Shine a light: Under-ice light and its ecological implications in a changing Arctic Ocean

The Arctic marine ecosystem is shaped by the seasonality of the solar cycle, spanning from 24-h light at the sea surface in summer to 24-h darkness in winter. The amount of light available for under-ice ecosystems is the result of different physical and biological processes that affect its path through atmosphere, snow, sea ice and water. In this article, we review the present state of knowledge of the abiotic (clouds, sea ice, snow, suspended matter) and biotic (sea ice algae and phytoplankton) controls on the underwater light field. We focus on how the available light affects the seasonal cycle of primary production (sympagic and pelagic) and discuss the sensitivity of ecosystems to changes in the light field based on model simulations. Lastly, we discuss predicted future changes in under-ice light as a consequence of climate change and their potential ecological implications, with the aim of providing a guide for future research.     

Formation of organochlorine by-products in bleached laundry

Laundering fabrics with chlorine bleach plays a role in health and hygiene as well as aesthetics. However, laundry bleaching may create chlorinated by-products with potentially adverse human health effects. Studies have shown that toxic chlorinated gases are produced in the headspace of washing machines when hypochlorite-containing bleach is used. Laundry bleaching has also been implicated in contributing dissolved organochlorine to municipal wastewater. However, there have been no reports of organochlorines produced and retained in fabric as a result of laundry bleaching. We have used a chlorine-specific X-ray spectroscopic analysis to demonstrate the formation of organochlorine by-products in cotton fabrics laundered with chlorine bleach under typical household conditions. Organochlorine formation increases at higher wash temperature. At least two pools of organochlorine are produced in bleached fabric: a labile fraction that diminishes over several months of storage time as well as a more stable fraction that persists after more than 1 year. Our results also suggest that residual hypochlorite remains in fabric after laundering with bleach, presenting the possibility of direct and sustained dermal contact with reactive chlorine. This study provides a first step toward identifying a new risk factor for elevated organochlorine body burdens in humans.     

Distribution and morphological variation of low-shore algal turfs

The distribution of three functional groups of algae (filamentous, corticated terete and calcareous articulated) was investigated in low-shore, turf-forming assemblages from rocky shores in the western Mediterranean Sea (Italy). Algae were sampled along shores from three different stations. Shores were either exposed to wave action or sheltered and were characterised by various inclinations of the rocky substratum (horizontal, sloping and vertical). The hypotheses tested were: that the relative abundance of the three functional groups of algae (1) varies between sheltered and exposed shores, (2) is influenced by substratum inclination and (3) that these distributions are consistent across stations. There was no clear relationship between the morphology of turf-forming algae and shore characteristics. Covers of filamentous, corticated terete and calcareous articulated algae differed among shores and stations, but patterns were not consistent across shores with similar exposure to waves and substratum inclination. Turfs often comprised algae with different morphologies, in a combination of anchor and epiphytic species. It is suggested that functional groups of algae, as currently identified, are not effective in describing changes in distribution of algae between sheltered and exposed shores, when turf morphologies are considered. Future research on relationships between morphology and ecology of algae should consider the potential importance of positive interactions among associated species, which could override responses of individual functional groups.     

Pilot scale testing composite swellable organosilica nanoscale zero‐valent iron—Iron‐Osorb®—for in situ remediation of trichloroethylene

Iron‐Osorb^® is a solid composite material of swellable organosilica with embedded nanoscale zero‐valent iron that was formulated to extract and dechlorinate solvents in groundwater. The unique feature of the highly porous organosilica is its strong affinity for chlorinated solvents, such as trichloroethylene (TCE), while being impervious to dissolved solids. The swellable matrix is able to release ethane after dechlorination and return to the initial state. Iron‐Osorb^® was determined to be highly effective in reducing TCE concentrations in bench‐scale experiments. The material was tested in a series of three pilot scale tests for in situ remediation of TCE in conjunction with the Ohio Environmental Protection Agency at a site in central Ohio. Results of these tests indicate that TCE levels were reduced for a period of time after injection, then leveled out or bounced back, presumably due to depletion of zero‐valent iron. Use of tracer materials and soil corings indicate that Iron‐Osorb^® traveled distances of at least 20 feet from the injection point during soil augmentation. The material appears to remain in place once the injection fluid is diluted into the surrounding groundwater. Overall, the technology is promising as a remediation method to treat dilute plumes or create diffuse permeable reactive barriers. Keys to future implementation include developing injection mechanisms that optimize soil distribution of the material and making the system long‐lasting to allow for continual treatment of contaminants emanating from the soil matrix. © 2011 Wiley Periodicals, Inc.     

A Simple Framework for Incorporating Seasonal Streamflow Forecasts into Existing Water Resource Management Practices1

Gong, Gavin, Lucien Wang, Laura Condon, Alastair Shearman, and Upmanu Lall, 2010. A Simple Framework for Incorporating Seasonal Streamflow Forecasts Into Existing Water Resource Management Practices. Journal of the American Water Resources Association (JAWRA) 46(3):574-585. DOI: 10.1111/j.1752-1688.2010.00435.x Abstract: Climate-based streamflow forecasting, coupled with an adaptive reservoir operation policy, can potentially improve decisions by water suppliers and watershed stakeholders. However, water suppliers are often wary of straying too far from their current management practices, and prefer forecasts that can be incorporated into existing system modeling tools. This paper presents a simple framework for utilizing streamflow forecasts that works within an existing management structure. Climate predictors are used to develop seasonal inflow forecasts. These are used to specify operating rules that connect to the probability of future (end of season) reservoir states, rather than to the current storage, as is done now. By considering both current storage and anticipated inflow, the likelihood of meeting management goals can be improved. The upper Delaware River Basin in the northeastern United States is used to demonstrate the basic idea. Physically plausible climate-based forecasts of March-April reservoir inflow are developed. Existing simulation tools and rule curves for the system are used to convert the inflow forecasts to reservoir level forecasts. Operating policies are revised during the forecast period to release less water during forecasts of low reservoir level. Hindcast simulations demonstrate reductions of 1.6% in the number of drought emergency days, which is a key performance measure. Forecasts with different levels of skill are examined to explore their utility.     

Reality check on career success and weak paradigms: chance still favors the hearty soul

In an earlier article, we discussed the effects of dissensus and low paradigm development on the lives and scholarly successes of junior scholars. Our analysis painted a somewhat bleak picture, but our advice for moving forward was simple, actionable, and therefore hopeful. Based on the bleak picture that was painted, one particular aspect of our work, career‐level evaluation reliability, was recently critiqued. We respond to that critique here. Copyright © 2008 John Wiley & Sons, Ltd.     

Nonpoint-Source Agricultural Hazard Index: A Case Study of the Province of Cremona, Italy

This paper reports the results of a study aimed at the evaluation of the hazard level of farming activities in the province of Cremona, Italy, with particular reference to groundwater. The applied methodology employs a parametric approach based on the definition of potential hazard indexes (nonpoint-source agricultural hazard indexes, NPSAHI). Two categories of parameters were considered: the hazard factors (HF), which represent all farming activities that cause or might cause an impact on groundwater (use of fertilizers and pesticides, application of livestock and poultry manure, food industry wastewater, and urban sludge), and the control factors (CF), which adapt the hazard factor to the characteristics of the site (geographical location, slope, agronomic practices, and type of irrigation). The hazard index (HI) can be calculated multiplying the hazard factors by the control factors and, finally, the NPSAHI are obtained dividing HI into classes on a percentile basis using a scale ranging from 1 to 10. Organization, processing, and display of all data layers were performed using the geographical information system (GIS) ArcView and its Spatial Analyst extension. Results show that the potential hazard of groundwater pollution by farming activities in the province of Cremona falls mainly in the fifth class (very low hazard).     

Brownfield redevelopment as a smart growth option in the United States

An evaluation is made of brownfields redevelopment as a smart growth policy compared to purchase of land, restrictive growth policies, changing transportation patterns, promoting compact development designs on the metropolitan fringe, and regional government. In the US brownfields redevelopment has clear advantages with regard to environmental protection, moral imperative, and government and special interest reactions. Its rank with regard to economic feasibility, ability to respond to changes in technology, and public reaction are not clear. A great deal more research is needed, especially about the costs of brownfield redevelopment and public preferences for housing type and location to be certain about brownfields redevelopment as a viable smart growth option.     

Facilitating climate‐change‐induced range shifts across continental land‐use barriers

Climate changes impose requirements for many species to shift their ranges to remain within environmentally tolerable areas, but near‐continuous regions of intense human land use stretching across continental extents diminish dispersal prospects for many species. We reviewed the impact of habitat loss and fragmentation on species’ abilities to track changing climates and existing plans to facilitate species dispersal in response to climate change through regions of intensive land uses, drawing on examples from North America and elsewhere. We identified an emerging analytical framework that accounts for variation in species' dispersal capacities relative to both the pace of climate change and habitat availability. Habitat loss and fragmentation hinder climate change tracking, particularly for specialists, by impeding both propagule dispersal and population growth. This framework can be used to identify prospective modern‐era climatic refugia, where the pace of climate change has been slower than surrounding areas, that are defined relative to individual species' needs. The framework also underscores the importance of identifying and managing dispersal pathways or corridors through semi‐continental land use barriers that can benefit many species simultaneously. These emerging strategies to facilitate range shifts must account for uncertainties around population adaptation to local environmental conditions. Accounting for uncertainties in climate change and dispersal capabilities among species and expanding biological monitoring programs within an adaptive management paradigm are vital strategies that will improve species' capacities to track rapidly shifting climatic conditions across landscapes dominated by intensive human land use.