Validation of a standardized portable fluorescence method for determining trace beryllium in workplace air and wipe samples

Beryllium is widely used in industry for its unique properties; however, occupational exposure to beryllium particles can cause potentially fatal disease. Consequently, exposure limits for beryllium particles in air and action levels on surfaces have been established to reduce exposure risks for workers. Field-portable monitoring methods for beryllium are desired in order to facilitate on-site measurement of beryllium in the workplace, so that immediate action can be taken to protect human health. In this work, a standardized, portable fluorescence method for the determination of trace beryllium in workplace samples, i.e., air filters and dust wipes, was validated through intra- and inter-laboratory testing. The procedure entails extraction of beryllium in 1% ammonium bifluoride (NH(4)HF(2), aqueous), followed by fluorescence measurement of the complex formed between beryllium ion and hydroxybenzoquinoline sulfonate (HBQS). The method detection limit was estimated to be less than 0.02 microg Be per air filter or wipe sample, with a dynamic range up to greater than 10 microg. The overall method accuracy was shown to satisfy the accuracy criterion (A< or = +/-25%) for analytical methods promulgated by the US National Institute for Occupational Safety and Health (NIOSH). Interferences from numerous metals tested (in >400-fold excess concentration compared to that of beryllium) were negligible or minimal. The procedure was shown to be effective for the dissolution and quantitative detection of beryllium extracted from refractory beryllium oxide particles. An American Society for Testing and Materials (ASTM) International voluntary consensus standard based on the methodology has recently been published.     

The good soldier: who is s(he)?

This paper examines how perceptions of Organizational Citizenship Behaviors (OCBs) are affected by socially constructed gender roles. We argue that gender roles are important for the perception, categorization, and consequences of OCBs. We suggest that the dimensions of OCBs (altruism, courtesy, sportsmanship, and civic virtue) are related to gender stereotypes. Combining social identity theory with gender role theory suggests that the ‘gender’ of these behaviors, the job, the job incumbent, and the gender identity of the observer interact, potentially broaden the breadth of requisite job behaviors defined as either in‐ or extra‐role. Implications are discussed. Copyright © 2001 John Wiley & Sons, Ltd.     

ZOOPLANKTON COMMUNITIES OF A NEW PUMPED STORAGE RESERVOIR1

ABSTRACT: Zooplankton colonization was followed for 16 months in Lake Oconee, Georgia, a new pumped storage reservoir. Data were interpreted to identify differences among stations and seasons, as a function of the reservoir's early stage of development and of pumped storage operations. Colonization was rapid, and the zooplankton community was characterized by a high species diversity; approximately 40 rotifer species and 14 cladoceran genera were recorded. Zooplankton density varied along an environmental gradient from riverine to lentic conditions. Rotifer abundance varied from 10⁴-10⁶ individuals/m³, with maxima in the summers Copepod and cladoceran densities ranged from 10³ to nearly 10⁵ individuals/m³; maxima for stations other than the dam were observed in the summer and early fall, but high values at the dam station occurred throughout winter 1980. When pumped storage operations began in December 1979, zooplankton densities increased at the dam station. Pumpback decreased the intensity of the environmental gradient from riverine to lentic conditions, and led to a more similar zooplankton community structure throughout the reservoir.     

SEDIMENTATION IN LAKE ONALASKA,NAVIGATION POOL 7, UPPER MISSISSIPPI RIVER,SINCE IMPOUNDMENT1

ABSTRACT: Sediment accumulation was evaluated in Lake Onalaska, a 2800-ha backwater impoundment on the Upper Mississippi River. Computer programs were used to process fathometric charts and generate an extensive data set on water depth for the lake. Comparison of 1983 survey data with pre-impoundment (before 1937) data showed that Lake Onalaska had lost less than 10 percent of its original mean depth in the 46 years since impoundment. Previous estimates of sedimentation rates based on Cesium-137 sediment core analysis appear to have been too high.     

A NET BENEFIT MODEL FOR RECREATION PLANNING AT DRINKING WATER RESERVOIRS1

A management model was developed for determining levels of recreation activities at public drinking water reservoirs. Quabbin Reservoir, located in central Massachusetts, served as a case study for the model. An interdisciplinary research team was formed to study the impact of selected recreation activities on water quality, public demand and willingness to pay for selected recreation activities, carrying capacity constraints, and the economic cost/benefits associated with increases in recreation at the Quabbin Reservation. Study variables were integrated into a quadratic programming model, producing the number of participants that corresponds to maximum net benefits for specific development packages on design days. The recreation mix associated with maximum net economic benefits was found to be cost-effective (assuming the use of reasonable entrance fees) and not deleterious to water quality. However, as a result of the findings of a related study, it was recommended that nutrients, particularly from wastewater, not be permitted to enter the reservoir, since the current phosphorous level may be at a critical point. Management techniques that would safeguard against this occurrence were recommended. The model was sensitive to management objectives; recommendations were limited to activities that would not lower the existing high quality of Quabbin water.     

Reconstructed Stream Flow for the Salt and Verde Rivers From Tree-Ring Data1

ABSTRACT: The Salt and Verde Rivers of central Arizona provide the water supply for metropolitan Phoenix and a considerable acreage of irrigated agriculture. Rapid urbanization has caused concern over future water supply and aggravated flooding in the already flood-prone Salt River Valley. Tree-ring data were used as a proxy source to extend the annual and seasonal runoff records back to A.D. 1580 and thus to determine whether the period of record for annual discharge adequately represents the long term flow characteristics of the two rivers. Results show that several periods of extended low flow have occurred during the past 400 years, many of which were more severe then any comparable period since 1890. The low flow periods appear to have a recurrence interval of about 22 years. Also the gaged records contain an above average number of high seasonal and annual flows when compared to the entire 400 years. The reconstructions contain important implications for future water supply and flood potentials in the Salt River Valley.     

An Ombudsman for Humanitarian Assistance?

The early phases of a project to design and make operational an ombudsman for humanitarian assistance (HAO) are described in this paper. Beginning with a brief historical overview of the ombudsman concept, it then outlines seven key features of a potential HAO that were identified in the initial feasibility study. The main conclusion from the feasibility study was that, in principle, it is possible to design an HAO by adapting the operational frameworks of existing ombudsman schemes so as to match the needs of the humanitarian sector. Although this seems possible in theory, there still remain some major challenges requiring practical testing in a pilot phase. The most fundamental of these is how to enable the beneficiaries of aid to make their voices heard and register their views on the management of the emergency that is affecting them. Important also, are the issues of ensuring an international jurisdiction and finding sustainable ways of financing the scheme. Finally, the paper alludes to the framework of the pilot itself and how to address the main challenges ahead.