Organic chloramines in chlorine-based disinfected watersystems: A critical review

This paper is a critical review of current knowledge of organic chloramines in water systems,including their formation, stability, toxicity, analyticalmethods for detection, and their impact on drinking water treatment and quality. The term organic chloramines may refer to any halogenated organic compounds measured as part of combined chlorine (the difference between themeasured free and total chlorine concentrations), andmay include N-chloramines, N-chloramino acids, N-chloraldimines and N-chloramides. Organic chloramines can form when dissolved organic nitrogen or dissolved organic carbon react with either free chlorine or inorganic chloramines. They are potentially harmful to humans and may exist as an intermediate for other disinfection by-products. However, little information is available on the formation or occurrence of organic chloramines in water due to a number of challenges. One of the biggest challenges for the identification and quantification of organic chloramines in water systems is the lack of appropriate analytical methods. In addition, many of the organic chloramines that formduring disinfection are unstable,which results in difficulties in sampling and detection. To date research has focussed on the study of organic monochloramines. However, given that breakpoint chlorination is commonly undertaken in water treatment systems, the formation of organic dichloramines should also be considered. Organic chloramines can be formed frommany different precursors and pathways. Therefore, studying the occurrence of their precursors in water systems would enable better prediction and management of their formation.     

Reduction of pharmaceutically active compounds by a lagoon wetland wastewater treatment system in Southeast Louisiana

A number of pharmaceutically active compounds (PhACs) have been detected in the aquatic environment as a result of discharges of municipal wastewater. In the state of Louisiana, USA, many municipalities treat wastewater using natural systems, such as lagoons and wetlands, rather than conventional wastewater treatment technologies. Nearly all research to date has focused on the fate of PhACs in conventional treatment plants, not constructed and natural wetlands. In the wastewater treatment plant (WWTP) for Mandeville, Louisiana, USA, wastewater flows of 7600 m³ d⁻¹ are treated in a series of aeration lagoons (basins), followed by a constructed wetland and UV disinfection, before being discharged into a natural forested wetland (i.e. Bayou Chinchuba) and eventually, Lake Pontchartrain. Thirteen out of the 15 PhACs investigated were detected in the wastewater inflow to the treatment plant. Only 9 of the 13 compounds were above the detection limits at the treatment plant effluent. The concentrations of most compounds were reduced by greater than 90% within the plant, while carbamazepine and sotalol were only reduced by 51% and 82%, respectively. The percent reductions observed in the Mandeville system were greater than reduction rates reported for conventional WWTPs; perhaps due to the longer treatment time (30 days). Most target PhACs were not completely removed before discharge into Lake Pontchartrain, although their collective annual loading was reduced to less than 1 kg and down to ppb with significant potential for dilution in the large lake.     

Characteristics and source attribution of PM2.5 during 2016 G20 Summit in Hangzhou: Efficacy of radical measures to reduce source emissions

A field campaign was conducted to study the PM_2.5 and atmospheric gases and aerosol's components to evaluate the efficacy of radical measures implemented by the Chinese government to improve air quality during the 2016 G20 Summit in Hangzhou China. The lower level of PM_2.5 (32.48 ± 11.03 µg/m³) observed during the control period compared to pre-control and post-control periods showed that PM_2.5 was alleviated by control policies. Based on the mass concentrations of particulate components, the emissions of PM_2.5 from local sources including fossil fuel, coal combustion, industry and construction were effectively reduced, but non-exhaust emission was not reduced as effectively as expected. The accumulation of SNA (SO₄^2?, NO₃^?, NH₄⁺) was observed during the control period, due to the favourable synoptic weather conditions for photochemical reactions and heterogeneous hydrolysis. Because of transboundary transport during the control period, air masses from remote areas contributed significantly to local PM_2.5. Although, secondary organic carbon (OC_sec) exhibited more sensitivity than primary organic carbon (OC_pri) to control measures, and the increased nitrogen oxidation ratio (NOR) implied the regional transport of aged secondary aerosols to the study area. Overall, the results from various approaches revealed that local pollution sources were kept under control, indicating that the implementation of mitigation measures were helpful in improving the air quality of Hangzhou during G20 summit. To reduce ambient levels of PM_2.5 further in Hangzhou, regional control policies may have to be taken so as to reduce the impact of long-range transport of air masses from inland China.     

Enabling Sustainable Agro-Food Futures: Exploring Fault Lines and Synergies Between the Integrated Territorial Paradigm,Rural Eco-Economy and Circular Economy

What kind of futures does agro-food imaginaries enable and who can get involved in the making of agro-food futures? In this respect, what can the increasingly influential idea of circular economy potentially offer in terms of enabling more sustainable agrofood futures? We approach this task by first outlining the interconnected challenges that the agro-food system is facing related to environmental degradation, economic crises and social problems. Then we consider the way these challenges are being addressed in agro-food studies. We argue that agro-food research in recent years has seen important contributions in relation to studies of alternative food networks and the “quality” turn. These research agendas have challenged the current logic of the food system in terms of offering alternative visions of future development. We highlight two examples from the literature—the eco-economy and the integrated territorial agri-food paradigm—that develop broader frameworks for rethinking the future of the agro-food system and which have distinguished themselves in contrast to the industrialized and globalized conventional food system. We find that with respect to reorienting and reconfiguring economic structures and relations all three approaches share a common goal, but circular economy stands out in relation to the actors that are included by, for example, emphasizing collaborations and partnerships with extant agro-food businesses. Also with regards to scalar politics, it would be prudent to consider the potentials offered by the increasingly influential ideas around circular economy.