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171.
172.
Nonylphenols were determined from the water, suspended particle, and sediment samples taken from the Lake Shihwa in Korea and its surrounding creeks flowing through municipal and industrial areas, and into the lake. The nonylphenols were detected at the concentration ranges of 0.0-41.3 microg/l, 0.0-116.6 and 0.3-31.7 mg/kg in water, suspended particle and sediment samples respectively. The contamination levels of nonylphenols were increased along the down stream. Considerably high levels of nonylphenols were found at the industrial area compared to the municipal area. No remarkable differences were found between the isomer patterns of nonylphenols for the sample matrices of each sampling site, i.e. water, suspended solids and sediment. Strong correlations between water and sediment with 10(5.2) of the mean partition coefficient (Koc ) were observed. These indicate that most of nonylphenols came from industrial wastewater at high level. It is thought that the water quality of the Lake Shihwa is affected greatly by industrial environments surrounding. 相似文献
173.
In this study, a new empirical equation for the transverse dispersion coefficient has been developed based on the hydraulic
and geometric parameters in natural streams using a regression technique. First, a total of 32 data sets in 16 streams were
collected. Among those sets, 16 sets were used for deriving the new equation, and the other 16 sets were used for verifying
the equation. Then, through dimensional analysis, it was found that the normalized transverse dispersion coefficient is associated
with several parameters such as sinuosity, aspect ratio, and a friction term. The robust least square method was applied to
estimate regression coefficients. The newly proposed equation was proven to be superior in explaining the dispersion characteristics
of natural streams more precisely compared to the existing equations. 相似文献
174.
Robert Wallerstein Tracey Oh Judy Durcan Yaakov Abdelhak Mark Clachko Hana Aviv 《黑龙江环境通报》2002,22(8):722-724
We report the prenatal diagnosis of trisomy 6 mosaicism via amniocentesis, in which trisomy 6 cells were identified in three of five culture vessels with 33% (5/15) of colonies showing trisomic cells. The pregnancy was electively terminated and examination revealed minor abnormalities (shortening of the femurs, micrognathia, posterior malrotation of the ears, and bilateral camptomelia of the second digit of the hands and fifth digits of the feet). Cytogenetic analysis of the placenta showed trisomy 6 in 100% of 20 cells studied. Karyotype was 46,XX in 100 cells examined from fetal skin. There are relatively few prenatally diagnosed cases of mosaic trisomy 6 at amniocentesis. Confined placental mosaicism (CPM) has been postulated in other cases where follow-up cytogenetic studies were not available. The present case differs from those previously reported, as it appears to represent CPM of chromosome 6 with phenotypic effects to the fetus. Copyright © 2002 John Wiley & Sons, Ltd. 相似文献
175.
Gunung Oh Seo Yoon Park Myung Won Seo Ho Won Ra Tae Young Mun Jae-Goo Lee 《International Journal of Green Energy》2019,16(4):333-349
Cracking, steam reforming, dry reforming, and combined steam and dry reforming of toluene in model syngas were performed using catalysts to simulate tar removal produced during biomass gasification. The catalysts were prepared by adding Ru, Ca, and Mn to Ni-based catalysts, and their properties were measured using BET, pulse CO chemisorption, XRD and TG. In steam and dry reforming of toluene, a high toluene conversion was observed with increasing Ca content in the catalyst and catalysts containing Ca showed a higher activity than those containing Mn. In combined steam-dry reforming with syngas, 1%CaNiRu/Al2O3 indicated a conversion of 93.9% at 800°C. 相似文献
176.
177.
Yong-Sang Choi Chang-Hoi Ho Hye-Ryun Oh Rokjin J. Park Chang-Geun Song 《Atmospheric environment (Oxford, England : 1994)》2009,43(35):5654-5660
Over the western North Pacific, a large amount of land aerosols from Asian-Pacific countries is transported by the prevailing westerlies. This transport makes the radiative characteristics of these aerosols diverse, particularly when one compares those characteristics over the coastal sea with those over the open sea. In this paper we discuss a method that uses satellite data to obtain the single-scattering albedo (ω) and asymmetry factor (g) of atmospheric aerosols for two large-scale subdivisions—the coastal sea (within 250 km from the coast) and the open sea (the remaining area)—over the western North Pacific (110°E–180°, 20°N–50°N). Our estimation method uses satellite measurements, obtained over a six-year period (2000–2005), of aerosol optical depth (AOD) and shortwave fluxes at both the surface and the top of the atmosphere (TOA); the measurements are obtained using the Moderate Resolution Imaging Spectroradiometer (MODIS) and the Clouds and the Earth's Radiant Energy System (CERES). For the two subdivisions, the estimated annual means of (ω,g) at 630 nm are significantly different: (0.94, 0.65) over the coastal sea and (0.97, 0.70) over the open sea. From a quantitative viewpoint, this result indicates that in comparison with aerosols over the open sea, those over the coastal sea show greater absorption and lesser forward scattering of solar radiation. The estimated optical properties are responsible for the aerosol surface cooling observed by MODIS and CERES, which is approximately 138 and 108 W m−2 per AOD over the coastal sea and open sea, respectively. 相似文献
178.
Tara Sankar Pathak Jung-Ho Yun Se-Jong Lee Dae-Jin Baek Ki-Jung Paeng 《Journal of Polymers and the Environment》2010,18(1):45-56
Alginates, extracted from algae are linear unbranched polymers containing β-(1→4)-linked d-mannuronic acid (M) and α-(1→4)-linked l-guluronic acid (G) residues. The conversion of alginic acid into the metal alginate is confirmed using FTIR spectroscopy.
Asymmetric and symmetric stretching of free carboxyl group present in metal alginate occurs almost at the same position in
various solvent compositions. Total intrusion volume of metal alginate prepared in propanol (0.0742 mL/g) is greater compared
to those in ethanol (0.0648 mL/g) and methanol (0.0393 mL/g) as solvent. Surface morphology as well as porosity and pore size
distribution of metal alginate are greatly influenced by solvent. It can be seen from thermal analysis results that calcium
alginate prepared using different solvent compositions started decomposing at 100 °C, but rapid degradation started around
200 °C. The results showed a stepwise weight loss during thermal sweep, indicating different types of reactions during degradation.
First and second step of rapid degradation was situated around 200–300 and 300–550 °C, respectively; whereas the final step
is situated around 550–650 °C. The trend of degradation was similar for all the solvents, although the amount of final residue
varied from one solvent to another. At the same time, lower thermal stability was also observed with higher heating rates.
Additionally, a kinetic analysis was performed to fit with TGA data, where the entire degradation process has been considered
as three consecutive first order reactions. 相似文献
179.
Sang-Keun Song Zang-Ho Shon Yoo-Keun Kim Yoon-Hee Kang In-Bo Oh Chang-Hoon Jung 《Atmospheric environment (Oxford, England : 1994)》2010,44(5):713-723
The influence of ship emissions on ozone (O3) concentrations in a coastal area (CA) including Busan port, Korea was examined based on a numerical modeling approach during a high O3 episode. The analysis was performed by two sets of simulation scenarios: (1) with ship emissions (e.g., TOTAL case) and (2) without ship emissions (e.g., BASE case). A process analysis (PA) (the integrated processes rate (IPR) and integrated reaction rate (IRR) analyses) was used to evaluate the relative contributions of individual physical and chemical processes in O3 production in and around the CA (e.g., sites of Dong Sam (DS) and Dae Yeon (DY)). The model study suggested the possibility that pollutant gases emitted from the ships traversing Busan port can exert a direct impact on the O3 concentration levels in the CA. Largest impacts of ship emissions on the O3 concentrations were predicted at the coast (up to 15 ppb) and at inland locations (about 5 ppb) due to both the photochemical production of pollutant gases emitted from the ships and meteorological conditions. From the PA, the photochemical production of O3 (P(O3)) due to ship emissions in the CA was found to increase by a mean of 1.5 ppb h?1 (especially by ≥10 ppb h?1 at the DS site) during the day. 相似文献
180.
Jai-Young Lee Sun Young Youm Sang-Il Choi Byung-Taek Oh 《Journal of Material Cycles and Waste Management》2009,11(3):214-221
The present study investigated the reactivity and ability of permeable reactive barriers [zero-valent iron (ZVI)-barrier plus
biobarrier) to remove various contaminants (Cd, As, Zn, Cu, Mn, Cr, NO3
−, NH4
+, and CODcr) from synthetic leachate. Two different reactive materials were used in this study, namely ZVI and autoclaved lightweight
concrete (ALC). After 90 days of column operation, the contaminant profiles were determined along the length of the columns.
The heavy metals were extensively removed in the bio-ALC and sequential barriers (ZVI plus bio-ALC), however the removal efficiencies
for the heavy metals Zn and Cr in the ALC and bio-ALC barriers were comparatively low. Nitrate was completely removed (>99.9%)
in the ALC, bio-ALC, and sequential barriers. More than 50% of the produced ammonium and organic materials were removed in
the biologically reactive zone of the sequential barriers. The results of the present study suggest that sequential barriers
are one of the best solutions for in situ remediation and that they can be applied to clean up the leachate released from
landfills. 相似文献