Rapid removal of nitrate and sulfate in freshwater wetland sediments

Anaerobic microbial processes play particularly important roles in the biogeochemical functions of wetlands, affecting water quality, nutrient transport, and greenhouse gas fluxes. This study simultaneously examined nitrate and sulfate removal rates in sediments of five southwestern Michigan wetlands varying in their predominant water sources from ground water to precipitation. Rates were estimated using in situ push-pull experiments, in which 500 mL of anoxic local ground water containing ambient nitrate and sulfate and amended with bromide was injected into the near-surface sediments and subsequently withdrawn over time. All wetlands rapidly depleted nitrate added at ambient ground water concentrations within 5 to 20 h, with the rate dependent on concentration. Sulfate, which was variably present in porewaters, was also removed from injected ground water in all wetlands, but only after nitrate was depleted. The sulfate removal rate in ground water-fed wetlands was independent of concentration, in contrast to rates in precipitation-fed wetlands. Sulfate production was observed in some sites during the period of nitrate removal, suggesting that the added nitrate either stimulated sulfur oxidation, possibly by bacteria that can utilize nitrate as an oxidant, or inhibited sulfate reduction by stimulating denitrification. All wetland sediments examined were consistently capable of removing nitrate and sulfate at concentrations found in ground water and precipitation inputs, over short time and space scales. These results demonstrate how a remarkably small area of wetland sediment can strongly influence water quality, such as in the cases of narrow riparian zones or small isolated wetlands, which may be excluded from legal protection.     

OWNERSHIP AND WATER SYSTEM OPERATION1

ABSTRACT: Two types of organizational systems provide most of the water service in the United States. The investor-owned firm operates on a profit basis generally subject to state commission regulation. The government-owned firm is generally confronted by local control. The comparative efficiency of private versus government firm provision of water services is essentially an empirical issue. Unit costs and other operating statistics are examined for water firms of each ownership form. The analysis shows that private firms tend to have higher operation costs than do government firms, possibly attributable to wage-salary differentials. The analysis also indicates that capital investment in large government firms may result in diseconomies. The analysis creates serious doubt as to whether efficient provision of water services can be better facilitated by large mergers of either ownership form.     

FINANCING PRIVATE WATER RESOURCE DEVELOPMENT: ANALYSIS OF A STATE LOAN PROGRAM1

ABSTRACT. A State loan program was analyzed for its effects on groundwater development in Wyoming. The analysis focused on the effects of low-interest State financing on the economic feasibility of investments in center-pivot sprinkler irrigation systems. The feasibility analysis indicated that investments in sprinkler systems for production of cash crops are highly profitable, and would frequently be carried out whether or not the State loan program were available. Investments in sprinklers for production of forage crops are perhaps frequently made attractive by the loan program. Thus, while the program appears to have accelerated the pace of private water resource development in Wyoming, it has also subsidized some investments that would have been carried out regardless of the program's existence. Further analysis indicated that sprinkler investments carried out with State financing contribute substantially to firm growth when cast crops are grown, but have less marked, and sometimes negative, effects on growth when forage crops are produced. Some positive effects of the loan program on southeast Wyoming's regional economy were noted, though a complete empirical analysis of regional impacts was beyond the scope of the study.     

DIGITAL SIMULATION OF THE EFFECT OF THERMAL DISCHARGE ON STREAM WATER QUALITY1

A modified transient version of the Streeter-Phelps model along with the energy balance equation is employed to analyze the effects of waste heat discharge from power plants on stream water quality. Analysis is also made to examine the effects of the upstream water quality and stream velocity on the downstream DO concentration level. The resulting coupled nonlinear hyperbolic partial differential equations representing the energy, BOD and DO concentrations are solved by the method of characteristics and simulated on a digital computer. Final numerical results indicate that the allowable quantity of thermal discharge does heavily depend on the upstream quality.     

WATER QUALITY CONTROL BY ARTIFICIAL AERATION OF STREAM RECEIVING THERMAL AND ORGANIC WASTE DISCHARGES1

ABSTRACT: The purpose of this work is to study the installation of artificial aerators for water quality control of a stream which receives thermal and organic waste discharges. The location and numer of diffuser type aerators to be installed along the stream are determined so as to maintain the stream DO content above a certain minimum requirement (4 mg/l or 5 mg/l) for normal aquatic life. Effects of the stream velocity, upstream BOD concentration and rates of thermal and organic waste discharges to the stream are examined.     

NITROGEN TRANSFORMATIONS IN SEDIMENTS AS AFFECTED BY CHEMICAL AMENDMENTS1

ABSTRACT: A study was conducted to elucidate some of the chemical factors affecting the rate and pathways of N transformations in lake sediments. The main emphasis was placed on modifying a noncalcareous sediment with CaCO₃ to approximate the composition of a calcareous sediment. Additionally, the effects of Ca²⁺, CO₃^2-, Mg2⁺ and OH^- were evaluated by using appropriate chemicals. Further, the effect of aluminum sulfate was evaluated with both sediment types. Sediment pH at 7 days was not affected by CaCO₃, but was decreased by aluminum sulfate. The CaCO₃ treatment increased the rate of ammonification, nitrification, reduction of acetylene to ethylene and methane formation, while with few exceptions the other treatments decreased the rate of the transformations studied. Aluminum sulfate, which has been proposed as a lake restoration treatment, increased ammonification but decreased most of the other transformations.     

THE IMPACT OF HIGH INTEREST RATES ON OPTIMUM MULTIPLE OBJECTIVE DESIGN OF SURFACE RUNOFF URBAN DRAINAGE SYSTEMS1

ABSTRACT. This research examines the impact of high rates of interest upon the least cost system design for urban drainage systems when water quality is a critical parameter. Results of examination of twelve alternative system designs in a case study watershed indicate the least cost study design is highly sensitive to the rate of interest, but not sensitive to the water quality parameters. When the high rates of interest currently prevalent are introduced into the model those systems which contain open channel collection components are selected as the least cost system. At low rates of interest pipeline collection components are selected as the least cost system. Holding pond components of system design are cost effective at several levels of water quality. They are neutral to the rate of interest so they are incorporated in least cost systems at all the levels of interest rates. The results of the study indicate that at the current high rates of interest open channel collection systems and holding ponds are cost effective system components to achieve selected levels of water quality in urban drainage system design.     

A STUDY OF THE SURFACE SYNOPTIC CIRCULATION PATTERNS IN ASSOCIATION WITH THE DROUGHT OF THE 1960's IN THE NORTHEASTERN UNITED STATES1

A comparative evaluation is made of the frequency of air mass and frontal types during a 4-year representative portion of the drought as opposed to an equivalent non-drought period. Selection of the non-drought period is based on the Palmer Drought Index. Results indicate a statistically significant increase in the occurrence of continental polar air during the drought. Other conclusions concerning conditions during the drought, not statistically significant but worth further study, are: lower frequency of maritime tropical air in the summer months, more occurrences of cold and occluded fronts, and fewer occurrences of stationary fronts.     

FACTORS AFFECTING SALINITY REDUCTION IN LAKE TARPON,PINELLAS COUNTY,FLORIDA1

ABSTRACT: Following an enclosure of a sink-hole connecting Lake Tarpon to the Gulf of Mexico, the chloride concentration of lake waters decreased. Water and chloride budgets for the lake in 1975 were prepared, and predictions using the model of Lerman and Brunskill (1971) were made as to the time required for the lake to achieve fresh water status. Model verification indicated good agreement with predictions in 1976; however, data on [C1^-] for 1977 and 1978 are not as supportive of the model used. The information concerning the Lake Tarpon watershed provided by this latter fact is discussed.