Simultaneous removal of potent cyanotoxins from water using magnetophoretic nanoparticle of polypyrrole: adsorption kinetic and isotherm study

Cyanotoxins, microcystins and cylindrospermopsin, are potent toxins produced by cyanobacteria in potable water supplies. This study investigated the removal of cyanotoxins from aqueous media by magnetophoretic nanoparticle of polypyrrole adsorbent. The adsorption process was pH dependent with maximum adsorption occurring at pH 7 for microcystin-LA, LR, and YR and at pH 9 for microcystin-RR and cylindrospermopsin (CYN). Kinetic studies and adsorption isotherms reflected better fit for pseudo-second-order rate and Langmuir isotherm model, respectively. Thermodynamic calculations showed that the cyanotoxin adsorption process is endothermic and spontaneous in nature. The regenerated adsorbent can be successfully reused without appreciable loss of its original capacity.     

Evaluation of the efficacy of a portable LIBS system for detection of CWA on surfaces

Laser-induced breakdown spectroscopy (LIBS) is a laser-based optical technique particularly suited for in situ surface analysis. A portable LIBS instrument was tested to detect surface chemical contamination by chemical warfare agents (CWAs). Test of detection of surface contamination was carried out in a toxlab facility with four CWAs, sarin (GB), lewisite (L1), mustard gas (HD), and VX, which were deposited on different substrates, wood, concrete, military green paint, gloves, and ceramic. The CWAs were detected by means of the detection of atomic markers (As, P, F, Cl, and S). The LIBS instrument can give a direct response in terms of detection thanks to an integrated interface for non-expert users or so called end-users. We have evaluated the capability of automatic detection of the selected CWAs. The sensitivity of our portable LIBS instrument was confirmed for the detection of a CWA at surface concentrations above 15 μg/cm². The simultaneous detection of two markers may lead to a decrease of the number of false positive.     

Simulative governance: on the collaborative narrative of civil society participation in the CDM stakeholder framework

The Kyoto Protocol’s Clean Development Mechanism (CDM) is often cited as an exemplar of new, hybrid forms of global environmental governance operating at the public–private interface. Practically, enacting this arrangement involves a wide range of non-state actors. This broad involvement is here assumed to mark a shift towards more polycentric and networked modes of governance in which agents collaborate as ‘stakeholders’ in the process of consensual rule-setting and implementation. Using post-political critique, the depoliticising effects of the stakeholder framework on civil society actors are interrogated, using formal and informal participation opportunities to raise concerns regarding specific CDM projects. The analysis suggests that the CDM’s collaborative narrative of stakeholding structurally fails to stimulate public (re)engagement and is, instead, a prime example of simulative governance that struggles to achieve the simultaneity of two incompatibilities: the participatory revolution and the post-political turn.     

The ecology of the red fox (<Emphasis Type="Italic">Vulpes vulpes</Emphasis> L.) in the middle Lena River basin

The population of foxes in the central regions of Yakutia has grown by a factor of four to five during the period from 2000 to 2011–2012, following an increase in the abundance of voles from the genus Microtus. A total of 130 carcasses of foxes taken in 2007–2012 have been examined. Age- and sex-related variation in morphological features has been described. The demographic structure of the population has been studied by estimating animal age from annual layers in the recording structures. Changes in female fertility and involvement in reproduction depending on age and feeding conditions have been analyzed. Changes in the composition of fox diet caused by long-term population depression in the mountain hare and their effect on the dynamics of fox abundance have been revealed. Age- and sex-related characteristics of the condition factor in foxes and sex-related differences in their dietary preferences have been demonstrated.     

Epigenetic variation in the American mink, <Emphasis Type="Italic">Neovison vison</Emphasis>, from eastern Europe: A search for factors of polymorphism

A comparative analysis of epigenetic variation has been performed in nine European populations and population groups of the American mink. It has been shown that differentiation of samples in nonmetric characters is due mainly to endogenous processes that have occurred in introduced populations in the course of colonization of new territory by the invasive species. Environmental factors have played a secondary role, with the influence of the geographic (latitudinal) origin of a given sample being considerable and stronger than that of macroclimatic factors.     

Characteristics of stone moroko population dynamics at different stages of naturalization in lake- and steam-type Dnieper reservoirs

The probable source of stone moroko, Pseudorasbora parva (Temminck & Schlegel, 1846), populations in lake- and stream-type Dnieper reservoirs was revealed. The dynamics and specific growth rates of these populations over 20 years were analyzed. The dynamic phase portrait method was used to determine the timing of stages in the process of invader naturalization and the periods when its populations were in equilibrium. The potential growth rates of P. parva populations in the Kremenchug and Dneprodzerzhinsk reservoirs were estimated.     

Methodological choices in solution-oriented adaptation research: a diagnostic framework

While methodological choices are critical for solution-oriented adaptation research, the current debate on these is underdeveloped and characterized by simple dichotomies such as bottom-up and top-down as well as vaguely defined concepts such as vulnerability. Adaptation challenges and approaches for addressing them are more diverse than these labels suggest. This paper addresses this deficit by developing a diagnostic framework that helps to identify approaches suitable for addressing a given adaptation challenge. The framework was developed out of the necessity to discuss diverse approaches from natural science, social science and practice in a set of adaptation case studies conducted within the European funded MEDIATION project. Based on these case studies complemented by the literature, we iteratively abstracted typical adaptation challenges researched, typical approaches taken, and empirical, theoretical and normative criteria applied for choosing a particular approach. Our results refine the methodological debate by distinguishing between the three general adaptation challenges of identifying adaptation needs, identifying adaptation measures and appraising adaptation options. Adaptation challenges are further classified according to private and public interest involved, individual or various types of collective action involved, data/model availability, decision-making time horizon, etc. For each type of challenge and approach, we give examples and discuss salient issues. Our results point to the opportunity to apply institutional and behavioural research to support the identification of measures and possibly avoiding barriers in practice. The diagnostic framework also serves as the basis for the forthcoming guidance for assessing vulnerability, impacts and adaptation to be published by the UNEP programme of research on climate change vulnerability, impacts and adaptation.