different studies. Furthermore, the vertical concentration gradients within the canopy measured at several forest sites are rather inconsistent and the existing deposition models do rarely account for chemical transformation and detoxification processes. Only a simultaneous measurement of all photochemically relevant trace gases, plant physiological parameters at different sites and forest species over entire vegetation periods, and model parameterization according to the measurement results from the experimental sites will contribute to the clarification of the canopy processes and will ensure realistic risk assessments. 相似文献
13.
Assessing the microbial activity of soil samples,its nutrient limitation and toxic effects of contaminants using a simple respiration test 总被引:4,自引:0,他引:4
Eight soil samples from five wells of a former gas plant site differing in the contamination with BTEX and PAHs as well as the nutrient content were investigated by soil respiration measurements. The basal, glucose as well as NH4+ and PO4(3-) induced cumulative oxygen consumption and carbon dioxide production in 72 and 120 h were determined and additionally the maximal turnover rates and the limitation quotients were calculated. Without additional carbon source only one of five investigated samples was clearly nutrient limited. After glucose supplementation four of seven investigated samples showed nutrient limitation that was in accordance with the available ammonium and phosphorous content. BTEX and PAHs did not exhibit an inhibiting effect on the respiration rate. In contrast, BTEX containing samples exhibited the highest oxygen consumption indicating biodegradation of the contaminants. The results show that oxygen consumption and carbon dioxide production as well as the kinetic of these processes are all informative parameters characterizing the whole microbial respiration potential and their nutrient limitation in soil samples. Therefore this fast respirometric method can be used for the decision if further detailed studies of the bioremediation are useful and if nutrient supplementation is recommended to enhance natural attenuation. 相似文献
14.
Stefan Garthe Katrin Ludynia Ommo Hüppop Ulrike Kubetzki Juan F. Meraz Robert W. Furness 《Marine Biology》2012,159(9):1907-1915
We investigated migration and wintering of adult northern gannets (Morus bassanus) breeding in east Scotland, North Sea, by deploying geolocation loggers over three winters. The wintering ranges of these birds varied from the North Sea to the Atlantic off West Africa. Flight time was taken as a proxy for migration and foraging effort. Gannets wintering off Africa had higher total flight times during migration than birds wintering further north. Total flight times in different wintering regions were generally low. Birds off West Africa consistently spent < 25 % of daylight hours in flight, but birds further north showed more variable values that may reflect more variable weather or food availability. Winter sea surface temperatures ranged from 9 °C (North Sea) to 16 °C (West Africa). Thermostatic costs in winter as estimated by measuring thermal conductance in carcasses in still air and water were 28 % higher in North Sea than off West Africa. This effect is aggravated by higher thermostatic costs caused by stronger wind chills in the North Sea compared to the conditions off West Africa. Birds wintering close to the UK arrived at the colony on average 12 days earlier than birds wintering off West Africa. We conclude that the net cost-benefit analysis may be similar for all wintering areas investigated. 相似文献
15.
Solomon D Lehmann J de Zarruk KK Dathe J Kinyangi J Liang B Machado S 《Journal of environmental quality》2011,40(3):704-718
We investigated speciation, oxidative state changes, and long- and short-term molecular-level dynamics of organic S after 365 d of aerobic incubation with and without the addition of sugarcane residue using XANES spectroscopy. Soil samples were collected from the upper 15 cm of undisturbed grasslands since 1880, from undisturbed grasslands since 1931, and from cultivated fields since 1880 in the western United States. We found three distinct groups of organosulfur compounds in these grassland-derived soils: (i) strongly reduced (S to S) organic S that encompasses thiols, monosulfides, disulfides, polysulfides, and thiophenes; (ii) organic S in intermediate oxidation (S to S) states, which include sulfoxides and sulfonates; and (iii) strongly oxidized (S) organic S, which comprises ester-SO-S. The first two groups represent S directly linked to C and accounted for 80% of the total organic S detected by XANES from the undisturbed soils. Aerobic incubation without the addition of sugarcane residue led to a 21% decline in organanosulfur compounds directly linked to C and to up to an 82% increase inorganic S directly bonded to O. Among the C-bonded S compounds, low-valence thiols, sulfides, thiophenic S, and intermediate-valence sulfoxide S seem to be highly susceptible to microbial attack and may represent the most reactive components of organic S pool in these grassland soils. Sulfonate S exhibited a much lower short-term reactivity. The incorporation of sugarcane residue resulted in an increase in organosulfur compounds directly bonded to C at the early stage of incubation. However, similar to soils incubated without residue addition, the proportion of organic S directly linked to C continued to decline with increasing duration of aerobic incubation, whereas the proportion of organic S directly bonded to O showed a steady rise. 相似文献
16.
We tested joint effects of predator loss and increased resource availability on the grazers’ trophic level and the propagation
of trophic interactions in a benthic food web by excluding larger predatory fish from cages and manipulating nutrients in
the coastal zone of the Baltic Sea. The combination of nutrient enrichment and excluding larger predators induced an increase
in medium-sized predatory fish (three-spined stickleback). The meso-predator fish in turn did not change the total abundance
of the invertebrate herbivores, but did cause a substantial shift in their community composition towards the dominance of
gastropods by reducing amphipods by 40–60%, while gastropods were left unchanged. The shift in grazer composition generated
a 23 times higher producer biomass, but only under nutrient enrichment. Our results show that top-predator declines can substantially
shift the species composition at the grazers’ level, but that cascading effects on producers by a trophic cascade strongly
depend on resource availability. 相似文献
17.
Weise Katrin Kurth Thomas Politowski Irina Winkelmann Carola Schäffer Andreas Kretschmar Susanne Berendonk Thomas Ulrich Jungmann Dirk 《Environmental science and pollution research international》2022,29(18):26706-26725
Environmental Science and Pollution Research - Although the development and application of nanomaterials is a growing industry, little data is available on the ecotoxicological effects on aquatic... 相似文献
18.
Axel Strauß Katrin Y. Solmsdorff Roger Pech Jens Jacob 《Behavioral ecology and sociobiology》2008,62(10):1551-1558
Predators can strongly influence the microhabitat use and foraging behaviour of prey. In a large-scale replicated field experiment
in East Gippsland, Australia, we tested the effects of reduced alien red fox (Vulpes vulpes) and alien wild dog (Canis lupus familiaris) abundance (treatment) on native bush rat (Rattus fuscipes) behaviour. Bush rats are exposed to two main guilds of predators, namely mammalian carnivores and birds of prey. Tracking
rat movements using the spool-and-line technique revealed that, in treatment sites, rats used ground cover, which provides
shelter from predators, less often than at unmanipulated fox and wild dog abundance (non-treatment sites). In treatment sites,
rats more frequently moved on logs where they would have been exposed to hunting foxes and dogs than in non-treatment sites.
Furthermore, in treatments, rats showed a preference for understorey but not in non-treatments. Hence, bush rats adapted their
behaviour to removal of alien terrestrial predators. Giving-up densities (GUDs) indicated no treatment effects on the marginal
feeding rate of bush rats. Interestingly, GUDs were higher in open patches than in sheltered patches, suggesting higher perceived
predation risk of bush rats during foraging at low versus high cover. The lack of treatment effects on GUDs but the clear
response of bush rats to cover may be explained by the impact of predators other than foxes and wild dogs. 相似文献
19.
Wood samples impregnated with inorganic wood preservatives containing the elements arsenic, boron, chromium, copper, fluorine, and/or zinc were burned in a furnace. Three different kinds of ash were collected: furnace, boiler, and so-called fly ash. Analyses showed that the ash contained large amounts of elements originating from the inorganic wood preservatives. Further interest was focused on the leachability of the above-mentioned elements. For this purpose a laboratory batch leaching test according to the German Standard DIN 38 414 part 4 was chosen. The results indicate that the leachability is in a range where the release of these elements to the environment from deposited ash can be considered as detrimental. 相似文献
20.
Trends of perfluorochemicals in Greenland ringed seals and polar bears: Indications of shifts to decreasing trends 总被引:1,自引:0,他引:1
Time-series of perfluorinated alkylated substances (PFASs) in East Greenland polar bears and East and West Greenland ringed seals were updated in order to deduce whether a response to the major reduction in perfluoroalkyl production in the early 2000s had occurred. Previous studies had documented an exponential increase of perfluorooctane sulphonate (PFOS) in liver tissue from both species. In the present study, PFOS was still the far most dominant compound constituting 92% (West Greenland ringed seals), 88% (East Greenland ringed seals) and 85% (East Greenland polar bears). The PFOS concentrations increased up to 2006 with doubling times of approximately 6 years for the ringed seal populations and 14 years in case of polar bears. Since then a rapid decrease has occurred with clearing half-lives of approximately 1, 2 and 4 years, respectively. In polar bears perfluorohexane sulphonate (PFHxS) and perfluorooctane sulphonamide (PFOSA) also showed decreasing trends in recent years as do perfluorodecanoic acid (PFDA) and perfluoroundecanoic acid (PFUnA). For the West Greenland ringed seal population perfluorooctanoic acid (PFOA), perfluorononanoic acid (PFNA), PFDA and PFUnA peaked in the mid 2000s, whereas PFNA, PFDA and PFUnA in the East Greenland population have been stable or increasing in recent years. The peak of PFASs in Greenland ringed seals and polar bears occurred at a later time than in Canadian seals and polar bears and considerably later than observed in seal species from more southern latitudes. We suggest that this could be explained by the distance to emission hot-spots and differences in long-range transport to the Arctic. 相似文献