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151.
Jiménez B Rodríguez-Estrella R Merino R Gómez G Rivera L José González M Abad E Rivera J 《Environmental pollution (Barking, Essex : 1987)》2005,133(1):139-146
Organochlorine compounds (OCs) including polychlorinated dibenzo-p-dioxins (PCDDs), dibenzofurans (PCDFs), polychlorinated biphenyls (PCBs) and 1,1-dichloro-2,2-bis(p-chlorophenyl)ethylene (p-p'-DDE), heavy metals (Pb, Cd, Zn, Cu), and arsenic were measured in house sparrows (Passer domesticus) and common ground doves (Columbina passerina) from Baja California Sur, México. Concentrations of PCDD/Fs were low, with 21 pg/g for house sparrows, and 7.7 pg/g for common ground doves. Non-ortho-PCB concentrations in house sparrow and common ground doves were 58 and 254 pg/g, respectively, and are within the highest concentrations reported in species that are in the low levels of food webs. The major differences in organochlorine levels between species were found for ortho-PCBs and DDTs. ortho-PCB levels were higher in the seedeater species, whereas DDT levels were higher in the omnivorous species. Heavy metal levels were far below those associated with negative effects. 相似文献
152.
153.
Association of benzo(a)pyrene with dissolved organic matter: Prediction of Kdom from structural and chemical properties of the organic matter 总被引:1,自引:0,他引:1
The affinity of dissolved organic matter (DOM) for binding a polycyclic aromatic hydrocarbon, benzo(a)pyrene (BaP), was measured for 11 surface and ground waters and a commercial humic acid. The hydrophobic-acid (HbA) and hydrophobic-neutral (HbN) compositions of the DOM, solution absorptivity at 270nm (ABS270), and DOM molar volumes were determined. Waters enriched in HbA material had a larger molar volume and higher aromatic content (as indicated by the ABS270). There was a good correlation between the size and HbA content of the DOM from the different sources and the Kdom for binding BaP. An excellent predictive relationship (r2 = 0.9) was demonstrated between the ABS270 of a water and the Kdom for binding BaP. Based on these results, it is suggested that binding of BaP to DOM depends not only on the hydrophobicity of DOM, but also on the existence of an open structure within the DOM to provide access of the aqueous solute to hydrophobic domains within the DOM. 相似文献
154.
LaRosa LE Buckley TJ Wallace LA 《Journal of the Air & Waste Management Association (1995)》2002,52(1):41-49
Black carbon (BC) was measured every 5 min for two years (May 1998-May 2000) inside and immediately outside a northern Virginia house (suburban Washington, DC) occupied by two nonsmokers. Two aethalometers, which measure BC by optical transmission through a quartz fiber tape, were employed indoors and outdoors. Meteorological parameters were obtained on an hourly basis from nearby Dulles airport. Indoor activities were recorded to identify indoor sources such as combustion activities, which occurred 9% of the time during the first year and 4% of the time during the second year. At times without indoor sources, indoor/outdoor BC ratios averaged 0.53 in the first year and 0.35 in the second year. The main outdoor source of BC was the general regional background, contributing 83-84% of the total during each of the two years. Morning rush hour traffic contributed 8-9% of the total BC. An evening peak in the fall and winter, thought to include contributions from wood burning, was responsible for approximately 8% of the annual average BC concentration. The main indoor sources of BC were cooking and candle burning, contributing 16 and 31%, respectively, of the annual average indoor concentrations in the two years. Relative humidity (RH) affected the outdoor aethalometer in both years. An artifact associated with the tape advance was noted for the aethalometer, but a correction factor was developed that reduced the associated error by a factor of 2. 相似文献
155.
The ban of commonly used soil fumigants, DBCP and EDB, for control of nematodes in pineapple fields has prompted investigations into a non-fumigant nematicide, fenamiphos (Nemacur®). The transformation and adsorption in soil of fenamiphos and its transformation products, f. sulfoxide and f. sulfone were studied in the laboratory. Fenamiphos adsorption on soil exceeded that of f. sulfoxide and f. sulfone. F. sulfoxide, however, was the most persistent. A one-dimensional simulation model was used to assess the impact of transformation and adsorption on the mobility and distribution of fenamiphos and f. sulfoxide in soil. Simulated results showed that fenamiphos stayed in the topsoil and transformed rapidly to f. sulfoxide. Because of the persistence and mobility of f. sulfoxide, this metabolite leached rapidly and significant amounts remained in the soil. This suggests that for times exceeding three weeks, f. sulfoxide may be the dominant compound providing nematode control in drip-irrigated pineapple. 相似文献
156.
Project MOHAVE was a major monitoring, modeling, and data analysis study whose objectives included the estimation of the contributions of the Mohave Power Project (MPP) and other sources to visibility impairment in the southwestern United States, in particular at Grand Canyon National Park. A major element of Project MOHAVE was the release of perfluorocarbon tracers at MPP and other locations during 50-day summer and 30-day winter intensive study periods. Tracer data (from about 30 locations) were sequestered until several source and receptor models were used to predict tracer concentrations. None of the models was successful in predicting the tracer concentrations; squared correlation coefficients between predicted and measured tracer were all less than 0.2, and most were less than 0.1. 相似文献
157.
Monica A. Sundset Perry S. Barboza Thomas K. Green Lars P. Folkow Arnoldus Schytte Blix Svein D. Mathiesen 《Die Naturwissenschaften》2010,97(3):273-278
Reindeer (Rangifer tarandus) eat and utilize lichens as an important source of energy and nutrients in winter. Lichens synthesize and accumulate a wide
variety of phenolic secondary compounds, such as usnic acid, as a defense against herbivores and to protect against damage
by UV-light in solar radiation. We have examined where and to what extent these phenolic compounds are degraded in the digestive
tract of the reindeer, with particular focus on usnic acid. Three male reindeer were given ad libitum access to a control
diet containing no usnic acid for three weeks and then fed lichens ad libitum (primarily Cladonia stellaris) containing 9.1 mg/g DM usnic acid for 4 weeks. Usnic acid intake in reindeer on the lichen diet was 91–117 mg/kg BM/day.
In spite of this, no trace of usnic acid or conjugates of usnic acid was found either in fresh rumen fluid, urine, or feces.
This suggests that usnic acid is rapidly degraded by rumen microbes, and that it consequently is not absorbed by the animal.
This apparent ability to detoxify lichen phenolic compounds may gain increased importance with future enhanced UV-B radiation
expected to cause increased protective usnic acid/phenol production in lichens. 相似文献
158.
Laura Rodríguez-Loeches Alejandro Barro Martha Pérez Frank Coro 《Die Naturwissenschaften》2009,96(4):531-536
Both sexes of Phoenicoprocta capistrata have functional tymbals. The scanning electron microscopy revealed differences in the morphology of these organs in males
and females. Male tymbals have a well-developed striated band, constituted by 21 ± 2 regularly arranged striae whereas female
tymbals lack a striated band. This type of sexual dimorphism is rare in Arctiidae. The recording of the sound produced by
moths held by the wings revealed that while males produced trains of pulses organized in modulation cycles, females produced
clicks at low repetition rate following very irregular patterns. Statistically, there are differences between sexes in terms
of the duration of pulses, which were 355 ± 24 μs in the case of males and 289 ± 29 μs for females. The spectral characteristics
of the pulses also show sexual dimorphism. Male pulses are more tuned (Q
10 = 5.2 ± 0.5) than female pulses (Q
10 = 2.7 ± 0.5) and have a higher best frequency (42 ± 1 kHz vs. 29 ± 2 kHz). To our knowledge, this is the first report on
an arctiid moth showing sexual dimorphism in tymbal’s anatomy that leads to a best frequency dimorphism. Males produce sound
at mating attempts. The sounds recorded during mating are modulation cycles with the same spectral characteristics as those
recorded when males are held by the wings. The morphological and acoustic features of female tymbals could indicate a process
of degeneration and adaptation to conditions under which the emission of complex patterns is not necessary.
Frank Coro no longer works at Universidad de La Habana. 相似文献
159.
David I.S. Green Samuel M. McDeid William G. Crumpton 《Journal of the American Water Resources Association》2019,55(3):543-558
We present estimates of the volumetric storage capacities of currently drained upland depressions and catchment depressional specific storage and runoff storage indices for the Des Moines Lobe of Iowa (DML‐IA) subregion of the Prairie Pothole Region of North America. Storage capacities were determined using hydrologically enforced Light Detection and Ranging‐derived digital elevation models, and a unique geoprocessing algorithm. Depressional specific storage was estimated for each 12‐digit Hydrologic Unit Code (HUC12) watershed in the region from total catchment‐specific depressional storage volume and catchment area. Runoff storage indices were calculated using catchment depressional specific storage values and estimates of the amount of rainfall likely to fall within each watershed during sub‐annual and 1‐, 2‐, 5‐, and 10‐year 24‐h events. The 173,171 identified drained depressions in the DML‐IA can store up to 903.5 Mm3 of runoff. Most of this capacity is in depressions located in the north of the region. Specific storage varies from nearly 109 mm in the younger landscapes to <10 mm in older more eroded areas. For 95% of the HUC12 watersheds comprising the region, depressional storage will likely be exhausted by rainfall‐derived runoff in excess of a 1‐year 24‐h event. Rainfall amounts greater than a 5‐year 24‐h event will exceed all available depressional storage. Therefore, the capacity of drained depressions in the DML‐IA to mitigate flooding resulting from infrequent, but large, storm events is limited. 相似文献
160.
Kristen M. Shockley Heather Ureksoy Ozgun Burcu Rodopman Laura F. Poteat Timothy Ryan Dullaghan 《组织行为杂志》2016,37(1):128-153
Career success is a main focus of career scholars as well as organizational stakeholders. Historically, career success has been conceptualized and measured in an objective manner, mainly as salary, rank, or number of promotions. However, the changing nature of work has also necessitated a change in the way many employees view success, adding a more subjective component. Although there has been theoretical discussion and calls to develop a comprehensive measure of subjective career success, no contemporary comprehensive quantitative measure exists. The goal of this study was to create and validate a measure of subjective career success, titled the Subjective Career Success Inventory (SCSI). The SCSI includes 24 items that address subjective career success via eight dimensions. The scale was developed and validated through four phases of data collection, beginning with interviews and focus groups, followed by item sorting tasks, then item refinement through confirmatory factor analysis, and finally convergent and discriminant validity quantitative analysis. Theoretical and practical implications are discussed. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献