Laboratory and Field Evaluation of Measurement Methods for One-Hour Exposures to O3, PM25, and CO

ABSTRACT

While researchers have linked acute (less than 12-hr) ambient O₃, PM₂₅, and CO concentrations to a variety of adverse health effects, few studies have characterized short-term exposures to these air pollutants, in part due to the lack of sensitive, accurate, and precise sampling technologies. In this paper, we present results from the laboratory and field evaluation of several new (or modified) samplers used in the “roll-around” system (RAS), which was developed to measure 1-hr O₃, PM₂₅, and CO exposures simultaneously. All the field evaluation data were collected during two sampling seasons: the summer of 1998 and the winter of 1999.

To measure 1-hr O₃ exposures, a new active O₃ sampler was developed that uses two nitrite-coated filters to measure O₃ concentrations. Laboratory chamber tests found that the active O₃ sampler performed extremely well, with a collection efficiency of 0.96 that did not vary with temperature or relative humidity (RH). In field collocation comparisons with a reference UV photometric monitor, the active O₃ sampler had an effective collection efficiency ranging between 0.92 and 0.96 and a precision for 1-hr measurements ranging between 4 and 6 parts per billion (ppb). The limits of detection (LOD) of this method were 9 ppb-hr for the chamber tests and ~16 ppb-hr for the field comparison tests.

PM_2.5 and CO concentrations were measured using modified continuous monitors—the DustTrak and the Langan, respectively. A size-selective inlet and a Nafion dryer were placed upstream of the DustTrak inlet to remove particles with aerodynamic diameters greater than 2.5 um and to dry particles prior to the measurements, respectively. During the field validation tests, the DustTrak consistently reported higher PM_2.5 concentrations than those obtained by the collocated 12-hr PM_{2 5} PEM samples, by approximately a factor of 2. After the DustTrak response was corrected (correction factor of 2.07 in the summer and 2.02 in the winter), measurements obtained using these methods agreed well with R² values of 0.87 in the summer and 0.81 in the winter. The results showed that the DustTrak can be used along with integrated measurements to measure the temporal and spatial variation in PM_{2 5} exposures. Finally, during the field validation tests, CO concentrations measured using the Langan were strongly correlated with those obtained using the reference method when the CO levels were above the LOD of the instrument [~1 part per million (ppm)].     

Microwave Process for Volatile Organic Compound Abatement

ABSTRACT

The CHA Corporation has completed the U.S. Air Force Phase II Small Business Innovation Research program to investigate the feasibility of using a novel microwave-based process for the removal and destruction of volatile organic compounds (VOCs) in effluents from noncombustion sources, such as paint booth ventilation streams. Removal of solvents by adsorption, followed by the regeneration of saturated granular activated carbon (GAC) by microwave energy, was achieved in a single fixed-bed reactor. Microwave regeneration of the fixed-bed-saturated carbon restored the original GAC adsorption capacity. After 20 adsorption/regeneration cycles, the adsorption capacity dropped from 13.5 g methyl ethyl ketone (MEK)/100 g GAC to 12.5 g MEK/100 g GAC. During microwave regeneration of the GAC fixed bed, the concentrated desorbed paint solvent was oxidized by passing the solvent mixture through a fixed bed of an oxidation catalyst mixed with silicon carbide in a microwave reactor. A 98% oxidation efficiency was consistently achieved from the oxidation of VOCs in the microwave catalytic reactor.     

Decomposition of Gas Phase 1,3-Butadiene by Ultraviolet/Ozone Process

Abstract

A pilot-scale plug-flow reactor was built to investigate its performance in treating airborne 1,3-butadiene (BD) via ozonation (O₃) and ultraviolet (UV)/O₃ technologies. Governing factors, such as the initial molar ratio of ozone to BD, UV volumetric electric input power, and moisture content in the influent airstream, were investigated. Experiments were conducted at an influent BD concentration of ～50 ppm, an ambient temperature of 26 °C, and a gas retention time of 85 sec. Results show that an initial molar ratio of ozone to BD of 3.5 and 2 sufficed to obtain BD decompositions of >90% for ozonation and UV/O₃, respectively. The UV irradiance did not directly promote the decomposition of BD, rather, it played a role in promoting the production of secondary oxidants, such as hydroxyl radicals. Kinetic analyses indicate that both types of BD decomposition are peudo–first-order with respect to BD concentrations. Moisture content (relative humidity = 40–99%) and UV volumetric electric input power (0.147 and 0.294 W/L) are both factors that weakly affect the rate of BD decomposition. Economic evaluation factors, including both energy of ozone production and UV electric input power, were also estimated.     

A temporal trend study (1972-2008) of perfluorooctanesulfonate, perfluorohexanesulfonate, and perfluorooctanoate in pooled human milk samples from Stockholm, Sweden

The widespread presence of perfluorooctanesulfonate (PFOS), perfluorooctanoate (PFOA), and perfluorohexanesulfonate (PFHxS) in human general populations and their slow elimination profiles have led to renewed interest in understanding the potential human neonatal exposures of perfluoroalkyls (PFAs) from consumption of human milk. The objective of this study was to evaluate the concentrations of PFOS, PFHxS, and PFOA in pooled human milk samples obtained in Sweden between 1972 and 2008 (a period representing the most significant period of PFA production) and to see whether the time trend of these analytes parallels that indicated in human serum. Chemical analysis of PFOS, PFHxS, and PFOA was performed on pooled Swedish human milk samples from 1972 to 2008 after methodological refinements. The 20 samples which formed the 2007 pool were also analyzed individually to evaluate sample variations. Analyses were performed by HPLC-MS/MS. Due to the complexities of the human milk matrix and the requirement to accurately quantitate low pg/mL concentrations, meticulous attention must be paid to background contamination if accurate results are to be obtained. PFOS was the predominant analyte present in the pools and all three analytes showed statistically significant increasing trends from 1972 to 2000, with concentrations reaching a plateau in the 1990s. PFOA and PFOS showed statistically significant decreasing trends during 2001-2008. At the end of the study, in 2008, the measured concentrations of PFOS, PFHxS, and PFOA in pooled human milk were 75 pg/mL, 14 pg/mL, and 74 pg/mL, respectively. The temporal concentration trends of PFOS, PFHxS, and PFOA observed in human milk are parallel to those reported in the general population serum concentrations.     

Challenges posed by climate change: is environmental protection an ethical issue?

Climate is one of the more complex physical systems in nature, its behaviour being fundamentally non-linear and chaotic. In assessing the potential risks from climate change and the costs of averting it, researchers and policymakers encounter pervasive uncertainty. Sceptics demand to get rid of the inherent uncertainties, and some experts, on the other end, keep sending out messages of catastrophic scenarios hoping that this will increase people’s awareness of the danger we face. The recent admission of a mistake in IPCC’s Climate change 2007 report (promptly broadcast by all the major media groups and newspapers from Jan. 20th 2010 onwards) made by the head of the Intergovernmental Panel on Climate Change—that Himalayan glaciers could melt away by 2035 (the IPCC claim of 2035 is wrong by over 300 years.)—has already brought a damage to the IPCC’s reputation that is likely to be considerable. But in this paper, perhaps risking being provocative and paradoxical, instead of looking for the right answers to what we think are inevitable uncertainties, we intend to search for new questions that may lead to a new way of thinking and may bring about new lifestyles and behaviour for citizens and firms.     

Development impact of advocacy initiatives in solid waste management in Nigeria

Solid waste management (SWM) in many low- and middle-income countries is sometimes driven by the informal sector. Unfortunately, contributions of the sector to SWM are not acknowledged in many developing countries. This situation often arises from inadequate awareness and lack of advocacy for these development contributions. This article reports on the impact of a study conducted by final-year geography undergraduates on the informal waste management sector in Nsukka urban area, Nigeria. The purposes of this exercise were to stimulate development intervention on behalf of the sector to improve perceptions, attitudes and performance, to impart a range of development research skills and to expose the students to the business opportunities provided by SWM and recycling. Informal waste sector workers and government officials responsible for SWM were interviewed, and some commercial data on recycling operations were collected. Findings of this study indicate that such advocacy initiatives were effective in increasing students’ awareness of opportunities and interest in working in the informal waste sector to promote better SWM and development in Nigeria. Lessons from this university case study are also drawn for other developing countries struggling to achieve the poverty reduction and job creation Millennium Development Goals (MDGs).     

Climate change and variability in Sub-Saharan Africa: a review of current and future trends and impacts on agriculture and food security

Sub-Saharan Africa has been portrayed as the most vulnerable region to the impacts of global climate change because of its reliance on agriculture which is highly sensitive to weather and climate variables such as temperature, precipitation, and light and extreme events and low capacity for adaptation. This article reviews evidence on the scope and nature of the climate change challenge; and assesses the impact of climate change on agriculture and food security in Sub-Saharan Africa. From the review, it is apparent that the climate in Africa is already exhibiting significant changes, evident by changes in average temperature, change in amount of rainfall and patterns and the prevalence of frequency and intensity of weather extremes. The review also revealed that although uncertainties exist with regards to the magnitude of impacts, climate will negatively affect agricultural production in Sub-Saharan Africa. Specifically, as result of current and expected climate change, the area suitable for agriculture, the length of growing seasons and yield potential, particularly along the margins of semi-arid and arid areas, are expected to decrease. These impacts will affect all components of food security: food availability, food accessibility, food utilisation and food stability and hence increase the risk of hunger in the region. The review thus confirms the general consensus that Sub-Saharan Africa is the most vulnerable region to climate change. It suggests that, policymakers and development agencies should focus on formulating and implementing policies and programmes that promote farm level adaptation strategies currently being practiced by farmers across the region.     

The survey of living conditions in the Arctic (SLiCA): A comparative sustainable livelihoods assessment

The Arctic is a region of the world experiencing extremely rapid climatic and social change. Indigenous communities have faced similar challenges for millennia and have historically demonstrated remarkable resilience to socioecological perturbations. In contemporary contexts, however, it appears that the pace and extent of change is overwhelming the adaptive capacities of many indigenous communities. Scholars recently completed a survey of living conditions spanning the circumpolar Arctic to quantitatively document the impacts of social and ecological stress across regions. The database they created is called the Survey of Living Conditions in the Arctic or SLiCA. This article explores the utility of using this dataset to compare livelihood systems across three sub-regions of Alaska and four sub-regions within the Chukotka Autonomous Okrug of the Russian Federation. The results point out that livelihood systems in Chukotka have a substantially lower level of sustainability than in Northwest Alaska due to the high prevalence of vulnerable households.     

Intensification level of rice farming in Myanmar: implication for its sustainable development

This study aims to estimate the intensification of rice farming in Myanmar particularly due to chemical fertilizer application, using farm-level data obtained from field surveys conducted in the 2000s. Relatively high-input rice farming was found in dry season crop in the delta zone and the double crop in well-irrigated lowlands of the central dry zone. The chemical fertilizer used there was about 88–159 kg NPK (nitrogen, N; phosphate, P₂O₅; and potash, K₂O) ha⁻¹ (76–110 kg nitrogen (N) ha⁻¹), and the average paddy yield ranged from 2.8 to 3.5 ton ha⁻¹. On the other hand, nutrient input in survey sites of rain-fed lowland was between 11 and 53 kg NPK ha⁻¹ (5 and 36 kg N ha⁻¹), and the yield ranged from 1.1 to 2.3 ton ha⁻¹. The national average of paddy yield and nutrient input of fertilizer was roughly estimated to be around 2.4 ton ha⁻¹ and 60 kg NPK ha⁻¹, respectively. A gap was observed between these calculated values and the official statistics. A comparison of fertilizer use efficiency for rice production in Myanmar with that in China and Vietnam has shown that the efficiency in Myanmar has not declined to an inappropriate level even in its intensive ones. Rice production in Myanmar has room for increasing the yield by capital intensification. Nevertheless, considering its sustainability as well as productivity, further intensification in rice farming technology in irrigated lowlands of Myanmar may neither be the best nor the only way.