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981.
We report measurements of solubility limits for benzene, toluene, and TCE in systems that contain varying levels of biomass up to 0.13 g mL−1 for TCE and 0.25 g mL−1 for benzene and toluene. The solubility limit increased from 21 to 48 mM when biomass (in the form of yeast) was added to aqueous batch systems containing benzene. The toluene solubility limit increased from 4.9 to greater than 20 mM. For TCE, the solubility increased from 8 mM to more than 1000 mM. Solubility for TCE (trichloroethylene) was most heavily impacted by biomass levels, changing by two orders of magnitude as the microbial concentrations approach those in biofilms. 相似文献
982.
983.
Aishah S. A. K. Sharifah Hanafiah Zainal Abidin Mohamad R. Sulaiman Kheng H. Khoo Hairi Ali 《Journal of Material Cycles and Waste Management》2008,10(2):116-123
Malaysia is in dire need of alternatives to landfilling for solid waste management. Recently, landfills have faced the problems
of overfilling, overflowing of leachates leading to pollution of water resources, and uncontrolled dust emissions adversely
affecting the local environment. With the rising cost of urbanization coupled with the high rate of waste generation, one
possible method of waste treatment that is receiving particular attention by the government is incineration. Incineration
of solid waste is rather new in Malaysia, with limited usage in handling small sources of waste generation such as the municipal
solid waste (MSW) of resort islands; however, its potential in ameliorating the problems associated with solid waste treatment
may make it an attractive alternative to landfill. This article presents the results of test runs conducted to investigate
the performance of a locally designed and manufactured rotary kiln incinerator (RKI). The test runs were conducted using MSW
collected from the Shah Alam municipality. The combustion efficiency was analyzed by looking at the temperature profiles and
chemical species concentrations. To complement the combustion characteristics measurements, predictions of the air flow in
the incinerator during the process were also investigated. The overall performance of the RKI suggests that it is suitable
for treating MSW. 相似文献
984.
Markéta Julinová Marie Dvořáčková Jan Kupec Jitka Hubáčková Martina Kopčilová Jaromír Hoffmann Pavol Alexy Anna Nahálková Ida Vašková 《Journal of Polymers and the Environment》2008,16(4):241-249
Improving biodegradability of PVA/starch blends is a reality already documented by a number of works. Admittedly, mechanical
properties of products (for example, tensile strength) are somewhat worse, but suitable composition optimizing or chemical
modifying of starch may eliminate the problem to a large degree. This work is an attempt to find another potential effect
influencing biodegradability, that of technological procedure for producing films from these blends on an extruder. The procedure
with a so-called pre-extrusion step (two-stage) and dry-blend (single-stage) produced blends of slightest differences in achieved
biodegradability (virtually within limits of experimental error) in aerobic (76 vs. 79%) as well as anaerobic breakdown (48
vs. 52%). Conversely, morphological analysis exhibited superior homogeneity of films prepared by the two-stage process; their
tensile strength was also higher. 相似文献
985.
986.
Sławomir Stelmach Ryszard Wasielewski 《Journal of Material Cycles and Waste Management》2008,10(2):110-115
More than 1.1 million tons of municipal and industrial sewage sludge is produced annually in Poland. Most of this sewage sludge
is landfilled or used for recultivation and fertilization of soil. After accession of Poland to the EU, large investments
are planned for wastewater treatment, so it is expected that the amount of sewage sludge produced in Poland will grow in the
near future. It is well known that the combustion of sewage sludge is becoming a more and more popular utilization method
of such waste. Unfortunately, the current situation in Poland makes it impossible to incinerate the sewage sludge because
of a lack of incinerators. One possible solution for Poland is the co-firing of dried sewage sludge in existing coal-fired
utility boilers. This article presents results of initial Polish industrial trials of dried municipal sewage sludge and hard
coal co-combustion in an OP-230 pulverized coal boiler. Such a solution was shown to be technically viable and not to require
changes to the existing technological system. Cocombustion of sewage sludge with coal in power plants seems to be the best
solution for sludge utilization in the near future in Poland. 相似文献
987.
Jörg Luster Manoj Menon Sandra Hermle Rainer Schulin Madeleine S. Günthardt-Goerg Bernd Nowack 《Water, Air, & Soil Pollution: Focus》2008,8(2):163-176
Soil translocation for recultivation of soil removed from construction sites and for the preparation of refilled lysimeters
inevitably involves disturbance of soil structure, and, if intermediate storage is included, also drying and rewetting of
the soil. We report on an experiment with model forest ecosystems, where uncontaminated forest subsoils were covered with
non-contaminated or freshly heavy metal (mainly Zn and Cu) contaminated topsoil in large lysimeters. Monitoring of the chemical
composition of the drainage water revealed two distinct soil conditioning phases. During an initial phase of about a year
strongly elevated nitrate and sulfate concentrations occurred that were attributed to a mineralisation flush caused by the
increased accessability of mineralisable nitrogen and sulfur in destroyed aggregates. These effects were significantly larger
in lysimeters with calcareous subsoil than in those with acidic subsoil. The second phase was characterised by a gradual decrease
in dissolved organic carbon and sulfate concentrations, in particular in the acidic subsoil. This decrease may be attributed
to the depletion of pools made accessible during aggregate destruction or the formation of new aggregates. These chemical
changes had only little effects on the concentrations of copper and zinc in the drainage water. Based on our results, it can
be concluded that large refilled lysimeters can be used for many purposes without risk of compromised results, if a conditioning
phase of about 1 year with sufficiently moist soil conditions is respected. Nevertheless, gradual changes in soil chemical
characteristics still occur after this initial phase. Implications for the recultivation of sites using relocated soils are
discussed. 相似文献
988.
989.
K. Pritsch D. Ernst F. Fleischmann S. Gayler T. E. E. Grams A. Göttlein W. Heller N. Koch H. Lang R. Matyssek J. C. Munch M. Olbrich H. Scherb S. Stich J. B. Winkler M. Schloter 《Water, Air, & Soil Pollution: Focus》2008,8(2):139-154
A lysimeter study was performed to monitor effects of elevated ozone on juvenile trees of Fagus sylvatica L. as well as on the plant–soil system. During a fumigation period over almost three growing seasons, parameters related
to plant growth, phenological development and physiology as well as soil functions were studied. The data analyses identified
elevated ozone to delay leaf phenology at early and to accelerate it at late developmental stages, to reduce growth, some
leaf nutrients (Ca, K) as well as some soluble phenolics (hydroxycinnamic acid derivatives, total flavonol glycosides). No
or very weak ozone effects were found in mobile carbon pools of leaves (starch, sucrose), and other phenolic compounds (flavans).
Altered gene expression related to stress and carbon cycling corresponded well with findings from leaf phenology and chemical
composition analyses indicating earlier senescence and oxidative stress in leaves under elevated ozone. Conversely in the
soil system, no effects of ozone were detected on soil enzyme activities, rates of litter degradation and lysimeter water
balances. Despite the fact that the three reported years 2003–2005 were climatically very contrasting including a hot and
dry as well as an extremely wet summer, and also mild as well as cold winters, the influence of ozone on a number of plant
parameters is remarkably consistent, further underlining the phytotoxic potential of elevated tropospheric ozone levels. 相似文献
990.
Martin Braniš 《Water, Air, & Soil Pollution: Focus》2008,8(1):49-60
To assess the effect of changes in traffic density and fuels used for heating at the beginning of the 1990s, 1992–2005 monthly
averages of PM10, SO2, NO2, NO, CO and O3 from Prague, the Czech capital, were analyzed together with long term trends in emissions of major pollutants, fuel consumption
and number of vehicles registered in Prague. The data from all monitoring stations were retrieved from the database of the
state automated monitoring system. Correlation coefficients between ambient monthly averaged temperature and all pollutants
of concern showed distinct seasonal trends. The results showed that while SO2 and to some extent also CO concentrations dropped namely in the first half of the analyzed period (1992–1997) as a result
decreased fossil fuel consumption for local heating, the behaviour of other pollutant concentrations followed a different
pattern. PM10 concentrations decreased during the beginning of the 1990s but showed a sign of increase after 2000. Concentrations of ozone
and NO2 did not reveal any significant change throughout the whole studied period. It can be concluded that during the studied period
traditional urban sources of pollution, such as coal and oil combustion, lost their importance but were simultaneously substituted
by pollutants from automotive transport (namely PM and NO2) making the problem of air quality even worse. 相似文献