Distribution of Chlorinated Organic Pollutants in Harbor Sediments of Livorno (Italy): A Multivariate Approach to Evaluate Dredging Sediments

Dredging is a very important procedure for harbor management. InItaly the guidelines for the offshore dumping of dredged materials are issued by the Ministry of Environment. Theydescribed a few steps of dredging activities, such as thesampling strategy, but do not deal with limits or guide-valuesfor the chemical, physical and biological composition of theresulting sediments. The quality of dredged materials is mainlydependent on the presence of inorganic and organic pollutants.In particular, polychlorinated biphenyls (PCBs) and organo-chlorinated pesticides are seen as a high priority inmarine environment by international organizations because oftheir persistence, toxicity and bioaccumulation capacity.In this article the presence of some PCBs and organo-chlorinatedpesticides in sediment samples collected from the harbor ofLivorno (Northern Tyrrhenian Sea) was investigated. Theconcentration of HCHs, Aldrin, Chlordanes, DDEs, DDTs, and PCBsin 12 representative sites ranged between <1 g kg^–1and 95, 19, 32, 35, 107, and 111 g kg^–1, respectively.The application of univariate and multivariate statisticaltechniques, such as linear regression analysis and principalcomponent analysis, to the experimental data showed a differentdistribution of PCBs in the two sediment layers. On thecontrary, the vertical distribution of the other investigatedpollutants was more homogeneous and affected by randomvariability. The multivariate approach was an important tool to establish more rational criteria for the management of dredged materials.     

Preliminary air pollution monitoring in San Miguel, Buenos Aires

Passive diffusion samplers were employed in San Miguel(Buenos Aires Metropolitan Area) for a preliminary airpollution monitoring. The highest loads were observedin downtown, compared with an urban background site.Total suspended particulate matter (TSPM) varied from0.257 to 0.033 mg cm^-2 month^-1; dust was examinedfor particle nature and size distribution. A similartrend was observed for nitrogen dioxide (NO₂) andTSPM spatial distribution, suggesting that traffic isthe major pollution source. Sulphur dioxide (SO₂)values were low and rather homogeneous. Levels for theinvestigated pollutants are below EPA's guide linevalues. Geographic (flat area, near to Rio de LaPlata) and climatologic factors (rainfalls andvariable wind directions) contribute to disperse pollutants.     

Seasonal characteristics of haze observed by continuous visibility monitoring in the urban atmosphere of Kwangju, Korea

Continuous visibility monitoring has been carried out inKwangju, Korea since May 1999. The total light extinctioncoefficient b _ext measured by a transmissometer andreveals seasonal trends in urban visual air quality,especially under hazy conditions with a visual range of lessthan 15 km. Seasonal atmospheric visibility under lowrelative humidity during the winter was observed to be betterthan during any other seasons. Summertime visibility wasseverely degraded due to highly increased light scattering byhygroscopic particles under high humidity atmosphericconditions. Visibility during spring and fall was alsomoderate. However, yellow sand in spring caused the lowestvisibility conditions over the measurement area for a fewdays. With continuous monitoring using the transmissometer,the daily average seasonal visual range was measured to be13.1, 9.2, 11.0, and 13.9 km in spring, summer, falland winter, respectively. Under the atmospheric humiditycondition less than 60%, visual range was observed tobe 16.1, 13.9, 15.1, and 16.6 km in spring, summer,fall, and winter, respectively. The mean light extinctionbudget by sulfate and nitrate aerosols was determined to bethe highest value of 63.71% during the summer and thelowest value of 27.08% during spring. During the `yellow sand dust' period, a mean light extinction budget by soil particles was estimated to be at an unusually high value of 44.22%.     

Application of intrawell testing of RCRA groundwater monitoring data when no upgradient well exists

A statistical quality control approachto detect changes in groundwater quality from aregulated waste unit is described. The approachapplies the combined Shewhart-CUSUM control chartmethodology for intrawell comparison of analyteconcentrations over time and does not require anupgradient well. A case study from the U.S.Department of Energy's Hanford Site is used forillustration purposes. This method is broadlyapplicable in groundwater monitoring programs wherethere is no clearly defined upgradient location, thegroundwater flow rate is exceptionally slow, or wherea high degree of spatial variability exists inparameter concentrations. This study also indicatesthat the use of the Data Quality Objectives (DQO)process can assist in designing an efficient andcost-effective groundwater monitoring plan to achievethe optimum goal of both low false positive and lowfalse negative rates (high power).     

An Evaluation of Selenium Concentrations in Water, Sediment, Invertebrates, and Fish from the Republican River Basin: 1997–1999

The Republican River Basin of Colorado,Nebraska, and Kansas lies in a valley which contains PierreShale as part of its geological substrata. Selenium is anindigenous constituent in the shale and is readily leached intosurrounding groundwater. The Basin is heavily irrigated throughthe pumping of groundwater, some of which is selenium-contaminated, onto fields in agricultural production. Water,sediment, benthic invertebrates, and/or fish were collected from46 sites in the Basin and were analyzed for selenium to determinethe potential for food-chain bioaccumulation, dietary toxicity,and reproductive effects of selenium in biota. Resultingselenium concentrations were compared to published guidelines orbiological effects thresholds. Water from 38% of the sites (n = 18) contained selenium concentrations exceeding 5 g L^-1, which is reported to be a high hazard for selenium accumulation into the planktonic food chain. An additional 12 sites (26% of the sites) contained selenium in water between 3–5 g L^-1, constituting a moderate hazard. Selenium concentrations in sedimentindicated little to no hazard for selenium accumulation fromsediments into the benthic food chain. Ninety-five percent ofbenthic invertebrates collected exhibited selenium concentrationsexceeding 3 g g^-1, a level reported as potentially lethal to fish and birds that consume them. Seventy-five percent of fish collected in 1997, 90% in 1998, and 64% in 1999 exceeded 4 g g^-1selenium, indicating a high potential for toxicity andreproductive effects. However, examination of weight profilesof various species of collected individual fish suggestedsuccessful recruitment in spite of selenium concentrations thatexceeded published biological effects thresholds for health andreproductive success. This finding suggested that universalapplication of published guidelines for selenium may beinappropriate or at least may need refinement for systems similarto the Republican River Basin. Additional research is needed todetermine the true impact of selenium on fish and wildliferesources in the Basin.     

A Study on Transfer Factors of 60Co and 65Zn from Soil to Plants in the Tropical Environment of Bangladesh

Soil to plant transfer factor (TF) of⁶⁰Co and ⁶⁵Zn was determined fromradioisotope experiments on plants grown in pots underoutdoor ambient tropical conditions for three growingseasons (1995–1998). The TFs were obtained fordifferent plants/crops such as, rice, bean, peanutspineapple, cabbage, tomato, spinach and grass. Theaverage TF values of ⁶⁰Co are found to be 0.087,0.15, 0.12, 0.67, 0.28, 0.79, 1.03 and 0.34respectively for the above mentioned plants/crops. Incase of ⁶⁵Zn, the average TF values are found tobe 2.24, 1.17, 0.89, 1.09, 0.78, 1.34, 2.92 and 1.78,respectively, for the above mentioned plants/crops. Thedata will be useful to assess the radiation exposureto man associated with the releases of radionuclidesfrom nuclear facilities by means of radiologicalassessment models that require transfer factors asinput parameters to predict the contamination ofradionuclides in foodchain.     

Cadmium and Lead Levels in Fish (Tilapia Nilotica) Tissues as Biological Indicator for Lake Water Pollution

Cadmium and lead were determined in different tissues (muscle,gill, stomach, intestine, liver, vertebral column and scales) of Tilapia nilotica from the High Dam Lake, Aswan (Egypt) to assess the lake water pollution with those toxic metals. Fish samples were chosen from different ages and weights to be analyzed along with samples of the aquatic plant(Najas armeta), sediment and lake water.The results showed that cadmium and lead concentrations were higher in fish scales and vertebral column than in the other parts of the fish. Cadmium and lead levels in High Dam lake water and fish (Tilapia nilotica) were a result of the pollution which uptakes from aquatic plants, sediments andgasoline containing lead that leaks from fishery boats. Tilapia nilotica fish was used as a good bio-assay indicator for the lake pollution with cadmium and lead. The fish musclesin this study were in the safety baseline levels for man consumption.     

Ambient Air Quality Monitoring Network Design for Assessing Human Health Impacts from Exposures to Airborne Contaminants

Existing methods of establishing ambientair quality monitoring networks typically evaluateonly parameters related to ambient concentrations ofthe contaminant(s) of interest such as emissionsource characteristics, atmospheric transport anddispersion, secondary reactions, depositioncharacteristics, and local topography. However,adverse health risks from exposures to airbornecontaminants are a function of the contaminant andthe anatomic and physiologic characteristics of theexposed population. Thus, ambient air qualitymonitoring networks designed for the protection ofpublic health or for epidemiological studiesevaluating adverse health impacts from exposures toambient air contaminants should account for bothcontaminant characteristics and human healthparameters. A methodology has been establishedwhich optimizes ambient air quality monitoringnetworks for assessments of adverse human healthimpacts from exposures to airborne contaminants byincorporating human health risk assessmenttechniques. The use of risk assessment techniquesas the basis for designing ambient air qualitymonitoring networks will help to target limitedfinancial and human resources to evaluate humanhealth risks from exposures to airbornecontaminants.     

A Watershed-based Cumulative Risk Impact Analysis: Environmental Vulnerability and Impact Criteria

Swine Concentrated Animal Feeding Operations (CAFOs) have received much attention in recent years. As a result, a watershed-based screening tool, the Cumulative Risk Index Analysis (CRIA), was developed to assess the cumulative impacts of multiple CAFO facilities in a watershedsubunit. The CRIA formula calculates an index number based on: 1) the area of one or more facilities compared to the area of the watershed subunit, 2) the average of the environmental vulnerability criteria, and 3) the average of the industry-specific impact criteria. Each vulnerability or impact criterion is ranked on a 1 to 5 scale, with a low rank indicating low environmental vulnerability or impact and a high rank indicating high environmental vulnerability or impact. The individual criterion ranks, as well as the total CRIA score, can be used to focus the environmental analysis and facilitate discussions with industry, public, and other stakeholders in the Agency decision-making process.     

The Monitoring and Risk Assessment of Zn Deposition Around a Metal Smelter in Latvia

Heavy metal concentrations in Hylocomium splendens collected around a metal smelter in Latvia showed very high concentrations of Zn (>200 g/g), and elevated concentrations of Pb (38.3 g/g) and Cu (18.3 g/g). In an attempt to better evaluate the potential toxicity of the high Zn concentrations, a serial elution method was used to determine the concentrations of zinc in intercellular, extracellular exchangeable cell wall, intracellular, and particle fractions. The intercellular Zn concentrations represent the water soluble component of the total concentrations, and were low with no clear trends. Zn concentrations in the extra- and intracellular and particle fractions decreased exponentially from the pollutant source. Intracellular Zn concentrations in moss close to the emission source are within the range considered to be potentially toxic, from other single element exposure studies. The proportion of Zn in the relatively insoluble particle fraction, which is least associated with environmental risk, was greater closer to the pollution source, reaching > 30% in the oldest Hylocomium splendens segments.