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361.
The European Water Framework Directive (WFD) requires the definition of reference conditions, i.e. pristine conditions, for all surface waters. As the present state of Danish coastal waters cannot be referred to as pristine, reference conditions have to be assessed by analysis of historical data or by the use of models. Using Randers Fjord as an example, the aim of this work was i) to demonstrate possibilities and restrictions of assessing reference conditions by historical data and by modelling; and ii) to demonstrate how ecological conditions have changed along with eutrophication. The ample historical data from Randers Fjord allowed us to assess reference conditions with respect to benthic macrophytes and benthic fauna. Models of varying complexity enabled us to assess reference conditions for nutrients, chlorophyll a, Secchi depth, and eelgrass. We conclude that models can be a useful supplement to assess reference conditions, though they are presently restricted by the lack of quantitative links between eutrophication and species composition. 相似文献
362.
Der VII. Internationale Kongre? für ?kologie ergab die M?glichkeit, auch einige Spezialisten aus der ?kologischen Spurenelementforschung in Florenz zusammenzubringen. Dabei zeigte sich deutlich, da? noch wesentliche Arbeit auf dem Weg zu einem generellen Verst?ndnis der Wirkung einzelner Elemente und ihrer Spezies vor uns liegt. Obwohl auf analytischem Sektor beachtliche Durchbrüche durch die Entwicklung leistungsf?higer Methoden bewerkstelligt wurden, bleiben noch wichtige Fragen zur essentiellen und/oder toxikologischen Wirkung einzelner Spurenelemente zu beantworten. Hieraus lassen sich aus den Beitr?gen der Teilnehmer des Symposiums folgende Forderungen ableiten:
相似文献
1. | Es ist nicht einzusehen, da? sich die aktuelle Spurenelementforschung im wesentlichen auf nur 1/3 der chemischen Elemente des chemischen Systems der Elemente beschr?nkt. Mit gleicher Intensit?t wie Cadmium, Quecksilber und Arsen sollten auch Elemente wie beispielsweise Lanthan, Platin und Antimon in spurenanalytische Fragestellungen vermehrt einbezogen werden. Die analytischen Techniken hierfür stehen weitgehend zur Verfügung. |
2. | Der Totalgehalt an Elementen ist ein erster Hinweis auf Vorkommen und Verteilung einzelner Spurenelemente in der Umwelt, bietet aber h?ufig nicht die M?glichkeit, etwas über deren Wirkung auszusagen. Hierzu ist es notwendig, die “Speciation”, das hei?t, die Bindungsform des jeweiligen Elementes in der zu untersuchenden Umweltprobe n?her zu ermitteln, um daraus m?gliche Effekte und Wirkungen auf Organismen und Organismengemeinschaften abzuleiten. |
3. | Die Qualit?t der analytischen Daten, die bei derartigen Untersuchungen gewonnen werden, sind einer strengen Qualit?tskontrolle durch Einsatz und Entwicklung weiterer Referenzmaterialien, Ringanalysen und anderer Steuerungsmechanismen zu gew?hrleisten. |
4. | Die überw?ltigende Datenmenge, die in den letzten 30 Jahren in der Spurenelementforschung zusammengetragen wurde, entbehrt derzeit jeglicher generalisierender Auswertung. Es wird daher vorgeschlagen die Daten, soweit sie analytisch brauchbar sind, aus den letzten 20 bis 30 Jahren in Form einer Datenbank zusammenzutragen und hieraus m?gliche Zusammenh?nge und notwendige Schlu?folgerungen für weitere Untersuchungen abzuleiten. |
5. | Die Bioindikation bzw. das Biomonitoring sollte verst?rkt betrieben werden, da M?glichkeiten einer fl?chendeckenden, zeitaufl?senden Untersuchung einzelner Effekte spezifischer Spurenelemente er?ffnet werden. Die sich hieraus ergebenden Folgerungen für m?gliche Sanierungs-oder prophylaktische Ma?nahmen ergaben sich nicht nur aus Forderungen in diesem Symposium, sondern auch auf weiteren Symposien des gesamten INTECOL-Kongresses. |
363.
Boron is an essential nutrient for plants and the potential exists for efficient removal of this element by wetland treatment systems due to accumulation by plants. To evaluate the efficacy of using Spirodella polyrrhiza to treat boron-contaminated wastewater or to be a suitable species for removing other nutrients from boron-containing wastewater the toxicity of this micronutrient was determined using standard methods. Frond production is apparently a more sensitive endpoint than either growth rate or the presence of abnormal fronds. Frond production in S. polyrrhiza was significantly reduced at 3.55 mg B/l. Significant reductions in growth rate and the percentage of abnormal (chlorotic, necrotic, and dead) fronds were observed at 18.9 and 22.4 mg B/l, respectively. The EC50 for frond production, frond growth rate, and abnormal fronds were 14.3, 11.7, and 17.7 mg B/l, respectively. S. polyrrhiza did not remove significant amounts of boron from the treatment solutions under the conditions and concentrations existing in this study. The inability of S. polyrrhiza to remove even small amounts of boron from the test solutions indicates this species is not suitable for treating boron-containing wastewater, even those with low boron concentrations. 相似文献
364.
Mercury baseline levels in Flemish soils (Belgium) 总被引:4,自引:0,他引:4
Tack FM Vanhaesebroeck T Verloo MG Van Rompaey K Van Ranst E 《Environmental pollution (Barking, Essex : 1987)》2005,134(1):173-179
It is important to establish contaminant levels that are normally present in soils to provide baseline data for pollution studies. Mercury is a toxic element of concern. This study was aimed at assessing baseline mercury levels in soils in Flanders. In a previous study, mercury contents in soils in Oost-Vlaanderen were found to be significantly above levels reported elsewhere. For the current study, observations were extended over two more provinces, West-Vlaanderen and Antwerpen. Ranges of soil Hg contents were distinctly higher in the province Oost-Vlaanderen (interquartile range from 0.09 to 0.43 mg/kg) than in the other provinces (interquartile ranges from 0.7 to 0.13 and 0.7 to 0.15 mg/kg for West-Vlaanderen and Antwerpen, respectively). The standard threshold method was applied to separate soils containing baseline levels of Hg from the data. Baseline concentrations for Hg were characterised by a median of 0.10mg Hg/kg dry soil, an interquartile range from 0.07 to 0.14 mg/kg and a 90% percentile value of 0.30 mg/kg. The influence of soil properties such as clay and organic carbon contents, and pH on baseline Hg concentrations was not important. Maps of the spatial distribution of Hg levels showed that the province Oost-Vlaanderen exhibited zones with systematically higher Hg soil contents. This may be related to the former presence of many small-scale industries employing mercury in that region. 相似文献
365.
Gönüllü MT Avşar Y Bayhan H Sakar S Arslankaya E Apaydin O Kurt U 《Environmental monitoring and assessment》2005,109(1-3):57-64
The shores of the Golden Horn—once most important seaport of the region—represented throughout history a romantic and recreational
venue. This tributary to the Bosphorus, however, became seriously polluted with the extensive industrialization and rapid
population growth in Istanbul over the past century. Two main tributaries, the Alibeykoy and the Kagithane, dumped both liquid
and solid waste from residential areas and industry (small and large-scale) into the Golden Horn. As a result of this pollution,
the landward three to four kilometers of the estuary became swamped with sediment. The dominance of anaerobic activity resulted
in a highly unpleasant smell, and the shallow depth as one progressed up the bay restricted navigation. In early 1997 The
Istanbul Metropolitan Municipality began a dredging operation and gradually diverted all domestic and industrial wastewater
discharge from the Golden Horn. Since then there have been remarkable improvements in water quality.
This paper presents the state of eutrophication through the water body of the Golden Horn; parameters such as DO, TKN, NH3-N, NO3-N, the total phosphorus (TP) and dissolved phosphorus (PO4-P), phytoplankton and chlorophyll-a have been were analyzed in samples of water taken from various points in the Golden Horn. The presence of DO and the phytoplankton,
both indicators of primary productivity in an aquatic body, has been evaluated in relation to former conditions. 相似文献
366.
In the spring of 1989, an experimental study of the spawning behaviour of Calanus finmarchicus was carried out in Malangen, northern Norway. Here, a single cohort of females reproduce from mid-March to May, approximately coinciding with the wax and wane of the spring phytoplankton bloom. An evaluation of population characteristics such as the proportion of adults, sex ratio, as well as gonad maturation and daily productivity of the females clearly reveals three phases within the population's reproductive period. In between incline and decline, the highest spawning rates (on average >20 eggs female-1 d-1, equivalent to 5.7% body C d-1) occur after the males have disappeared from the population and almost all females have mature gonads. During this period, the ratio of adults to copepodid Stage Vs changes from dominance of adults to that of CVs. Although first egg production was observed prior to the phytoplankton increase, it is suggested that the onset of the phytoplankton spring bloom in the first few days of April enhances the final maturation of ovaries in the females and therefore triggers the onset of the main spawning period. The clutch sizes (max. 95 eggs clutch-1) vary with the age of the females, while the spawning frequencies depend on the available food quantities. The overlap of an estimated minimal 4 wk spawning period for the individuals leads to a main reproductive phase for the population of ca. 3 wk, during which time mean clutch sizes and spawning frequencies are maximal (highest average clutch size: 70 eggs female-1 clutch-1, 100 to 60% of the females spawning). This period ends before the end of the phytoplankton bloom. Calculated by stepwise interpolation and summation of the mean daily egg production in the population, an average female produced ca. 600 eggs during the spring bloom in Malangen 1989. We suggest that reproduction and population development of C. finmarchicus in spring follows a reproducible pattern for a given temperature regime and non-limiting food conditions. In the case of clearly identifiable cohorts, it seems possible to trace the state of reproduction by evaluating population parameters. 相似文献
367.
368.
369.
A personal air sampling method using Amberlite XAD-2 coated with 2,4-dinitrophenylhydrazine has been developed for acrolein and glutaral dehyde. Acrolein in the 0.01 to 1.2 mg/m3 range or glutaraldehyde in the 0.03 to 3.5 mg/m3 range is easily analysed in a 5 1 air sample. Recoveries are high (80–100%), and samples stable at least for two weeks if stored in the dark until analysed. 相似文献
370.
Synthetic routes for the preparation of halogenated diphenyl ethers and dibenzofurans are reviewed, and isomers reported in the literature are listed. In addition, the routes preferred for the synthesis of specific chlorinated isomers - especially from the point of view of an unambiguous structural assignment - are discussed in detail. The route recommended for chlorinated diphenyl ethers is the coupling of biaryliodonium salts with phenols, and for chlorinated dibenzofurans the palladium acetate-promoted cyclization of diphenyl ethers. Chlorinated isomers of diphenyl ethers and dibenzofurans which are available via these routes are listed. Furthermore, the synthesis of a new octachlorodiphenyliodonium salt and its coupling with three different chlorophenols are described, and the cyclization of an octachlorodiphenyl ether to octachlorodibenzofuran is shown. 相似文献