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661.
J.M. Zhang T. Wang A.J. Ding X.H. Zhou L.K. Xue C.N. Poon W.S. Wu J. Gao H.C. Zuo J.M. Chen X.C. Zhang S.J. Fan 《Atmospheric environment (Oxford, England : 1994)》2009,43(2):228-237
Knowledge on atmospheric abundance of peroxyacetyl nitrate (PAN) is important in assessing the severity of photochemical pollution, and for understanding chemical transformation of reactive odd nitrogen and its impact on the budget of tropospheric ozone (O3). In summer 2006, continuous measurements of PAN were made using an automatic GC–ECD analyzer with an on-line calibrator at a suburban site of Lanzhou (LZ) and a remote site of Mt. Waliguan (WLG) in western China, with concurrent measurements of O3, total reactive nitrogen (NOy) and carbon monoxide (CO). At LZ, several photochemical episodes were observed during the study, and the average mixing ratio of PAN (plus or minus standard deviation) was 0.76 (±0.89) ppbv with the maximum value of 9.13 ppbv, compared to an average value of 0.44 (±0.16) ppbv at remote WLG. The PAN mixing ratios in LZ exhibited strong diurnal variations with a maximum at noon, while enhanced concentrations of PAN were observed in the evening and a minimum in the afternoon at WLG. The daily O3 and PAN concentration maxima showed a strong correlation (r2 = 0.91) in LZ, with a regression slope (PAN/O3) of 0.091 ppbv ppbv?1. At WLG, six well-identified pollution plumes (lasting 2–8 h) were observed with elevated concentrations of PAN (and other trace gases), and analysis of backward particle release simulation shows that the high-PAN events at WLG were mostly associated with the transport of air masses that had passed over LZ. 相似文献
662.
Nenad Aleksic K. Roy G. Sistla J. Dukett N. Houck P. Casson 《Atmospheric environment (Oxford, England : 1994)》2009,43(17):2709-2716
Federal and state programs over the past two decades have resulted in the reduction of emissions of precursors of acid rain. Concomitant with these changes, measured concentrations of acidity in precipitation and in watersheds have shown a downward trend or improvement. However, another pathway for these precursors is through cloud and fog events that often tend to occur at high-elevation regions affecting the fauna and flora as well. In this study we report on long-term measurements of cloud water and precipitation chemistry made from 1994 onwards at a high-elevation location, Whiteface Mountain NY, in the northeastern United States. Trends and inter-relationship between the ions were examined along with ambient SO2 measurements and Adirondack lakes chemistry data. 相似文献
663.
We present one of the most comprehensive studies of night-time radical chemistry to date, from the Tropospheric ORganic CHemistry experiment (TORCH) in the summer of 2003. TORCH provided a wealth of measurements with which to study the oxidizing capacity of the atmosphere. The measurements provided input to a zero-dimensional box model which has been used to study night-time radical chemistry during the campaign. Average night-time predicted concentrations of OH (2.6 × 105 molecule cm?3), HO2 (2.9 × 107 molecule cm?3) and [HO2+ΣRO2] radicals (2.2 × 108 molecule cm?3) were an order of magnitude smaller than those predicted during the daytime. The model under-predicted the night-time measurements of OH, HO2 and [HO2+ΣRO2] radicals, on average by 41%, 16% and 8% respectively. Whilst the model captured the broad features of night-time radical behaviour, some of the specific features that were observed are hard to explain. A rate of radical production assessment was carried out for the whole campaign between the hours of 00:00 and 04:00. Whilst radical production was limited owing to the absence of photolytic reactions, production routes via the reactions of alkenes with O3 provided an effective night-time radical source. Nitrate radical concentrations were predicted to be 0.6 ppt on average with a peak of 18 ppt on August 9th during a polluted heat wave period. Overall, the nitrate radical contributes about a third of the total initiation via RO2, mostly through reaction with alkenes. 相似文献
664.
Zheng Li Erin N. Porter Andreas Sjödin Larry L. Needham Sangil Lee Armistead G. Russell James A. Mulholland 《Atmospheric environment (Oxford, England : 1994)》2009,43(27):4187-4193
Twenty-eight polycyclic aromatic hydrocarbons (PAH) and methylated PAHs (Me-PAH) were measured in daily PM2.5 samples collected at an urban site, a suburban site, and a rural site in and near Atlanta during 2004 (5 samples/month/site). The suburban site, located near a major highway, had higher PM2.5-bound PAH concentrations than did the urban site, and the rural site had the lowest PAH levels. Monthly variations are described for concentrations of total PAHs (∑PAHs) and individual PAHs. PAH concentrations were much higher in cold months than in warm months, with average monthly ∑PAH concentrations at the urban and suburban-highway monitoring sites ranging from 2.12 to 6.85 ng m?3 during January–February and November–December 2004, compared to 0.38–0.98 ng m?3 during May–September 2004. ∑PAH concentrations were found to be well correlated with PM2.5 and organic carbon (OC) within seasons, and the fractions of PAHs in PM2.5 and OC were higher in winter than in summer. Methyl phenanthrenes were present at higher levels than their un-substituted homologue (phenanthrene), suggesting a petrogenic (unburned petroleum products) input. Retene, a proposed tracer for biomass burning, peaked in March, the month with the highest acreage and frequency of prescribed burning and unplanned fires, and in December, during the high residential wood-burning season, indicating that retene might be a good marker for burning of all biomass materials. In contrast, potassium peaked only in December, indicating that it might be a more specific tracer for wood-burning. 相似文献
665.
There are two principal strategies for managing climate change risks: mitigation and adaptation. Until recently, mitigation
and adaptation have been considered separately in both climate change science and policy. Mitigation has been treated as an
issue for developed countries, which hold the greatest responsibility for climate change, while adaptation is seen as a priority
for the South, where mitigative capacity is low and vulnerability is high. This conceptual divide has hindered progress against
the achievement of the fundamental sustainable development challenges of climate change. Recent attention to exploring the
synergies between mitigation and adaptation suggests that an integrated approach could go some way to bridging the gap between
the development and adaptation priorities of the South and the need to achieve global engagement in mitigation. These issues
are explored through a case study analysis of climate change policy and practice in Bangladesh. Using the example of waste-to-compost
projects, a mitigation-adaptation-development nexus is demonstrated, as projects contribute to mitigation through reducing
methane emissions; adaptation through soil improvement in drought-prone areas; and sustainable development, because poverty
is exacerbated when climate change reduces the flows of ecosystem services. Further, linking adaptation to mitigation makes
mitigation action more relevant to policymakers in Bangladesh, increasing engagement in the international climate change agenda
in preparation for a post-Kyoto global strategy. This case study strengthens the argument that while combining mitigation
and adaptation is not a magic bullet for climate policy, synergies, particularly at the project level, can contribute to the
sustainable development goals of climate change and are worth exploring. 相似文献
666.
The fate and transport processes of a toxic chemical such as atrazine, an herbicide, in a reservoir are significantly influenced
by hydrodynamic regimes of the reservoir. The two-dimensional (2D) laterally-integrated hydrodynamics and mass transport model,
CE-QUAL-W2, was enhanced by incorporating a submodel for toxic contaminants and applied to Saylorville Reservoir, Iowa. The
submodel describes the physical, chemical, and biological processes and predicts unsteady vertical and longitudinal distributions
of a toxic chemical. The simulation results from the enhanced 2D reservoir model were validated by measured temperatures and
atrazine concentrations in the reservoir. Although a strong thermal stratification was not identified from both observed and
predicted water temperatures, the spatial variation of atrazine concentrations was largely affected by seasonal flow circulation
patterns in the reservoir. In particular, the results showed the effect of flow circulation on spatial distribution of atrazine
during summer months as the river flow formed an underflow within the reservoir and resulted in greater concentrations near
the surface of the reservoir. Atrazine concentrations in the reservoir peaked around the end of May and early June. A good
agreement between predicted and observed times and magnitudes of peak concentrations was obtained. The use of time-variable
decay rates of atrazine led to more accurate prediction of atrazine concentrations, while the use of a constant half-life
(60 days) over the entire period resulted in a 40% overestimation of peak concentrations. The results provide a better understanding
of the fate and transport of atrazine in the reservoir and information useful in the development of reservoir operation strategies
with respect to timing, amount, and depth of withdrawal. 相似文献
667.
Understanding how setting attributes influence the nature of the visitor experience is crucial to effective recreation management.
Highly influential attributes are useful indicators to monitor within a planning framework, such as Limits of Acceptable Change.
This study sought to identify the setting attributes perceived to have the most profound effect on the ability to have “a
real wilderness experience” and to assess the degree to which attribute importance varied with situational context and visitor
characteristics. To this end, exiting hikers were surveyed at moderate and very high use trailheads in Alpine Lakes Wilderness,
WA (USA), and Three Sisters Wilderness, OR (USA). They were asked about the degree to which encountering varying levels of
different setting attributes would add to or detract from their experience. Attributes with the largest range of effect on
experience, based on evaluations of different levels, were considered most important. The most influential attributes were
litter and several types of campsite interaction—people walking through camp and number of other groups camping close by.
The perceived importance of setting attributes did not vary much between wilderness locations with substantially different
use levels, suggesting that conclusions are robust and generalizable across wilderness areas. There also was little difference
in the perceptions of day and overnight visitors. In contrast, we found substantial variation in the perceived importance
of setting attributes with variation in wilderness experience, knowledge, attachment, and motivation. Our results validate
the emphasis of many wilderness management plans on indicators of social interaction, such as number of encounters. 相似文献
668.
The Effect of Water Harvesting Techniques on Runoff,Sedimentation, and Soil Properties 总被引:1,自引:0,他引:1
This study addressed the hydrological processes of runoff and sedimentation, soil moisture content, and properties under the
effect of different water harvesting techniques (treatments). The study was conducted at three sites, representing environmental
condition gradients, located in the southern part of the West Bank. For each treatment, the study evaluated soil chemical
and physical properties, soil moisture at 30 cm depth, surface runoff and sedimentation at each site. Results showed that
runoff is reduced by 65–85% and sedimentation by 58–69% in stone terraces and semi-circle bunds compared to the control at
the semi-humid site. In addition, stone terraces and contour ridges significantly reduced the amount of total runoff by 80%
and 73%, respectively, at the arid site. Soil moisture content was significantly increased by water harvesting techniques
compared to the control in all treatments at the three study sites. In addition, the difference between the control and the
water harvesting structures were higher in the arid and semi-arid areas than in the semi-humid area. Soil and water conservation,
via utilization of water harvesting structures, is an effective principle for reducing the negative impact of high runoff
intensity and subsequently increasing soil moisture storage from rainfall. Jessour systems in the valley and stone terraces
were effective in increasing soil moisture storage, prolonging the growing season for natural vegetation, and decreasing the
amount of supplemental irrigation required for growing fruit trees. 相似文献
669.
Diversity of Soil Nematodes in Areas Polluted with Heavy Metals and Polycyclic Aromatic Hydrocarbons (PAHs) in Lanzhou,China 总被引:1,自引:0,他引:1
This study investigated the soil nematode community structure along the Yellow River in the Lanzhou area of China, and analyzed
the impact of heavy metals (Cd, Pb, Cr, Cu, and Zn) and polycyclic aromatic hydrocarbons (PAHs) on the nematode community.
Soil samples from five locations (named A–E), which were chosen for soil analysis, showed significant differences in their
heavy metal content (p < 0.01), as well as in the variety of nematodes (up to 41 genera) and families (up to 20) that were present. The different
samples also differed significantly in the total PAH content (p < 0.05), as well as the six types of PAH present. Sites A–C showed the most severe contamination with heavy metals and PAHs;
these sites had the lowest abundance of fungivores and omnivore/predators, but the proportion of bacteriovores was the highest
(p < 0.05). Site E, in contrast, showed only minor pollution with heavy metals and PAHs, and it contained the highest abundance
of plant parasites (p < 0.05). Several nematode ecological indicators were found to correlate with concentration of soil pollutants at all the
sites tested: the maturity index (MI, in addition to plant parasites), plant parasite index (PPI), ΣMI (including all the
soil nematodes), Shannon-Wiener diversity index (H′′), and Wasilewska index (WI). Disturbance to the soil environment was more severe when MI, ΣMI, and H′ values were lower. The results of the study show that the abundance and structure of the soil nematode communities in the
sampling locations were strongly influenced by levels of heavy metals and PAHs in the soil. They also show that the diversity
index H′ and the maturity index can be valuable tools for assessing the impact of pollutants on nematodes. 相似文献
670.
Frank Merry Britaldo Soares-Filho Daniel Nepstad Gregory Amacher Hermann Rodrigues 《Environmental management》2009,44(3):395-407
Logging has been a much maligned feature of frontier development in the Amazon. Most discussions ignore the fact that logging
can be part of a renewable, environmentally benign, and broadly equitable economic activity in these remote places. We estimate
there to be some 4.5 ± 1.35 billion m3 of commercial timber volume in the Brazilian Amazon today, of which 1.2 billion m3 is currently profitable to harvest, with a total potential stumpage value of $15.4 billion. A successful forest sector in
the Brazilian Amazon will integrate timber harvesting on private lands and on unprotected and unsettled government lands with
timber concessions on public lands. If a legal, productive, timber industry can be established outside of protected areas,
it will deliver environmental benefits in synergy with those provided by the region’s network of protected areas, the latter
of which we estimate to have an opportunity cost from lost timber revenues of $2.3 billion over 30 years. Indeed, on all land
accessible to harvesting, the timber industry could produce an average of more than 16 million m3 per year over a 30-year harvest cycle—entirely outside of current protected areas—providing $4.8 billion in returns to landowners
and generating $1.8 billion in sawnwood sales tax revenue. This level of harvest could be profitably complemented with an
additional 10% from logging concessions on National Forests. This advance, however, should be realized only through widespread
adoption of reduced impact logging techniques. 相似文献