ANALYSIS OF LAS,ABS AND COMMERCIAL DETERGENTS BY TWO-PHASE TITRATION1

ABSTRACT: A two-phase titration method was developed and evaluated to determine the concentration of linear alkylate sulfonate (LAS), branched-chain alkyl benzene sulfonate (ABS), dishwashing detergents, and laundry detergents in water. This method is capable of quantitatively determining anionic surfactants in either fresh water or saline water and it is therefore superior to the widely used Methylene Blue Method. To simplify the titration method for adoptation to remote field utilization, a field test kit was developed. This test kit includes only a separatory funnel, a titration burette, a set of liquid measuring apparatus, and some chemicals. Emphasis was placed on compactness of the kit and simplicity in the test manipulation, so that its operation can be performed by relatively unskilled wastewater monitoring personnel.     

Orientation in Cave-Dwelling wood rats

Summary Allegheny wood rats (Neotoma floridana magister) are occasionally found beyond the light penetration zone in caves. The means of orientation used by cave-trapped rats were studied using a radial maze and double-platform jumping tasks. The effects of various sensory manipulations upon their performances were evaluated, including visual deprivation, reversible deafening, control of chemical cues, and vibrissae trimming. The rats performed best when visible light was available, but they were able to do the tasks in the absence of light as long as their hearing was intact. Manipulation of other sensory cues had no effect. Intact animals seldom produced sounds when ambient sounds were available, but when these were very soft they did produce nonvical sounds. It appears that these cave-dwelling wood rats use acoustic means of orientation in the dark and that they are able to use some environmental sounds when these are available.     

Seed dispersal of desert annuals

We quantified seed dispersal in a guild of Sonoran Desert winter desert annuals at a protected natural field site in Tucson, Arizona, USA. Seed production was suppressed under shrub canopies, in the open areas between shrubs, or both by applying an herbicide prior to seed set in large, randomly assigned removal plots (10-30 m diameter). Seedlings were censused along transects crossing the reproductive suppression borders shortly after germination. Dispersal kernels were estimated for Pectocarya recurvata and Schismus barbatus from the change in seedling densities with distance from these borders via inverse modeling. Estimated dispersal distances were short, with most seeds traveling less than a meter. The adhesive seeds of P. recurvata went farther than the small S. barbatus seeds, which have no obvious dispersal adaptation. Seeds dispersed farther downslope than upslope and farther when dispersing into open areas than when dispersing into shrubs. Dispersal distances were short relative to the pattern of spatial heterogeneity created by the shrub and open space mosaic. This suggests that dispersal could contribute to local population buildup, possibly facilitating species coexistence. Overall, these results support the hypothesis that escape in time via delayed germination is likely to be more important for desert annuals than escape in space.     

Ticketing aggressive cars and trucks (TACT): How does it work on city streets?

Objective: The purpose of this study was to determine the feasibility of modifying the Ticking Aggressive Cars and Trucks (TACT) program, originally designed to work on state highways, within a metropolitan area to reduce unsafe interactions and their related crashes between drivers of large trucks and passenger vehicles.

Methods: Using crash data, the driving behaviors most commonly associated with large truck and passenger vehicle crashes were identified. A public awareness campaign using media messaging and increased law enforcement was created targeting these associated behaviors. The frequency of these behaviors both before and after the public awareness campaign was determined through observation of traffic at 3 specific locations within the city. Each location had a sufficient volume of large truck and passenger traffic to observe frequent interactions. Pre- and postintervention data were compared using negative binomial regression with generalized estimating equations to evaluate whether the campaign was associated with a reduction in the identified driving behaviors.

Results: A comparison between crash data from before, during, and after the campaign and crashes during the same time periods in previous years did not show a significant difference (P =.081). The number of large trucks observed in traffic remained the same during pre- and postintervention periods (P =.625). The rates of negative interactions per 100 large trucks decreased for both large trucks and passenger vehicles after the intervention, with calculated rate ratios of 0.58 (95% confidence interval [CI], 0.48, 0.70) and 0.31 (95% CI, 0.20, 0.47). The greatest reduction was seen in passenger vehicles following too close, with a rate ratio of 0.21 (95% CI, 0.15, 0.30).

Conclusions: Although designed for reducing crashes on highways, the TACT program can be an effective approach for improving driver behaviors on city streets.     

关于欧盟植物保护品对鸟类和哺乳动物的风险评估的反思：过去、现在和未来

植物保护品在农作物上的使用会导致鸟类和哺乳动物接触有毒化学物质。在欧盟,关于此类暴露的风险评估均以当前(2009)欧洲食品安全局(EFSA)颁布的指导性文件为依据,与之前的版本相比,该文件在理论风险评估的可实现性方面有所提高(SANCO/4145/2000)。自从7年前实施2009 EFSA 指导性文件以来,基于此已经对众多植物保护品的毒性进行了成功地评估。然而,在今后的修订版本中仍然存在需要改进的重要方面。这篇焦点文章讨论了目前方案的风险评估经验,包括输入参数的保守水平和监管当局的解释以及如何在不远的将来对指导性文件进行修订提出建议。明确了推进指导文件的几方面建议,例如与生态相关的鸟类和哺乳动物生殖端点的推导和情境风险评估中建模方法的使用。在完善现有数据库方面,本文也有所强调,包括校对全欧洲相关焦点物种和扩大食物残留数据库。为了能够在将来形成一个真实可用的指导性文件,强烈建议在产业、监管和欧洲食品安全局等部门之间进行开放和建设性的沟通和交流。这样的合作也将鼓励会员国之间的融合,从而减轻产业和监管机构工作负荷。
精选自Amy C. Brooks, Mike Fryer, Alan Lawrence, Juan Pascual, Rachel Sharp. Reflections on bird and mammal risk assessment for plant protection products in the European Union: past, present and future. Environmental Toxicology and Chemistry: Volume 36, Issue 3, pages 565–575, July 2017. DOI: 10.1002/etc.3719
详情请见http://onlinelibrary.wiley.com/wol1/doi/10.1002/etc.3719/full
     

Can urban P conservation help to prevent the brown devolution?

Achieving better understanding phosphorus (P) flows through urban ecosystems is needed to conserve P, as non-renewable phosphate rock deposits become depleted and the global human population increases. A baseline mass flow analysis (MFA) for P developed for the Twin Cities Watershed (TCW, which includes most of the Minneapolis-St. Paul metropolitan region) showed that most P input was stored in the system (65%) or leaked from it (31%); only 4% was deliberately exported as useful products. In a realistic, comprehensive conservation scenario P input was reduced by 15%; deliberate export of P in the form of sewage sludge, food waste, and landscape waste was 68% of P input. In this scenario, increased deliberate export was accomplished by decreasing leakage (to 9% of input) and storage (to 23% of input). If used as agricultural fertilizer, the deliberately exported P in the conservation scenario would support about half of the food production required by the TCW.     

环境技术创新对产业生态管理的影响

产业生态管理呼唤致力于改进资源效率和提高生态效用的环境技术创新.环境技术创新在产业生态管理中的作用日益受到学术界和实践领域的关注,但这种作用到底有多大尚缺乏定量研究.本文构建了由产业生态管理的产出和投入构成的计量经济模型,将产业生态效率作为产出变量,将环境技术创新、环境政策、环保投资和环保人员作为投入变量,考察了环境技术创新对产业生态管理的实际影响.结果表明,当前我国主要省份的环境技术创新对产业生态管理的作用不明显,中西部地区的情况更为明显,而如果将工业创新力全部用于产业生态管理,则可大大削减环保投资、环境政策和环保人员的投入.由此得到结论:如何充分发挥环境技术创新的作用是当前我国生态工业发展的关键问题.     

Monitoring effects of a controlled subsurface carbon dioxide release on vegetation using a hyperspectral imager

A hyperspectral imaging system was used to monitor vegetation during a subsurface controlled release of carbon dioxide (CO₂). From August 3 to 10, 2007, 0.3 tons CO₂/day were released through a 70 m horizontal pipe located at a nominal depth of 1.8 m below the surface. Hyperspectral images of alfalfa plants were collected during the controlled release and used along with classification tree analysis to study changes in the reflectance spectra as a function of perpendicular distance from the horizontal pipe. Changes in the reflectance spectra near the red edge (650–750 nm) were observed over the course of the controlled release experiment for plants within a perpendicular distance of 1 m of the release pipe. These results indicate monitoring vegetation over a carbon sequestration site has the potential to allow monitoring of the integrity of the CO₂ storage.     

Using online databases to find journal articles on injury prevention and safety promotion topics: How do SafetyLit subscribers use other databases?

BackgroundA thorough search of the scholarly literature is an important part of any project. Although there are ethical and scientific reasons to justify the effort required to perform an exhaustive search, we hypothesize that many searchers do not use a sufficient number of databases nor do they use the query focusing techniques necessary to perform a comprehensive search.DesignSubscribers (approximately 19,000 people) to the SafetyLit email update, a weekly listing of recently published research on injury prevention and safety promotion, were surveyed to learn about their performance and knowledge of several key search behaviors necessary for conducting an exhaustive literature search.ResultsOver 90% of respondents perform searches of online databases and, although few have had any training in database use, they always or usually perform the search themselves. They reported performing searches using a wide variety of online bibliographic databases but only 10.3% queried two or more databases the last time they searched. Respondents’ assessment of their own knowledge and skills at searching a database had little to do with the amount of training they have received in the use of the database.ConclusionMost users self-limit the information they gather to that from one or two professional disciplines. Conducting a literature search using only one or two familiar sources can lead to a failure to access essential information published by researchers in parallel fields.     

Dependence on forest resources and tropical deforestation in Ghana

In Ghana, forests provide many products on which the local population subsists. However, these resources are depleting due to a variety of factors including agricultural expansion and over-exploitation of forest resources. This paper presents an analysis of the level of local dependence on forest resources and its implications for forest management in Ghana. The paper also outlines the causes of continuing deforestation in the studied region from the perspective of the local residents and discusses what role they could play in addressing the problem. The aim is to share more light on the current causes of deforestation and make suggestions for improved community-based forest management practices that could help to reduce deforestation. Primary data was collected through personal interviews and focus group discussions with 431 household heads randomly selected from three Forest Districts in Ghana. The survey showed that income from agriculture constituted 60% of the average total rural household income. Forest income provided 38% of total household income, and off-farm income 2%. The four most highly ranked causes of deforestation are poverty-driven agriculture, lack of alternative rural wage employment other than farming, household population levels, and conflict in traditional land practices. This shows a shift in the view of local people who in the past were quick to blame logging companies and government policies for deforestation. The majority of the respondents depended on wild animals like snail, bush meat, wild honey and wild and cultivated vegetables. Given the reasons for deforestation, much thought needs to go into agroforestry practices (e.g. snail farming, bee keeping, fish farming, and vegetable production) in efforts to reduce deforestation, which are currently less promoted. Readers should send their comments on this paper to: BhaskarNath@aol.com within 3 months of publication of this issue.