Effects of Weathering on Mechanical,Antimicrobial Properties and Biodegradation Process of Silver Loaded TPE Compounds

The incorporation of antimicrobial metals such as silver is an alternative to protect the material against microbial attack. However, loaded polymer can lose its antimicrobial properties after some time of use, and the additive may even leak out into the environment becoming harmful to non-target organisms. This study aims to evaluate the mechanical properties and antimicrobial activity of silver containing thermoplastic elastomer (TPE) samples exposed to weathering and the influence of additive incorporation in material biodegradation in the soil. For this purpose, silver ions (Ag⁺_bentonite, Ag⁺_phosphate) and silver nanoparticles (AgNp_silica) based additives were blended in a formulation of SEBS, polypropylene and mineral oil. The test samples were exposed to natural ageing over nine months, and were then evaluated according to their mechanical properties, antimicrobial activity, and degree of crystallinity and surface characteristics. The biodegradation process before and after natural ageing was evaluated through the generation of carbon dioxide. The results show that the action of natural ageing reduced the mechanical properties of loaded and unloaded TPE, and modified the degree of crystallinity and the chemical characteristic of the TPE surface. The presence or type of additive did not influence material resistance after being exposed to weathering. A decrease in antimicrobial activity in samples after natural ageing was observed. At a variable level and according to the chemical content, generation of carbon dioxide from TPE samples was greater in aged samples than in unexposed ones.     

Integrating Modeling and Field Experiments to Evaluate Impacts of Vegetative Practices on Ponderosa Pine Watersheds1

Abstract: Determining watershed response to vegetation treatment has been the subject of numerous hydrologic studies over the years. However, generalizing the information obtained from traditional paired‐watershed studies to other watersheds in a region is problematic because of the empirical nature of such studies and the context dependence of hydrologic responses. This paper addresses the issue of generalizing hydrologic information through integration of process‐based modeling and field observations from small‐scale watershed experiments. To this end, the results from application of a process‐based model were compared with the results from small‐scale watershed experiments in ponderosa pine forests of Arizona. The model simulated treatment impacts reasonably well when compared to the traditional paired‐watershed approach. However, the model tended to overestimate water yields during periods of low flow, and there was a significant difference between the two approaches in the estimation of treatment impacts during the first four years following treatment. The results indicate that the lumped‐parameter modeling approach used here may be limited in its ability to detect small changes, and tends to overestimate changes that occur immediately following treatment. It is concluded that watershed experiments can be highly informative due to their direct examination of cause‐effect relationships, while process‐based models are useful for their processing power and focus on functional relationships. The integrated use of both watershed experiments and process‐based models provides a way to generalize hydrologic information, illuminate the processes behind landscape treatment effects, and to generate and test hypotheses.     

Healthcare waste generation in hospitals per continent: a systematic review

Environmental Science and Pollution Research - There are increasing worldwide concerns about the negative impacts of healthcare waste generated in hospitals, especially in low- and middle-income...     

Recycling Expanded Polystyrene with a Biodegradable Solvent to Manufacture 3D Printed Prototypes and Finishing Materials for Construction

Journal of Polymers and the Environment - The amount of plastic waste generated is causing damage to the environment, such as sea and soil pollution, and one of the alternatives for disposing of...     

Ionic Dye Removal Using Solvent-Assisted Ionic Micellar Flocculation

Journal of Polymers and the Environment - The environmental impacts caused by dyes in industrial wastewater are incalculable, due to their adverse effects on the ecosystem and human life,...     

Chronic exposure to lead acetate promotes changes in the alveolar bone of rats: microstructural and physical–chemical characterization

Environmental Science and Pollution Research - There are a few data relating to the effects of lead (Pb) exposure on the alveolar bone, which has very distinct morphophysiological characteristics...