Peroxidase-mediated removal of endocrine disrupting compound mixtures from water

Several classes of oxidative enzymes have shown promise for efficient removal of endocrine disrupting compounds (EDCs) that are resistant to conventional wastewater treatments. Although the kinetics of reactions between individual EDCs and selected oxidative enzymes are well documented in the literature, there has been little investigation of reactions with EDC mixtures. This makes it impossible to predict how enzyme-mediated treatment systems will perform since wastewater effluents generally contain multiple EDCs. This paper reports pseudo-first order rate constants for a model oxidative enzyme, horseradish peroxidase (HRP), during single-substrate (k₁) and mixed-substrate (k_1-MIX) reactions. Measured values are compared with literature values of three Michaelis-Menten parameters: half-saturation constant (K_M), enzyme turnover number (k_CAT), and the ratio k_CAT/K_M. Published reports had suggested that each of these could be correlated with HRP reactivity towards EDCs in mixtures, and empirical results from this study show that K_M can be used to predict the sequence of EDC removal reactions within a particular mixture. We also observed that k_1-MIX values were generally greater than k₁ values and that compounds exhibiting greatest estrogenic toxicities reacted most rapidly in a given mixture. Finally, because K_M may be tedious to measure for every EDC of interest, we have constructed a quantitative structure-activity relationship (QSAR) model to predict these values. This model predicts K_M quite accurately (R² = 89%) based on two molecular characteristics: molecular volume and hydration energy. Its accuracy makes this QSAR a useful tool for predicting which EDCs will be removed most efficiently during enzyme treatment of EDC mixtures.     

Charge-based fractionation of oxyanion-forming metals and metalloids leached from recycled concrete aggregates of different degrees of carbonation: A comparison of laboratory and field leaching tests

The release and charge-based fractionation of As, Cr, Mo, Sb, Se and V were evaluated in leachates generated from recycled concrete aggregates (RCA) in a laboratory and at a field site. The leachates, covering the pH range 8.4-12.6, were generated from non-carbonated, and artificially and naturally carbonated crushed concrete samples. Comparison between the release of the elements from the non-carbonated and carbonated samples indicated higher solubility of the elements from the latter. The laboratory leaching tests also revealed that the solubility of the elements is low at the “natural pH” of the non-carbonated materials and show enhancement when the pH is decreased. The charge-based fractionation of the elements was determined by ion-exchange solid phase extraction (SPE); it was found that all the target elements predominantly existed as anions in both the laboratory and field leachates. The high fraction of the anionic species of the elements in the leachates from the carbonated RCA materials verified the enhanced solubility of the oxyanionic species of the elements as a result of carbonation. The concentrations of the elements in the leachates and SPE effluents were determined by inductively coupled plasma mass spectrometry (ICP-MS).     

Interactions between accumulation of trace elements and macronutrients in Salix caprea after inoculation with rhizosphere microorganisms

Although the beneficial effects on growth and trace element accumulation in Salix spp. inoculated with microbes are well known, little information is available on the interactions among trace elements and macronutrients. The main purpose of this study was to assess the effect of phytoaugmentation with the rhizobacteria Agromyces sp., Streptomyces sp., and the combination of each of them with the fungus Cadophora finlandica on biomass production and the accumulation of selected trace elements (Zn, Cd, Fe) and macronutrients (Ca, K, P and Mg) in Salix caprea grown on a moderately polluted soil. Dry matter production was significantly enhanced only upon inoculation with Agromyces sp. Regarding the phytoextraction of Cd and Zn, shoot concentrations were mostly increased after inoculation with Streptomyces sp. and Agromyces sp. + C. finlandica. These two treatments also showed higher translocation factors from roots to the leaves for both Cd and Zn. The accumulation of Cd and Zn in shoots was related to increased concentrations of K. This suggests that microorganisms that contribute to enhanced phytoextraction of Cd and Zn affect also the solubility and thus phytoavailability of K. This study suggests that the phytoextraction of Zn and Cd can be improved by inoculation with selected microbial strains.     

A Critique of Estimating Future Costs Using Most Likely Value

ASTM E2137 (Standard Guide for Estimating Monetary Costs and Liability for Environmental Matters, or E2137) is the guidance for developing estimates of future environmental costs. E2137 provides a hierarchy of cost estimation approaches, and expresses an explicit preference for the use of probabilistic cost analysis to develop expected values for environmental costs. Dr. Ram and his colleagues have published an article (Remediation Journal, Autumn 2013) which rejects the use of EV analysis, arguing that while “good in principle” it has little practical value because it is nearly impossible to develop supportable probabilities. The E2137 principles and processes have been used for more than a decade in the context of addressing future environmental costs, yet their view of E2137 renders the standard meaningless. We conclude that the deficiency is not in the ASTM standard, and that when properly constructed, probabilistic analyses can be used to develop expected values with supportable probabilities. ©2015 Wiley Periodicals, Inc.     

Integrating the Social Dimension in Remediation Decision‐Making: State of the Practice and Way Forward

Sustainable remediation guidance, frameworks, and case studies have been published at an international level illustrating established sustainability assessment methodologies and successful implementation. Though the terminology and indicators evaluated may differ, one common theme among international organizations and regulatory bodies is more comprehensive and transparent methods are needed to evaluate the social sphere of sustainable remediation. Based on a literature review and stakeholder input, this paper focused on three main areas: (1) status quo of how the social element of sustainable remediation is assessed among various countries and organizations; (2) methodologies to quantitatively and qualitatively evaluate societal impacts; and (3) findings from this research, including challenges, obstacles, and a path forward. In conclusion, several existing social impact assessment techniques are readily available for use by the remediation community, including rating and scoring system evaluations, enhanced cost benefit analysis, surveys/interviews, social network analysis, and multicriteria decision analysis. In addition, a list of 10 main social indicator categories were developed: health and safety, economic stimulation, stakeholder collaboration, benefits community at large, alleviate undesirable community impacts, equality issues, value of ecosystem services and natural resources, risk‐based land management and remedial solutions, regional and global societal impacts, and contributions to other policies. Evaluation of the social element of remedial activities is not without challenges and knowledge gaps. Identification of obstacles and gaps during the project planning process is essential to defining sustainability objectives and choosing the appropriate tool and methodology to conduct an assessment. Challenges identified include meaningful stakeholder engagement, risk perception of stakeholders, and trade‐offs among the various triple bottom line dimensions. ©2015 Wiley Periodicals, Inc.     

long Term Goals for Environmental Control— What’s Desirable and Possible in the Year 2000?

A panel discussion looking forward to the environment in the year 2000, was arranged by Lionel V. Baldwin, Program Chairman for APCA’s 67th Annual Meeting. To provide a lofty introduction of the subject he reached into outer space for a moderator—Captain Walter M. Schirra, one of the original astronaut team.     

Mesoscale Air Pollution Transport in the Chicago Lake Breeze

A two-day field program in Chicago studied mesoscale pollution transport during typical lake breezes. Streamlines calculated from serial pibal data suggest that a nearly closed circulation cell traps pollutants emitted near a shore line. Optically tracked tetroons confirm the helical trajectory of air within the lake breeze regime. Pollutants released within the inflow layer move inland, rise in a narrow zone of updrafts (100 cm/sec) at the lake breeze front, advect lakeward in the return flow layer aloft, and then subside back down into the inflow layer. Pollution then fumigates back to the surface as the air returns inland a second time causing concentrations higher than would otherwise be expected. Spectral aerosol measurements (0.5-3.0 and 7.0-9.0 micrometer size ranges) made by an instrumented aircraft reveal a marked particle size sorting.     

LEAD AND CADMIUM ASSOCIATED WITH SALTWATER INTRUSION IN A NEW JERSEY AQUIFER SYSTEM1

ABSTRACT: The U.S. Geological Survey collected ground-water samples from the upper and middle aquifers of the Potomac-Raritan-Magothy aquifer system in a 400-square-mile area of New Jersey from 1984 through 1986. Concentrations of lead were greater than the U.S. Environmental Protection Agency maximum contaminant level (MCL) of 50 micrograms per liter in water from 16 of 239 wells. The cencentrations of cadmium were greater than the MCL of 10 micrograms per liter in water from 10 to 241 wells. One-half of the wells that exceeded the lead MCL were in known areas of saltwater intrusion, as were all 10 wells that exceeded the cadmium MCL. The association of elevated concentrations of these metals with elevated concentrations of chloride indicates a mochanism related to saltwater intrusion.     

Economic incentives for TQEM: Are they in your future?

Traditional command-and-control regulations provide few opportunities for total quality environmental management because they usually do not take into account cost and efficiency factors. However, in the past several years both Congress and EPA have shown increasing interest in using incentive-type approaches to regulate the environment. These include taxes, marketable pollution privileges, deposits and refunds, information disclosure provisions, and subsidies. The author details examples of each and discusses how they can effectively complement a quality program.