Recycling of FRP composites: reusing fine GFRP waste in concrete mixtures

Fibre reinforced polymer (FRP) materials are being increasingly used in several applications, but especially in the construction and transportation industries. The composites industry is now producing a wide range of FRP products that include strengthening strips and sheets, reinforcing bars, structural profiles, sandwich panels, moulded planks and piping. The waste management of FRP materials, in particular those made with thermosetting resins, is a critical issue for the composites industry because these materials cannot be reprocessed. Therefore, most thermosetting FRP waste is presently sent to landfill, in spite of the significant environmental impact caused by disposing of it in this way. Because more and more waste is being produced throughout the life cycle of FRPs, innovative solutions are needed to manage it. This paper first presents a state-of-the-art review of the present alternatives available to manage FRP waste. It then describes an experimental study conducted on the technical feasibility of incorporating the fine waste generated during the manufacturing of glass fibre reinforced polymer (GFRP) composites in concrete mixtures. Tests were carried out to evaluate the fresh-state and hardened-state properties of concrete mixes in which between 0% and 20% of sand was replaced by GFRP fine waste. Although the incorporation of high proportions of GFRP waste was found to worsen concrete performance in terms of both mechanical and durability-related properties, it seems feasible to incorporate low proportions and reuse GFRP fine waste in concrete, particularly in non-structural applications such as architectural concrete or pavement slabs, where good mechanical properties are less important.     

Assays with Daphnia magna and Danio rerio as alert systems in aquatic toxicology

For the evaluation and monitoring of the water quality, a series of methodologies, which have as basis an ample variety of bioindicators, may be applied. The aim of this research was to evaluate the use of ecotoxicity assays with Daphnia magna and Danio rerio as alert systems in water contaminated with toxic substances. Using two toxicity databases, the sensibility of those aquatic organisms to a wide variety of chemical products and elements and to some chemical categories was investigated. The relation between the reference dose for human oral chronic exposure (RfD) of all chemical products and the acute toxicity values for both bioindicators was also studied. Acute toxicity tests with D. magna respond to a larger variety of chemicals with a higher sensitivity than those with D. rerio. Although mammals, crustaceans and fish have different routes of exposure, target organs and toxic mechanisms, acute toxicity essays with fish and Daphnia may be used as an initial screening before mammal models are used.     

Levels of PCDD/PCDFs and PCBs in edible marine species and human intake: a literature review

Polychlorinated dibenzo-p-dioxins (PCDDs), dibenzofurans (PCDFs) and biphenyls (PCBs) are lipophilic organic compounds whose origin comes from many different sources. PCDD/Fs and PCBs are ubiquitous and persistent environmental pollutants with a well known potential toxicity, which were included at the 1998 UN-EC POP protocol. Although human exposure to PCDD/Fs and PCBs can occur by various routes, food is the primary source. A number of studies have shown that the major food sources of these organic pollutants are fat-containing animal products, including fish and other seafood. Because of the frequent health recommendations concerning fish consumption, to determine the contribution to the dietary intake of chemical contaminants such as PCDD/Fs and PCBs through fish and other seafood consumption is an issue of special interest. This paper reviews the state of the science regarding recent literature on PCDD/F and PCB levels in marine species and human intake through fish and seafood consumption. The concentrations of these pollutants depend basically on the environment in which the respective species are caught. It is concluded that some groups of population frequently consuming high quantities of certain species could be significantly increasing health risks due to PCDD/F and PCB exposure.     

Health implications of radon distribution in living rooms and bedrooms in U.K. dwellings--a case study in Northamptonshire

Environmental radon exposure of residents of domestic premises in the United Kingdom (UK) and elsewhere in Europe is estimated on the basis of the measured radon concentrations in, and the relative occupancies of, the principal living room and bedroom. While studies on radon concentration variability in the individual units in apartment blocks in various countries have been described, little data has been reported on variability in two-storey single-family dwellings, and the majority of extant studies consolidate living room and bedroom data early in the analysis. To investigate this further, detailed analysis was made of radon concentration data from a set of thirty-four homes situated in areas of Northamptonshire known to exhibit high radon levels. All homes were of typical UK construction of brick/block/stone walls under a pitched tile/slate roof. Approximately 50% of the sample were detached houses, the remainder being semi-detached (duplex) or terraced (row-house). Around 25% of the sample possessed cellars, while 12% were single-storey dwellings (bungalows), reflecting the typical incidence of this type of dwelling in England. In the two-storey homes, all monitored bedrooms were on the upper floor. Distribution of the ratios of bedroom/living room radon concentrations (BR/LR ratio) in individual properties was left-skewed (mean 0.67, median 0.73, range 0.05-1.05) with a tail extending to just above 1.0. The mean is consistent with the outcome of earlier extensive studies in England, while the variability depends principally on the characteristics of the property, and not on seasonal factors. In a small set of homes, the BR/LR ratio was anomalously low, (mean 0.3). BR/LR ratios in single-storey homes clustered around a value of 1.0, indicating that house design, rather than lifestyle, is the dominant factor in determining bedroom radon concentrations. Homes with higher mean annual radon concentrations showed lower BR/LR ratios, supporting our proposal that, in some homes, radon emanation from building materials may comprise a significant component of the overall radon level.     

Trends in the spatial and temporal distribution of 129I and 99Tc in coastal waters surrounding Ireland using Fucus vesiculosus as a bio-indicator

Spatial and temporal trends in (129)I and (99)Tc concentrations around the Irish coastline have been evaluated using Fucus vesiculosus as a bio-indicator. (129)I concentrations in a recent set of seawater samples have also been recorded and reveal an identical spatial pattern. Concentrations of (129)I in Fucus from the northeast coast of Ireland proved to be at least two orders of magnitude higher than concentrations in Fucus from the west coast. The (129)I content of Fucus increased significantly between 1985 and 2003, in line with increases in discharges of (129)I from the Sellafield nuclear reprocessing plant. Similar trends were observed in the case of (99)Tc. (129)I/(99)Tc ratios in Irish seawater were deduced from the Fucus data, and compared to ratios in discharges from Sellafield and from the French reprocessing plant at Cap de la Hague. Levels of (129)I and (99)Tc in Fucus from the west coast were found to be enhanced with respect to levels in seaweeds from other regions in the Northern Hemisphere unaffected by discharges from nuclear installations such as those referred to.     

Indoor radon monitoring in Northern Iran using passive and active measurements

In this work we present the results of a 2-year survey of indoor radon variations in four cities of Lahijan, Ardabil, Sar-Ein and Namin in North and Northwest Iran. We used both passive and active measurements by solid state nuclear track detectors (SSNTDs) with CR-39 polycarbonate and PRASSI Portable radon Gas Surveyor. A total of 1124 samplers in Lahijan, Ardabil, Sar-Ein and Namin were installed. Sampling frequency was seasonal and sampling locations were randomly chosen based on dwelling structures, floors, geological formations, elevation and temperature variation parameters. For quality assurance, 281 active measurements and double sampling were carried out. Based on our results and the results of previous surveys, Ardabil and Lahijan have the second and third highest radon concentration in Iran, respectively (Ramsar is first). The average radon concentration during the year in Lahijan, Ardabil, Sar-Ein and Namin were 163, 240, 160 and 144 Bq/m(3) with medians of 160, 168, 124 and 133 Bq/m(3), respectively. These concentrations give rise to annual effective doses of 3.43 mSv/y for Lahijan and 5.00 mSv/y for Ardabil. The maximum recorded concentration was 2386 Bq/m(3) during winter in Ardabil and the minimum concentration was 55 Bq/m(3) during spring in Lahijan. Relationships between radon concentration and building materials and room ventilation were also studied. The dosimetry calculations showed that these four cities could be categorized as average natural radiation zones. The correlation coefficients relating warm and cold season radon variation data were obtained.     

Optimisation of systems to locate discrete gamma-ray sources within a large search area

Most systems used to locate discrete gamma-ray sources involve systematically passing a detector over the search area while seeking a significant increase in the observed count-rate. This paper discusses the ways in which such systems may be designed to maximise the probability of locating a source. It is shown that optimised systems use a collimated, energy-discriminating detector and overlapping counting intervals determined by the scanning geometry and speed.     

Radiocesium in caribou and reindeer in northern Canada, Alaska and Greenland from 1958 to 2000

This study summarizes the spatial and temporal trends of fallout (137)Cs concentrations in caribou and reindeer (Rangifer tarandus ssp.), reported in various programs in Canada, Alaska and Greenland, over a 40-y period. During the 1960s, the highest (137)Cs concentrations (2000-3000Bqkg(-1) wet weight in muscle) were found in the large caribou herds of central northern Canada, with levels about 50% lower in Alaska and Greenland. Concentrations varied by up to a factor of 6 between spring and fall. Concentrations in reindeer were comparable to those in caribou from the same regions. The highest (137)Cs concentrations (750Bqkg(-1)) in the late 1980s were found in the Caniapiscau herd of central Québec. The contribution from the Chernobyl accident in 1986 was estimated from (134)Cs measurements to be 10-40% of the total (137)Cs. Present concentrations have declined to 200-300Bqkg(-1). The effective half-life (T(eff)) of (137)Cs in Canadian caribou herds was estimated to be about 6 y. The potential impact on the health of northern residents is discussed.     

Analysis of radiocaesium in the Lebanese soil one decade after the Chernobyl accident

Fallout from the Chernobyl reactor accident due to the transport of a radioactive cloud over Lebanon in the beginning of May 1986 was studied 12 years after the accident for determining the level of (137)Cs concentration in soil. Gamma spectroscopy measurements were performed by using coaxial high sensitivity HPGe detectors. More than 90 soil samples were collected from points uniformly distributed throughout the land of Lebanon in order to evaluate their radioactivity. The data obtained showed a relatively high (137)Cs activity per surface area contamination, up to 6545Bqm(-2) in the top soil layer 0-3cm. The average activity of (137)Cs in the top soil layer 0-3cm in depth was 59.7Bqkg(-1) dry soil ranging from 15 to 119Bqkg(-1) dry soil. The horizontal variability was found to be about 45% between the sampling sites. The depth distribution of total (137)Cs activity in soil showed an exponential decrease. Estimation of the annual effective dose due to external radiation from (137)Cs contaminated soil for selected sites gave values ranging from 19.3 to 91.6 micro Svy(-1).     

A review of research on the environmental impact of e-business and ICT

This paper attempts to provide a review of the current state of the art of how e-business/ICT affects the environment. The work reviewed is in various forms including journal papers and thesis which have been peer-reviewed, as well as other resources such as projects and project reports, conference and symposia, and websites. It is claimed that the research examined has captured the most important work to date, either for a general knowledge of this new area or for background study by experts carrying out future research. The review has found that the currently dominant approach is either a micro-level case study approach or a macro-level statistical approach. It is concluded that a more predictive and empirical model, which can be applied within a sector of society, should be more beneficial in the long term. This approach should help simulate potential impacts resulting from changes of indicators, so that positive effects can be promoted and negative ones alleviated proactively, rather than knowing and accepting outcomes passively.