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961.
Tobias Mette Axel Albrecht Christian Ammer Peter Biber Ulrich Kohnle Hans Pretzsch 《Ecological modelling》2009,220(13-14):1670-1680
Forest growth simulators go beyond a mere tabulation of empirical measurements by employing biometric models that functionally describe the dependence of forest growth of the initial forest structure, growth conditions and management regime. This makes them very flexible and allows predicting growth reactions for unknown and/or complex forest growth scenarios. When simulation outcomes are to be used in silvicultural strategic planning, the results are of direct and delicate importance, and the correct simulator performance must be ascertained. This is especially so when the considered forest situation differs from the forest data used to parameterise the model (e.g. different geographical region).In this article, the forest growth simulator SILVA (version 2.2) was validated for 55 long-term experimental plots of mature mixed Silver fir–Norway spruce stands in southwest Germany (Picea abies, Abies alba). The evaluation was restricted to the upper canopy trees during the survey period 1989–2004. Following the general evaluation criteria for ecological models from [Vanclay, J.K., Skovsgaard, J.P., 1997. Evaluating forest growth models. Ecol. Mod. 98, 1–12], a specific methodology was developed to evaluate the simulated height and diameter growth on the basis of forest growth principles.The qualitative analysis proved the SILVA growth algorithms to be in accordance with physiologically based standard growth equations. The quantitative evaluation was limited by incomplete knowledge of the site conditions. To overcome this problem, the experimental plots were regarded as a “heterogeneous growth series” which allows analysing the growth behaviour in a more general way. It could be shown that for the given data set, the SILVA simulations produced an overestimation of height growth (median: +61% spruce, +12% fir), and an underestimation of diameter growth and competition sensitivity (median: ?16% spruce, ?70% fir). The errors partially compensated in the volume growth resulting in an overall over-/underestimation of +9% for spruce and ?58% for fir (median).The unbalanced height and diameter growth cannot be compensated by a change in the site conditions because this affects both height and diameter growth either positive or negative. Hence, an adjustment of selected parameterisation values appears to offer the best solution to adapt SILVA to the considered forest situation. This approach of adaptive parameterisation is discussed against a more general background of deductive vs. inductive forest growth modelling. 相似文献
962.
This paper describes the development of methods for selective extraction of polychlorinated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs) from soils and sediments, using pressurized liquid extraction with in-cell clean-up (SPLE). Two binary solvent mixtures, viz. dichloromethane/n-heptane (DCM/Hp), and diethylether/n-heptane (DEE/Hp), were evaluated. The SPLE extraction conditions were optimized using central composite face (CCF) design. Three factors were investigated: extraction temperature (60–160 °C), number of extraction cycles (1–3) and time per cycle (2–18 min). The results showed that DCM/Hp (1/1, v/v) and DEE/Hp (1/2, v/v) were the best extraction solvent compositions and that the extraction temperature was a critical factor that needed careful optimization to achieve high extraction efficiency without co-extraction of sulfuric acid. Under the optimal conditions, the SPLE methods provided results with good accuracy and precision. For the sandy soil certified reference material (CRM-529) the quantification results ended up in the range 82–110% as compared to the concentrations obtained by a reference method based on Soxhlet extraction and external column clean-up. Furthermore, for a clay soil (CRM-530) and a sediment reference material (WMS-01), the accuracy (trueness) of the TEQ values were +11% (DCM/Hp) and +8% (DEE/Hp) for CRM-530, +8% and ?7% for WMS-01, respectively. The individual congener concentrations also agreed well with the certified values. These findings show that SPLE is a promising method for combined extraction and clean-up of PCDD/Fs in soil/sediment samples. 相似文献
963.
Hartmut Koehler Jürgen Warrelmann Peter Behrend Ingo Dobner Tobias Frische Wolfgang Heyser Bernd Jastorff Ulrich Walter 《Environmental Sciences Europe》2001,13(6):359-368
The final article of a series of three evaluates the in situ-remediation of TNT(trinitrotoluene)-contaminated soil from ‘Werk Tanne’. The multidisciplinary approach allows a differentiated assessment. Grading with large-scale machinery leads to a depletion of TNT for almost 90% within the first 6 months, while ADNT(amino-dinitrotoluene)-content decreases more or less steadily over 1,5 years. Grading reduces the heterogenous distribution of the contamination only slightly. Results from field-monitoring and biotest-battery indicate residual toxicities of ecotoxicological relevance and a reduced capacity for biological regeneration, in comparison with the uncontamined site. Mycorrhized plants safe-guard the site and improve the soilecological conditions. Their role in reducing lower level residual toxicity requires further investigation. There is need for future research (1) on the dynamics and mechanisms of the initial decrease of TNT followed by stagnation, (2) on the fate of the primary metabolites, (3) on long-term effects of the phytoremediation, and (4) on the establishment of the complex monitoring for routine work. 相似文献
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Long-term monitoring data show that hard coral cover on the Great Barrier Reef (GBR) has reduced by >70 % over the past century. Although authorities and many marine scientists were in denial for many years, it is now widely accepted that this reduction is largely attributable to the chronic state of eutrophication that exists throughout most of the GBR. Some reefs in the far northern GBR where the annual mean chlorophyll a (Chl a) is in the lower range of the proposed Eutrophication Threshold Concentration for Chl a (~0.2–0.3 mg m−3) show little or no evidence of degradation over the past century. However, the available evidence suggests that coral diseases and the crown-of-thorns starfish will proliferate in such waters and hence the mandated eutrophication Trigger values for Chl a (~0.4–0.45 mg m−3) will need to be decreased to ~0.2 mg m−3 for sustaining coral reef communities. 相似文献
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